N-tert-Butoxycarbonyl-α-(2-fluorobenzyl)-l-proline
In the title compound, C17H22FNO4, the pyrrolidine ring adopts an envelope conformation with the disordered components of the methylene C atom, with site occupancies of 0.896 (7) and 0.104 (7), being the flap on either side of the mean plane involving the other atoms of the ring....
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813019788 |
| _version_ | 1819289365016215552 |
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| author | Mohd Mustaqim Rosli Ibrahim Abdul Razak R. V. Krishnakumar N. Srinivasan P. Rajalakshmi |
| author_facet | Mohd Mustaqim Rosli Ibrahim Abdul Razak R. V. Krishnakumar N. Srinivasan P. Rajalakshmi |
| author_sort | Mohd Mustaqim Rosli |
| collection | DOAJ |
| description | In the title compound, C17H22FNO4, the pyrrolidine ring adopts an envelope conformation with the disordered components of the methylene C atom, with site occupancies of 0.896 (7) and 0.104 (7), being the flap on either side of the mean plane involving the other atoms of the ring. The carboxylic acid group forms dihedral angles of 72.06 (11) and 45.44 (5)° with the N-tert-butoxycarbonyl group and the 2-fluorobenzyl group, respectively. In the crystal, two-dimensional layers of molecules parallel to (001) are built through an R44(23) motif generated via O—H...O, C—H...O and C—H...F interactions, and an R22(11) motif generated by C—H...O and C—H...F interactions. |
| first_indexed | 2024-12-24T03:05:41Z |
| format | Article |
| id | doaj.art-f19278b7e4e4494a89d8101cf1f5a8c0 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:05:41Z |
| publishDate | 2013-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-f19278b7e4e4494a89d8101cf1f5a8c02022-12-21T17:18:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-08-01698o1297o129710.1107/S1600536813019788N-tert-Butoxycarbonyl-α-(2-fluorobenzyl)-l-prolineMohd Mustaqim RosliIbrahim Abdul RazakR. V. KrishnakumarN. SrinivasanP. RajalakshmiIn the title compound, C17H22FNO4, the pyrrolidine ring adopts an envelope conformation with the disordered components of the methylene C atom, with site occupancies of 0.896 (7) and 0.104 (7), being the flap on either side of the mean plane involving the other atoms of the ring. The carboxylic acid group forms dihedral angles of 72.06 (11) and 45.44 (5)° with the N-tert-butoxycarbonyl group and the 2-fluorobenzyl group, respectively. In the crystal, two-dimensional layers of molecules parallel to (001) are built through an R44(23) motif generated via O—H...O, C—H...O and C—H...F interactions, and an R22(11) motif generated by C—H...O and C—H...F interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536813019788 |
| spellingShingle | Mohd Mustaqim Rosli Ibrahim Abdul Razak R. V. Krishnakumar N. Srinivasan P. Rajalakshmi N-tert-Butoxycarbonyl-α-(2-fluorobenzyl)-l-proline Acta Crystallographica Section E |
| title | N-tert-Butoxycarbonyl-α-(2-fluorobenzyl)-l-proline |
| title_full | N-tert-Butoxycarbonyl-α-(2-fluorobenzyl)-l-proline |
| title_fullStr | N-tert-Butoxycarbonyl-α-(2-fluorobenzyl)-l-proline |
| title_full_unstemmed | N-tert-Butoxycarbonyl-α-(2-fluorobenzyl)-l-proline |
| title_short | N-tert-Butoxycarbonyl-α-(2-fluorobenzyl)-l-proline |
| title_sort | n tert butoxycarbonyl 945 2 fluorobenzyl l proline |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813019788 |
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