Ethyl 2-chloro-[2-(4-chlorophenyl)hydrazin-1-ylidene]acetate
The title compound, C10H10Cl2N2O2, features a planar Car—N(H)—N=C(Cl) unit [torsion angle = 5.5 (4)°] whose benzene substituent is coplanar with it [dihedral angle = 4.7 (4)°]; this unit is slightly twisted with respec...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2010-09-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810032599 |
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author | Abdullah M. Asiri Mohie E. M. Zayed Seik Weng Ng |
author_facet | Abdullah M. Asiri Mohie E. M. Zayed Seik Weng Ng |
author_sort | Abdullah M. Asiri |
collection | DOAJ |
description | The title compound, C10H10Cl2N2O2, features a planar Car—N(H)—N=C(Cl) unit [torsion angle = 5.5 (4)°] whose benzene substituent is coplanar with it [dihedral angle = 4.7 (4)°]; this unit is slightly twisted with respect to the carboxyl –CO2 fragment [dihedral angle = 2.2 (52)°]. The amino group acts as a hydrogen-bond donor to the carbonyl O atom of an adjacent molecule; the hydrogen bond generates a helical polymer that runs along the b axis of the monoclinic unit cell. |
first_indexed | 2024-12-10T17:01:01Z |
format | Article |
id | doaj.art-f15e8c5d8a534e8cab4d14e6653a1f40 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-10T17:01:01Z |
publishDate | 2010-09-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-f15e8c5d8a534e8cab4d14e6653a1f402022-12-22T01:40:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669o2375o237510.1107/S1600536810032599Ethyl 2-chloro-[2-(4-chlorophenyl)hydrazin-1-ylidene]acetateAbdullah M. AsiriMohie E. M. ZayedSeik Weng NgThe title compound, C10H10Cl2N2O2, features a planar Car—N(H)—N=C(Cl) unit [torsion angle = 5.5 (4)°] whose benzene substituent is coplanar with it [dihedral angle = 4.7 (4)°]; this unit is slightly twisted with respect to the carboxyl –CO2 fragment [dihedral angle = 2.2 (52)°]. The amino group acts as a hydrogen-bond donor to the carbonyl O atom of an adjacent molecule; the hydrogen bond generates a helical polymer that runs along the b axis of the monoclinic unit cell.http://scripts.iucr.org/cgi-bin/paper?S1600536810032599 |
spellingShingle | Abdullah M. Asiri Mohie E. M. Zayed Seik Weng Ng Ethyl 2-chloro-[2-(4-chlorophenyl)hydrazin-1-ylidene]acetate Acta Crystallographica Section E |
title | Ethyl 2-chloro-[2-(4-chlorophenyl)hydrazin-1-ylidene]acetate |
title_full | Ethyl 2-chloro-[2-(4-chlorophenyl)hydrazin-1-ylidene]acetate |
title_fullStr | Ethyl 2-chloro-[2-(4-chlorophenyl)hydrazin-1-ylidene]acetate |
title_full_unstemmed | Ethyl 2-chloro-[2-(4-chlorophenyl)hydrazin-1-ylidene]acetate |
title_short | Ethyl 2-chloro-[2-(4-chlorophenyl)hydrazin-1-ylidene]acetate |
title_sort | ethyl 2 chloro 2 4 chlorophenyl hydrazin 1 ylidene acetate |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536810032599 |
work_keys_str_mv | AT abdullahmasiri ethyl2chloro24chlorophenylhydrazin1ylideneacetate AT mohieemzayed ethyl2chloro24chlorophenylhydrazin1ylideneacetate AT seikwengng ethyl2chloro24chlorophenylhydrazin1ylideneacetate |