Optimization of laser wavelength, power and pulse duration for eye-safe Raman spectroscopy

Abstract Raising the interest in remote chemical analysis, in particular through Raman and fluorescence spectroscopy, the opportunity of increasing the exposure represents an important step for an easier and more reliable spectrum analysis. However, the European directive 2006/25/EC defines the maxi...

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Main Authors: Federico Angelini, Francesco Colao
Format: Article
Language:English
Published: EDP Sciences 2019-03-01
Series:Journal of the European Optical Society-Rapid Publications
Subjects:
Online Access:http://link.springer.com/article/10.1186/s41476-019-0099-y
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author Federico Angelini
Francesco Colao
author_facet Federico Angelini
Francesco Colao
author_sort Federico Angelini
collection DOAJ
description Abstract Raising the interest in remote chemical analysis, in particular through Raman and fluorescence spectroscopy, the opportunity of increasing the exposure represents an important step for an easier and more reliable spectrum analysis. However, the European directive 2006/25/EC defines the maximum permitted exposure (MPE) to artificial radiations according to exposure duration, wavelength, coherence of the radiation and beam divergence. Though the Raman cross section scales in general according to the fourth power of the excitation wavelength, promoting the use of deep UV radiation, a synergy between wavelength and exposure time can raise the Raman signal in the near UV or in the near IR if compliance to eye-safety directives is requested. In this work we will analyze the possibilities offered by commercially available components for enhancing the Raman scattering under eye-safe conditions.
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spelling doaj.art-f1d1582289034ad8bb6d6c3d07a693fa2022-12-21T18:33:45ZengEDP SciencesJournal of the European Optical Society-Rapid Publications1990-25732019-03-011511810.1186/s41476-019-0099-yOptimization of laser wavelength, power and pulse duration for eye-safe Raman spectroscopyFederico Angelini0Francesco Colao1ENEA FSN-TECFIS-DIMENEA FSN-TECFIS-DIMAbstract Raising the interest in remote chemical analysis, in particular through Raman and fluorescence spectroscopy, the opportunity of increasing the exposure represents an important step for an easier and more reliable spectrum analysis. However, the European directive 2006/25/EC defines the maximum permitted exposure (MPE) to artificial radiations according to exposure duration, wavelength, coherence of the radiation and beam divergence. Though the Raman cross section scales in general according to the fourth power of the excitation wavelength, promoting the use of deep UV radiation, a synergy between wavelength and exposure time can raise the Raman signal in the near UV or in the near IR if compliance to eye-safety directives is requested. In this work we will analyze the possibilities offered by commercially available components for enhancing the Raman scattering under eye-safe conditions.http://link.springer.com/article/10.1186/s41476-019-0099-yRaman spectroscopyStandoff identificationSafety directivesLaser exposureEye-safe
spellingShingle Federico Angelini
Francesco Colao
Optimization of laser wavelength, power and pulse duration for eye-safe Raman spectroscopy
Journal of the European Optical Society-Rapid Publications
Raman spectroscopy
Standoff identification
Safety directives
Laser exposure
Eye-safe
title Optimization of laser wavelength, power and pulse duration for eye-safe Raman spectroscopy
title_full Optimization of laser wavelength, power and pulse duration for eye-safe Raman spectroscopy
title_fullStr Optimization of laser wavelength, power and pulse duration for eye-safe Raman spectroscopy
title_full_unstemmed Optimization of laser wavelength, power and pulse duration for eye-safe Raman spectroscopy
title_short Optimization of laser wavelength, power and pulse duration for eye-safe Raman spectroscopy
title_sort optimization of laser wavelength power and pulse duration for eye safe raman spectroscopy
topic Raman spectroscopy
Standoff identification
Safety directives
Laser exposure
Eye-safe
url http://link.springer.com/article/10.1186/s41476-019-0099-y
work_keys_str_mv AT federicoangelini optimizationoflaserwavelengthpowerandpulsedurationforeyesaferamanspectroscopy
AT francescocolao optimizationoflaserwavelengthpowerandpulsedurationforeyesaferamanspectroscopy