Toward Programmed Complex Stress-Induced Mechanical Deformations of Liquid Crystal Elastomers

We prepare a liquid crystal elastomer (LCE) with a spatially patterned liquid crystal director field from an all-acrylate LCE. Mechanical deformations of this material lead to a complex and spatially varying deformation with localised body rotations, shears and extensions. Together, these dictate th...

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Main Authors: Devesh Mistry, Helen F. Gleeson
Format: Article
Language:English
Published: MDPI AG 2020-04-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/10/4/315
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author Devesh Mistry
Helen F. Gleeson
author_facet Devesh Mistry
Helen F. Gleeson
author_sort Devesh Mistry
collection DOAJ
description We prepare a liquid crystal elastomer (LCE) with a spatially patterned liquid crystal director field from an all-acrylate LCE. Mechanical deformations of this material lead to a complex and spatially varying deformation with localised body rotations, shears and extensions. Together, these dictate the evolved shape of the deformed film. Using polarising microscopy, we map the local rotation of the liquid crystal director in Eulerian and Lagrangian frames and use these to determine rules for programming complex, stress-induced mechanical shape deformations of LCEs. Moreover, by applying a recently developed empirical model for the mechanical behaviour of our LCE, we predict the non-uniform stress distributions in our material. These results show the promise of empirical approaches to modelling the anisotropic and nonlinear mechanical responses of LCEs which will be important as the community moves toward realising real-world, LCE-based devices.
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spelling doaj.art-f2b0beab74aa4bd2a2d9a1c1b2a2c2c92023-11-19T22:02:30ZengMDPI AGCrystals2073-43522020-04-0110431510.3390/cryst10040315Toward Programmed Complex Stress-Induced Mechanical Deformations of Liquid Crystal ElastomersDevesh Mistry0Helen F. Gleeson1School of Physics and Astronomy, University of Leeds, Leeds LS2 9JT, UKSchool of Physics and Astronomy, University of Leeds, Leeds LS2 9JT, UKWe prepare a liquid crystal elastomer (LCE) with a spatially patterned liquid crystal director field from an all-acrylate LCE. Mechanical deformations of this material lead to a complex and spatially varying deformation with localised body rotations, shears and extensions. Together, these dictate the evolved shape of the deformed film. Using polarising microscopy, we map the local rotation of the liquid crystal director in Eulerian and Lagrangian frames and use these to determine rules for programming complex, stress-induced mechanical shape deformations of LCEs. Moreover, by applying a recently developed empirical model for the mechanical behaviour of our LCE, we predict the non-uniform stress distributions in our material. These results show the promise of empirical approaches to modelling the anisotropic and nonlinear mechanical responses of LCEs which will be important as the community moves toward realising real-world, LCE-based devices.https://www.mdpi.com/2073-4352/10/4/315liquid crystal elastomersempirical modelpolymersliquid crystalsmechanical properties
spellingShingle Devesh Mistry
Helen F. Gleeson
Toward Programmed Complex Stress-Induced Mechanical Deformations of Liquid Crystal Elastomers
Crystals
liquid crystal elastomers
empirical model
polymers
liquid crystals
mechanical properties
title Toward Programmed Complex Stress-Induced Mechanical Deformations of Liquid Crystal Elastomers
title_full Toward Programmed Complex Stress-Induced Mechanical Deformations of Liquid Crystal Elastomers
title_fullStr Toward Programmed Complex Stress-Induced Mechanical Deformations of Liquid Crystal Elastomers
title_full_unstemmed Toward Programmed Complex Stress-Induced Mechanical Deformations of Liquid Crystal Elastomers
title_short Toward Programmed Complex Stress-Induced Mechanical Deformations of Liquid Crystal Elastomers
title_sort toward programmed complex stress induced mechanical deformations of liquid crystal elastomers
topic liquid crystal elastomers
empirical model
polymers
liquid crystals
mechanical properties
url https://www.mdpi.com/2073-4352/10/4/315
work_keys_str_mv AT deveshmistry towardprogrammedcomplexstressinducedmechanicaldeformationsofliquidcrystalelastomers
AT helenfgleeson towardprogrammedcomplexstressinducedmechanicaldeformationsofliquidcrystalelastomers