Isotopic characteristics of carbon and oxygen within ordovician carbonate paleokarst in the tazhong region and their paleoenvironmental significance

The Tazhong region is a key area for oil and gas exploration and development within the Tarim basin. In this region, development of Ordovician carbonate paleokarsts has been found to be extremely heterogeneous. To investigate the developmental stages of these Ordovician carbonate karsts and their co...

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Main Authors: Qingyu Zhang, Bin Liang, Shaocong Ji, Jingrui Li
Format: Article
Language:English
Published: Frontiers Media S.A. 2023-01-01
Series:Frontiers in Earth Science
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/feart.2022.1047535/full
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author Qingyu Zhang
Qingyu Zhang
Bin Liang
Bin Liang
Shaocong Ji
Shaocong Ji
Jingrui Li
Jingrui Li
author_facet Qingyu Zhang
Qingyu Zhang
Bin Liang
Bin Liang
Shaocong Ji
Shaocong Ji
Jingrui Li
Jingrui Li
author_sort Qingyu Zhang
collection DOAJ
description The Tazhong region is a key area for oil and gas exploration and development within the Tarim basin. In this region, development of Ordovician carbonate paleokarsts has been found to be extremely heterogeneous. To investigate the developmental stages of these Ordovician carbonate karsts and their corresponding paleoenvironmental conditions, oxygen and carbon isotopic characteristics of calcite paleokarst fissure fillings were examined in conjunction with rock-structure analyses. Results show that δ18O (PDB) values tend towards negative values in general, ranging from −3.97% to −12.7% (average value −7.64%), which is indicative of the presence of paleokarstification via dissolution by atmospheric freshwater. Values of δ13C (PDB) span a relatively large range, from 2.48% to −2.13% (average value of 0.23%). This shows that the paleokarst in this area has gone through two stages of supergene and burial diagenesis, and the process of paleokarst is complex. The paleotemperature at which the karst fissure-filling deposits were formed ranged from 6.5 to 47.1°C (average value of 21.8°C), and the salinity of the medium has Z values from 117.48 to 130.24 (average value of 123.94). Four different paleokarsification settings were thus revealed: a marine depositional environment, an atmospheric freshwater karst-filling environment, a shallow-burial paleokarsification environment and a deep-burial high-temperature environment. It has thus been shown that the karst pores, fissures and caves formed by paleokarstification over multiple stages are the main reservoir spaces in this region. This study will serves as a basis for karst reservoir predictions, and exploration and development in this region.
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spelling doaj.art-f24535d6b54441adba8ba905ce6d6d142023-01-06T20:37:09ZengFrontiers Media S.A.Frontiers in Earth Science2296-64632023-01-011010.3389/feart.2022.10475351047535Isotopic characteristics of carbon and oxygen within ordovician carbonate paleokarst in the tazhong region and their paleoenvironmental significanceQingyu Zhang0Qingyu Zhang1Bin Liang2Bin Liang3Shaocong Ji4Shaocong Ji5Jingrui Li6Jingrui Li7Institute of Karst Geology, Chinese Academy of Geological Sciences Karst Dynamics Laboratory, Ministry of Natural Resources, Guilin, ChinaInternational Research Center on Karst Under the Auspices of UNESCO, National Center for International Research on Karst Dynamic System and Global Change, Guilin, ChinaInstitute of Karst Geology, Chinese Academy of Geological Sciences Karst Dynamics Laboratory, Ministry of Natural Resources, Guilin, ChinaInternational Research Center on Karst Under the Auspices of UNESCO, National Center for International Research on Karst Dynamic System and Global Change, Guilin, ChinaInstitute of Karst Geology, Chinese Academy of Geological Sciences Karst Dynamics Laboratory, Ministry of Natural Resources, Guilin, ChinaInternational Research Center on Karst Under the Auspices of UNESCO, National Center for International Research on Karst Dynamic System and Global Change, Guilin, ChinaInstitute of Karst Geology, Chinese Academy of Geological Sciences Karst Dynamics Laboratory, Ministry of Natural Resources, Guilin, ChinaInternational Research Center on Karst Under the Auspices of UNESCO, National Center for International Research on Karst Dynamic System and Global Change, Guilin, ChinaThe Tazhong region is a key area for oil and gas exploration and development within the Tarim basin. In this region, development of Ordovician carbonate paleokarsts has been found to be extremely heterogeneous. To investigate the developmental stages of these Ordovician carbonate karsts and their corresponding paleoenvironmental conditions, oxygen and carbon isotopic characteristics of calcite paleokarst fissure fillings were examined in conjunction with rock-structure analyses. Results show that δ18O (PDB) values tend towards negative values in general, ranging from −3.97% to −12.7% (average value −7.64%), which is indicative of the presence of paleokarstification via dissolution by atmospheric freshwater. Values of δ13C (PDB) span a relatively large range, from 2.48% to −2.13% (average value of 0.23%). This shows that the paleokarst in this area has gone through two stages of supergene and burial diagenesis, and the process of paleokarst is complex. The paleotemperature at which the karst fissure-filling deposits were formed ranged from 6.5 to 47.1°C (average value of 21.8°C), and the salinity of the medium has Z values from 117.48 to 130.24 (average value of 123.94). Four different paleokarsification settings were thus revealed: a marine depositional environment, an atmospheric freshwater karst-filling environment, a shallow-burial paleokarsification environment and a deep-burial high-temperature environment. It has thus been shown that the karst pores, fissures and caves formed by paleokarstification over multiple stages are the main reservoir spaces in this region. This study will serves as a basis for karst reservoir predictions, and exploration and development in this region.https://www.frontiersin.org/articles/10.3389/feart.2022.1047535/fullcarbon-oxygen isotopespaleokarstspaleoenvironmentscarbonatesordoviciantarim basin
spellingShingle Qingyu Zhang
Qingyu Zhang
Bin Liang
Bin Liang
Shaocong Ji
Shaocong Ji
Jingrui Li
Jingrui Li
Isotopic characteristics of carbon and oxygen within ordovician carbonate paleokarst in the tazhong region and their paleoenvironmental significance
Frontiers in Earth Science
carbon-oxygen isotopes
paleokarsts
paleoenvironments
carbonates
ordovician
tarim basin
title Isotopic characteristics of carbon and oxygen within ordovician carbonate paleokarst in the tazhong region and their paleoenvironmental significance
title_full Isotopic characteristics of carbon and oxygen within ordovician carbonate paleokarst in the tazhong region and their paleoenvironmental significance
title_fullStr Isotopic characteristics of carbon and oxygen within ordovician carbonate paleokarst in the tazhong region and their paleoenvironmental significance
title_full_unstemmed Isotopic characteristics of carbon and oxygen within ordovician carbonate paleokarst in the tazhong region and their paleoenvironmental significance
title_short Isotopic characteristics of carbon and oxygen within ordovician carbonate paleokarst in the tazhong region and their paleoenvironmental significance
title_sort isotopic characteristics of carbon and oxygen within ordovician carbonate paleokarst in the tazhong region and their paleoenvironmental significance
topic carbon-oxygen isotopes
paleokarsts
paleoenvironments
carbonates
ordovician
tarim basin
url https://www.frontiersin.org/articles/10.3389/feart.2022.1047535/full
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