Photocatalytic Alkylation of α-(Trifluoromethyl)Styrenes with Potassium Xanthogenates
A protocol for the coupling of potassium xanthogenates with α-(trifluoromethyl)styrenes in the presence of triethyl phosphite is reported. The reaction is carried out under blue light irradiation in the presence of organic photocatalyst 3DPAFIPN. The reaction proceeds via formation of alkyl radicals...
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| Format: | Article |
| Language: | English |
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MDPI AG
2021-12-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/11/12/1555 |
| _version_ | 1797505998830698496 |
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| author | Vyacheslav I. Supranovich Alexander D. Dilman |
| author_facet | Vyacheslav I. Supranovich Alexander D. Dilman |
| author_sort | Vyacheslav I. Supranovich |
| collection | DOAJ |
| description | A protocol for the coupling of potassium xanthogenates with α-(trifluoromethyl)styrenes in the presence of triethyl phosphite is reported. The reaction is carried out under blue light irradiation in the presence of organic photocatalyst 3DPAFIPN. The reaction proceeds via formation of alkyl radicals from readily available xanthogenate salts via oxidative desulfurization and cleavage of the carbon–oxygen bond assisted by triethyl phosphite. |
| first_indexed | 2024-03-10T04:26:21Z |
| format | Article |
| id | doaj.art-f1fc720da8e842d7acf7e9839f8ad481 |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-10T04:26:21Z |
| publishDate | 2021-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-f1fc720da8e842d7acf7e9839f8ad4812023-11-23T07:35:20ZengMDPI AGCatalysts2073-43442021-12-011112155510.3390/catal11121555Photocatalytic Alkylation of α-(Trifluoromethyl)Styrenes with Potassium XanthogenatesVyacheslav I. Supranovich0Alexander D. Dilman1N. D. Zelinsky Institute of Organic Chemistry, Leninsky Prosp. 47, 119991 Moscow, RussiaN. D. Zelinsky Institute of Organic Chemistry, Leninsky Prosp. 47, 119991 Moscow, RussiaA protocol for the coupling of potassium xanthogenates with α-(trifluoromethyl)styrenes in the presence of triethyl phosphite is reported. The reaction is carried out under blue light irradiation in the presence of organic photocatalyst 3DPAFIPN. The reaction proceeds via formation of alkyl radicals from readily available xanthogenate salts via oxidative desulfurization and cleavage of the carbon–oxygen bond assisted by triethyl phosphite.https://www.mdpi.com/2073-4344/11/12/1555radical reactionsxanthogenatesphotocatalysistriethyl phosphite |
| spellingShingle | Vyacheslav I. Supranovich Alexander D. Dilman Photocatalytic Alkylation of α-(Trifluoromethyl)Styrenes with Potassium Xanthogenates Catalysts radical reactions xanthogenates photocatalysis triethyl phosphite |
| title | Photocatalytic Alkylation of α-(Trifluoromethyl)Styrenes with Potassium Xanthogenates |
| title_full | Photocatalytic Alkylation of α-(Trifluoromethyl)Styrenes with Potassium Xanthogenates |
| title_fullStr | Photocatalytic Alkylation of α-(Trifluoromethyl)Styrenes with Potassium Xanthogenates |
| title_full_unstemmed | Photocatalytic Alkylation of α-(Trifluoromethyl)Styrenes with Potassium Xanthogenates |
| title_short | Photocatalytic Alkylation of α-(Trifluoromethyl)Styrenes with Potassium Xanthogenates |
| title_sort | photocatalytic alkylation of α trifluoromethyl styrenes with potassium xanthogenates |
| topic | radical reactions xanthogenates photocatalysis triethyl phosphite |
| url | https://www.mdpi.com/2073-4344/11/12/1555 |
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