3-(6-Methyl-2-pyridyl)-2-phenyl-3,4-dihydro-1,3,2-benzoxazaphosphinine 2-oxide

In the title compound, C19H17N2O2P, the six-membered 1,3,2-oxazaphosphinine ring adopts a boat conformation with the phosphoryl O atom in an equatorial position. The dihedral angle between the 6-methyl-2-pyridyl and phenyl groups is 75.5 (1)°. These substituents are trans...

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Bibliographic Details
Main Authors: V. H. H. Surendra Babu, M. Krishnaiah, M. Anil Kumar, C. Suresh Reddy, Rajni Kant
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809040367
Description
Summary:In the title compound, C19H17N2O2P, the six-membered 1,3,2-oxazaphosphinine ring adopts a boat conformation with the phosphoryl O atom in an equatorial position. The dihedral angle between the 6-methyl-2-pyridyl and phenyl groups is 75.5 (1)°. These substituents are trans to each other, and are oriented at angles of 57.2 (1) and 74.8 (1)°, respectively, to the benzene ring. The crystal structure is stabilized by intra- and intermolecular hydrogen bonds. The phosphoryl O atom participates in intermolecular C—H...O interactions with the neighbouring molecules, forming centrosymmetric R22(14) dimers.
ISSN:1600-5368