Detection of flonicamid insecticide in vegetable samples by UV–Visible spectrophotometer and FTIR
In the present study, the synthesis of 4,4′-((4-dimethylamino)cyclohexane-2,5-vinylidene)methylene))bis-(N, N-dimethylaniline) violet color dye by the hydrolyzed of Flonicamid in basic medium (OH−) followed by bromination and leucocrystal violet, as well as the synthesis of violet crystal by environ...
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| Format: | Article |
| Language: | English |
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Elsevier
2020-01-01
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| Series: | Results in Chemistry |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2211715620300370 |
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| author | Deepak Kumar Sahu Joyce Rai Manish K. Rai Manoj Kumar Banjare Mamta Nirmal Kalpana Wani Reshma Sahu Shraddha G. Pandey Prashant Mundeja |
| author_facet | Deepak Kumar Sahu Joyce Rai Manish K. Rai Manoj Kumar Banjare Mamta Nirmal Kalpana Wani Reshma Sahu Shraddha G. Pandey Prashant Mundeja |
| author_sort | Deepak Kumar Sahu |
| collection | DOAJ |
| description | In the present study, the synthesis of 4,4′-((4-dimethylamino)cyclohexane-2,5-vinylidene)methylene))bis-(N, N-dimethylaniline) violet color dye by the hydrolyzed of Flonicamid in basic medium (OH−) followed by bromination and leucocrystal violet, as well as the synthesis of violet crystal by environmental samples (i.e., cucumber, tomato, bottle gourd, soil, and water). Characterization for the synthesis of violet crystal dye by using UV–Vis spectrophotometer and FTIR methods. As a result, the UV–Vis absorption spectrum was observed at 580 nm. The limit of detection and limit of quantification was observed at 0.007 μg mL−1 and 0.025 μg mL−1 respectively. We have also conformational studied the functional group (such as an NH symmetric band are 1654.85 cm−1, symmetrical stretching CN is 1417.46 cm−1, NH and CN band 1321.34 cm−1, CC stretching is 1035.81 cm−1, a carbonyl group is 785.61 cm−1) involved in the complexation between flonicamid and bromination by FTIR method. This system has been successfully applied for the detection of flonicamid in various environmental sample i.e., cucumber, tomato, bottle gourd, soil, and water. This method advances in simple, selective, and rapid as well as economic for the determination of flonicamid insecticide in vegetable and fruit samples. |
| first_indexed | 2024-12-14T02:09:39Z |
| format | Article |
| id | doaj.art-f1f8ff0922574f3f8ec0d6f162bf5ba5 |
| institution | Directory Open Access Journal |
| issn | 2211-7156 |
| language | English |
| last_indexed | 2024-12-14T02:09:39Z |
| publishDate | 2020-01-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Results in Chemistry |
| spelling | doaj.art-f1f8ff0922574f3f8ec0d6f162bf5ba52022-12-21T23:20:47ZengElsevierResults in Chemistry2211-71562020-01-012100059Detection of flonicamid insecticide in vegetable samples by UV–Visible spectrophotometer and FTIRDeepak Kumar Sahu0Joyce Rai1Manish K. Rai2Manoj Kumar Banjare3Mamta Nirmal4Kalpana Wani5Reshma Sahu6Shraddha G. Pandey7Prashant Mundeja8School of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur, Chhattisgarh 492010, India; Chhattisgarh Council of Science and Technology, Raipur, Chhattisgarh 492014, IndiaChhattisgarh Council of Science and Technology, Raipur, Chhattisgarh 492014, IndiaSchool of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur, Chhattisgarh 492010, India; Corresponding author.School of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur, Chhattisgarh 492010, India; MATS School of Sciences, MATS University, Pagaria Complex, Pandri, Raipur, C.G. 492009, IndiaSchool of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur, Chhattisgarh 492010, IndiaSchool of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur, Chhattisgarh 492010, IndiaSchool of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur, Chhattisgarh 492010, IndiaSchool of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur, Chhattisgarh 492010, IndiaSchool of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur, Chhattisgarh 492010, IndiaIn the present study, the synthesis of 4,4′-((4-dimethylamino)cyclohexane-2,5-vinylidene)methylene))bis-(N, N-dimethylaniline) violet color dye by the hydrolyzed of Flonicamid in basic medium (OH−) followed by bromination and leucocrystal violet, as well as the synthesis of violet crystal by environmental samples (i.e., cucumber, tomato, bottle gourd, soil, and water). Characterization for the synthesis of violet crystal dye by using UV–Vis spectrophotometer and FTIR methods. As a result, the UV–Vis absorption spectrum was observed at 580 nm. The limit of detection and limit of quantification was observed at 0.007 μg mL−1 and 0.025 μg mL−1 respectively. We have also conformational studied the functional group (such as an NH symmetric band are 1654.85 cm−1, symmetrical stretching CN is 1417.46 cm−1, NH and CN band 1321.34 cm−1, CC stretching is 1035.81 cm−1, a carbonyl group is 785.61 cm−1) involved in the complexation between flonicamid and bromination by FTIR method. This system has been successfully applied for the detection of flonicamid in various environmental sample i.e., cucumber, tomato, bottle gourd, soil, and water. This method advances in simple, selective, and rapid as well as economic for the determination of flonicamid insecticide in vegetable and fruit samples.http://www.sciencedirect.com/science/article/pii/S2211715620300370PesticidesFlonicamidInsecticideVegetablesUV–Vis spectrophotometerFTIR |
| spellingShingle | Deepak Kumar Sahu Joyce Rai Manish K. Rai Manoj Kumar Banjare Mamta Nirmal Kalpana Wani Reshma Sahu Shraddha G. Pandey Prashant Mundeja Detection of flonicamid insecticide in vegetable samples by UV–Visible spectrophotometer and FTIR Results in Chemistry Pesticides Flonicamid Insecticide Vegetables UV–Vis spectrophotometer FTIR |
| title | Detection of flonicamid insecticide in vegetable samples by UV–Visible spectrophotometer and FTIR |
| title_full | Detection of flonicamid insecticide in vegetable samples by UV–Visible spectrophotometer and FTIR |
| title_fullStr | Detection of flonicamid insecticide in vegetable samples by UV–Visible spectrophotometer and FTIR |
| title_full_unstemmed | Detection of flonicamid insecticide in vegetable samples by UV–Visible spectrophotometer and FTIR |
| title_short | Detection of flonicamid insecticide in vegetable samples by UV–Visible spectrophotometer and FTIR |
| title_sort | detection of flonicamid insecticide in vegetable samples by uv visible spectrophotometer and ftir |
| topic | Pesticides Flonicamid Insecticide Vegetables UV–Vis spectrophotometer FTIR |
| url | http://www.sciencedirect.com/science/article/pii/S2211715620300370 |
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