Tetrakis(benzylamino)phosphonium chloride
The title salt, [P(NHCH2C6H5)4]+·Cl−, crystallizes with the P atom and Cl− anion lying on a twofold rotation axis. The P atom has a slightly distorted tetrahedral geometry with two classes of N—P—N angles [101.15 (10)...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810054401 |
| _version_ | 1819104929596309504 |
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| author | Khodayar Gholivand Hossein Mostaanzadeh Sedigheh Farshadian |
| author_facet | Khodayar Gholivand Hossein Mostaanzadeh Sedigheh Farshadian |
| author_sort | Khodayar Gholivand |
| collection | DOAJ |
| description | The title salt, [P(NHCH2C6H5)4]+·Cl−, crystallizes with the P atom and Cl− anion lying on a twofold rotation axis. The P atom has a slightly distorted tetrahedral geometry with two classes of N—P—N angles [101.15 (10) and 100.55 (11)° and 113.07 (9) and 114.83 (8)°] and the environments of sp2-hybridized N atoms are essentially planar (sum of angles = 359.9 and 360.1°). In the crystal, the phosphonium ion interacts with each neighboring chloride ion via two approximately equal N—H...Cl interactions, forming parallel chains along the c axis. |
| first_indexed | 2024-12-22T02:14:10Z |
| format | Article |
| id | doaj.art-f29049ba8a87434e8ca86de827503067 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:14:10Z |
| publishDate | 2011-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-f29049ba8a87434e8ca86de8275030672022-12-21T18:42:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-02-01672o311o31110.1107/S1600536810054401Tetrakis(benzylamino)phosphonium chlorideKhodayar GholivandHossein MostaanzadehSedigheh FarshadianThe title salt, [P(NHCH2C6H5)4]+·Cl−, crystallizes with the P atom and Cl− anion lying on a twofold rotation axis. The P atom has a slightly distorted tetrahedral geometry with two classes of N—P—N angles [101.15 (10) and 100.55 (11)° and 113.07 (9) and 114.83 (8)°] and the environments of sp2-hybridized N atoms are essentially planar (sum of angles = 359.9 and 360.1°). In the crystal, the phosphonium ion interacts with each neighboring chloride ion via two approximately equal N—H...Cl interactions, forming parallel chains along the c axis.http://scripts.iucr.org/cgi-bin/paper?S1600536810054401 |
| spellingShingle | Khodayar Gholivand Hossein Mostaanzadeh Sedigheh Farshadian Tetrakis(benzylamino)phosphonium chloride Acta Crystallographica Section E |
| title | Tetrakis(benzylamino)phosphonium chloride |
| title_full | Tetrakis(benzylamino)phosphonium chloride |
| title_fullStr | Tetrakis(benzylamino)phosphonium chloride |
| title_full_unstemmed | Tetrakis(benzylamino)phosphonium chloride |
| title_short | Tetrakis(benzylamino)phosphonium chloride |
| title_sort | tetrakis benzylamino phosphonium chloride |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810054401 |
| work_keys_str_mv | AT khodayargholivand tetrakisbenzylaminophosphoniumchloride AT hosseinmostaanzadeh tetrakisbenzylaminophosphoniumchloride AT sedighehfarshadian tetrakisbenzylaminophosphoniumchloride |