Crystal growth and mechanical properties of porous glass-ceramics derived from waste soda-lime-silica glass and clam shells

New low-cost and high strength porous glass-ceramics have been successfully fabricated in the Na2O–CaO–SiO2 glass system by powder sintering method, using pre-calcined clamshell (CS) and waste soda-lime-silica (SLS) glass as raw materials. The effect of pre-calcined CS content and sintering temperat...

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Bibliographic Details
Main Authors: Noor Aizat Noor Hisham, Mohd Hafiz Mohd Zaid, Dur Iffa Saparuddin, Sidek Hj. Ab Aziz, Farah Diana Muhammad, Sawao Honda, Yuji Iwamoto
Format: Article
Language:English
Published: Elsevier 2020-07-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785420314101
Description
Summary:New low-cost and high strength porous glass-ceramics have been successfully fabricated in the Na2O–CaO–SiO2 glass system by powder sintering method, using pre-calcined clamshell (CS) and waste soda-lime-silica (SLS) glass as raw materials. The effect of pre-calcined CS content and sintering temperature on crystal growth, physical properties, compressive strength and pore structure of foamed glass-ceramic samples were systematically investigated by means of X-ray diffraction (XRD), physical properties test, Brunauer–Emmett–Teller (BET) and field emission scanning electron microscopy (FESEM) micrograph. Besides, the pore-forming mechanism of the glass-ceramic samples was also presented in detail. This study used 3 wt.% of CS contents where the prepared powder was compacted into pellet form prior to sintered at 700–900 °C for 1 h. The minimum density (2.43 g/cm3) with maximum expansion (83.98%) was obtained after sintered at 800 °C. The XRD measurement shows the wollastonite (CaSiO3) crystalline phase has formed at 800 °C and the highest value of mechanical strength (1.21 MPa) with acceptable high total porosity value (58.27%) was obtained after sintered at 900 °C. Besides, the FESEM micrograph has visualized the porous structure of foam glass-ceramics samples sintered at 800 °C has the largest porous structure with closed pore characteristics.
ISSN:2238-7854