(μ-4-Methylbenzenethiolato-κ2S:S)bis[carbonyl(η5-cyclopentadienyl)molybdenum(II)]
The asymmetric unit of the title compound, [Mo2(C5H5)2(C7H7S)2(CO)2], consists of two half-molecules, each molecule lying on a centre of symmetry. The thiolate groups function as bridges between the MoII atoms, which adopt a quasi-octahedral geometry. In the octahedral environment the two ligating S...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808010751 |
| _version_ | 1818959469860618240 |
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| author | Seik Weng Ng Mei Lee Ooi Richard Chee Seng Wong |
| author_facet | Seik Weng Ng Mei Lee Ooi Richard Chee Seng Wong |
| author_sort | Seik Weng Ng |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Mo2(C5H5)2(C7H7S)2(CO)2], consists of two half-molecules, each molecule lying on a centre of symmetry. The thiolate groups function as bridges between the MoII atoms, which adopt a quasi-octahedral geometry. In the octahedral environment the two ligating S atoms are in a cis arrangement. |
| first_indexed | 2024-12-20T11:42:08Z |
| format | Article |
| id | doaj.art-f290829a6e5a4b49b09844335a4ff3fa |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:42:08Z |
| publishDate | 2008-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-f290829a6e5a4b49b09844335a4ff3fa2022-12-21T19:41:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-05-01645m695m69510.1107/S1600536808010751(μ-4-Methylbenzenethiolato-κ2S:S)bis[carbonyl(η5-cyclopentadienyl)molybdenum(II)]Seik Weng NgMei Lee OoiRichard Chee Seng WongThe asymmetric unit of the title compound, [Mo2(C5H5)2(C7H7S)2(CO)2], consists of two half-molecules, each molecule lying on a centre of symmetry. The thiolate groups function as bridges between the MoII atoms, which adopt a quasi-octahedral geometry. In the octahedral environment the two ligating S atoms are in a cis arrangement.http://scripts.iucr.org/cgi-bin/paper?S1600536808010751 |
| spellingShingle | Seik Weng Ng Mei Lee Ooi Richard Chee Seng Wong (μ-4-Methylbenzenethiolato-κ2S:S)bis[carbonyl(η5-cyclopentadienyl)molybdenum(II)] Acta Crystallographica Section E |
| title | (μ-4-Methylbenzenethiolato-κ2S:S)bis[carbonyl(η5-cyclopentadienyl)molybdenum(II)] |
| title_full | (μ-4-Methylbenzenethiolato-κ2S:S)bis[carbonyl(η5-cyclopentadienyl)molybdenum(II)] |
| title_fullStr | (μ-4-Methylbenzenethiolato-κ2S:S)bis[carbonyl(η5-cyclopentadienyl)molybdenum(II)] |
| title_full_unstemmed | (μ-4-Methylbenzenethiolato-κ2S:S)bis[carbonyl(η5-cyclopentadienyl)molybdenum(II)] |
| title_short | (μ-4-Methylbenzenethiolato-κ2S:S)bis[carbonyl(η5-cyclopentadienyl)molybdenum(II)] |
| title_sort | 956 4 methylbenzenethiolato 954 2s s bis carbonyl 951 5 cyclopentadienyl molybdenum ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808010751 |
| work_keys_str_mv | AT seikwengng 9564methylbenzenethiolato9542ssbiscarbonyl9515cyclopentadienylmolybdenumii AT meileeooi 9564methylbenzenethiolato9542ssbiscarbonyl9515cyclopentadienylmolybdenumii AT richardcheesengwong 9564methylbenzenethiolato9542ssbiscarbonyl9515cyclopentadienylmolybdenumii |