Physical and mechanical properties of starch films: the role of the cross-linking mechanism through iodine binding capacity
<p class="BDAbstract">In this study, a better knowledge of the influence of cross-linking mechanism on the mechanical properties of starch films is presented. Thus, waxy starch and cassava starch films, cross-linked with trisodium trimetaphosphate (STMP), were produced and characteri...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Instituto Federal de Educação, Ciência e Tecnologia da Paraíba
2023-07-01
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| Series: | Revista Principia |
| Subjects: | |
| Online Access: | https://periodicos.ifpb.edu.br/index.php/principia/article/view/6430 |
| Summary: | <p class="BDAbstract">In this study, a better knowledge of the influence of cross-linking mechanism on the mechanical properties of starch films is presented. Thus, waxy starch and cassava starch films, cross-linked with trisodium trimetaphosphate (STMP), were produced and characterized concerning their morphology, transport, and mechanical properties. Starch cross-linking was verified by RAMAN spectroscopy and by iodine binding capacity (IBC) values, which were determined by color analysis of digital images. Although cross-linking affects the morphology and crystallinity of the films, it was not observed a relationship between the mechanism of the cross-linking reaction of the starch chain (amylose-amylopectin and amylopectin-amylopectin) and the transport properties. The lower Young Modulus and IBC value and the higher elongation at break observed for cross-linking cassava starch films relative to control and waxy films indicate that cross-linking mechanism influences the mechanical properties of starch films and should be considered to tailor the final properties of packaging and biobased products.</p> |
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| ISSN: | 1517-0306 2447-9187 |