DCMC as a Promising Alternative to Bentonite in White Wine Stabilization. Impact on Protein Stability and Wine Aromatic Fraction

Protein haze in white wine is one of the most common non-microbial defects of commercial wines, with bentonite being the main solution utilized by the winemaking industry to tackle this problem. Bentonite presents some serious disadvantages, and several alternatives have been proposed. Here, an alte...

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Main Authors: Francesco Saracino, João Brinco, Diana Gago, Marco Gomes da Silva, Ricardo Boavida Ferreira, Jorge Ricardo-da-Silva, Ricardo Chagas, Luísa Maria Ferreira
Format: Article
Language:English
Published: MDPI AG 2021-10-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/26/20/6188
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author Francesco Saracino
João Brinco
Diana Gago
Marco Gomes da Silva
Ricardo Boavida Ferreira
Jorge Ricardo-da-Silva
Ricardo Chagas
Luísa Maria Ferreira
author_facet Francesco Saracino
João Brinco
Diana Gago
Marco Gomes da Silva
Ricardo Boavida Ferreira
Jorge Ricardo-da-Silva
Ricardo Chagas
Luísa Maria Ferreira
author_sort Francesco Saracino
collection DOAJ
description Protein haze in white wine is one of the most common non-microbial defects of commercial wines, with bentonite being the main solution utilized by the winemaking industry to tackle this problem. Bentonite presents some serious disadvantages, and several alternatives have been proposed. Here, an alternative based on a new cellulose derivative (dicarboxymethyl cellulose, DCMC) is proposed. To determine the efficiency of DCMC as a bentonite alternative, three monovarietal wines were characterized, and their protein instability and content determined by a heat stability test (HST) and the Bradford method, respectively. The wines were treated with DCMC to achieve stable wines, as shown by the HST, and the efficacy of the treatments was assessed by determining, before and after treatment, the wine content in protein, phenolic compounds, sodium, calcium, and volatile organic compounds (VOCs) as well as the wine pH. DCMC applied at dosages such as those commonly employed for bentonite was able to reduce the protein content in all tested wines and to stabilize all but the Moscatel de Setúbal varietal wine. In general, DCMC was shown to induce lower changes in the wine pH and phenolic content than bentonite, reducing the wine calcium content. Regarding which VOCs are concerned, DCMC produced a general impact similar to that of bentonite, with differences depending on wine variety. The results obtained suggest that DCMC can be a sustainable alternative to bentonite in protein white wine stabilization.
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spelling doaj.art-f1d22fe95ad74ddea2113b236bd531b52023-11-22T19:19:28ZengMDPI AGMolecules1420-30492021-10-012620618810.3390/molecules26206188DCMC as a Promising Alternative to Bentonite in White Wine Stabilization. Impact on Protein Stability and Wine Aromatic FractionFrancesco Saracino0João Brinco1Diana Gago2Marco Gomes da Silva3Ricardo Boavida Ferreira4Jorge Ricardo-da-Silva5Ricardo Chagas6Luísa Maria Ferreira7LEAF—Linking Landscape, Environment, Agriculture and Food Research Center, Instituto Superior de Agronomia, Universidade de Lisboa, Tapada da Ajuda, 1349-017 Lisboa, PortugalCENSE—Center for Environmental and Sustainability Research, NOVA School of Science and Technology, NOVA University of Lisbon, 2829-516 Caparica, PortugalLAQV-REQUIMTE, Departamento de Química, NOVA School of Science and Technology, 2829-516 Caparica, PortugalLAQV-REQUIMTE, Departamento de Química, NOVA School of Science and Technology, 2829-516 Caparica, PortugalLEAF—Linking Landscape, Environment, Agriculture and Food Research Center, Instituto Superior de Agronomia, Universidade de Lisboa, Tapada da Ajuda, 1349-017 Lisboa, PortugalLEAF—Linking Landscape, Environment, Agriculture and Food Research Center, Instituto Superior de Agronomia, Universidade de Lisboa, Tapada da Ajuda, 1349-017 Lisboa, PortugalLAQV-REQUIMTE, Departamento de Química, NOVA School of Science and Technology, 2829-516 Caparica, PortugalLAQV-REQUIMTE, Departamento de Química, NOVA School of Science and Technology, 2829-516 Caparica, PortugalProtein haze in white wine is one of the most common non-microbial defects of commercial wines, with bentonite being the main solution utilized by the winemaking industry to tackle this problem. Bentonite presents some serious disadvantages, and several alternatives have been proposed. Here, an alternative based on a new cellulose derivative (dicarboxymethyl cellulose, DCMC) is proposed. To determine the efficiency of DCMC as a bentonite alternative, three monovarietal wines were characterized, and their protein instability and content determined by a heat stability test (HST) and the Bradford method, respectively. The wines were treated with DCMC to achieve stable wines, as shown by the HST, and the efficacy of the treatments was assessed by determining, before and after treatment, the wine content in protein, phenolic compounds, sodium, calcium, and volatile organic compounds (VOCs) as well as the wine pH. DCMC applied at dosages such as those commonly employed for bentonite was able to reduce the protein content in all tested wines and to stabilize all but the Moscatel de Setúbal varietal wine. In general, DCMC was shown to induce lower changes in the wine pH and phenolic content than bentonite, reducing the wine calcium content. Regarding which VOCs are concerned, DCMC produced a general impact similar to that of bentonite, with differences depending on wine variety. The results obtained suggest that DCMC can be a sustainable alternative to bentonite in protein white wine stabilization.https://www.mdpi.com/1420-3049/26/20/6188white wineDCMCbentoniteprotein stabilitywine proteinwine aromatic fraction
spellingShingle Francesco Saracino
João Brinco
Diana Gago
Marco Gomes da Silva
Ricardo Boavida Ferreira
Jorge Ricardo-da-Silva
Ricardo Chagas
Luísa Maria Ferreira
DCMC as a Promising Alternative to Bentonite in White Wine Stabilization. Impact on Protein Stability and Wine Aromatic Fraction
Molecules
white wine
DCMC
bentonite
protein stability
wine protein
wine aromatic fraction
title DCMC as a Promising Alternative to Bentonite in White Wine Stabilization. Impact on Protein Stability and Wine Aromatic Fraction
title_full DCMC as a Promising Alternative to Bentonite in White Wine Stabilization. Impact on Protein Stability and Wine Aromatic Fraction
title_fullStr DCMC as a Promising Alternative to Bentonite in White Wine Stabilization. Impact on Protein Stability and Wine Aromatic Fraction
title_full_unstemmed DCMC as a Promising Alternative to Bentonite in White Wine Stabilization. Impact on Protein Stability and Wine Aromatic Fraction
title_short DCMC as a Promising Alternative to Bentonite in White Wine Stabilization. Impact on Protein Stability and Wine Aromatic Fraction
title_sort dcmc as a promising alternative to bentonite in white wine stabilization impact on protein stability and wine aromatic fraction
topic white wine
DCMC
bentonite
protein stability
wine protein
wine aromatic fraction
url https://www.mdpi.com/1420-3049/26/20/6188
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