Platinum Assisted Vapor–Liquid–Solid Growth of Er–Si Nanowires and Their Optical Properties

<p>Abstract</p> <p>We report the optical activation of erbium coated silicon nanowires (Er&#8211;SiNWs) grown with the assist of platinum (Pt) and gold (Au), respectively. The NWs were grown on Si substrates by using a chemical vapor transport process using SiCl<sub>4<...

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Main Authors: Shin Jung, Kim Myoung-Ha, Kim Il-Soo, Park Yong-Hee, Park Tae-Eon, Choi Heon-Jin
Format: Article
Language:English
Published: SpringerOpen 2009-01-01
Series:Nanoscale Research Letters
Subjects:
Online Access:http://dx.doi.org/10.1007/s11671-009-9477-5
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author Shin Jung
Kim Myoung-Ha
Kim Il-Soo
Park Yong-Hee
Park Tae-Eon
Choi Heon-Jin
author_facet Shin Jung
Kim Myoung-Ha
Kim Il-Soo
Park Yong-Hee
Park Tae-Eon
Choi Heon-Jin
author_sort Shin Jung
collection DOAJ
description <p>Abstract</p> <p>We report the optical activation of erbium coated silicon nanowires (Er&#8211;SiNWs) grown with the assist of platinum (Pt) and gold (Au), respectively. The NWs were grown on Si substrates by using a chemical vapor transport process using SiCl<sub>4</sub> and ErCl<sub>4</sub> as precursors. Pt as well as Au worked successfully as vapor&#8211;liquid&#8211;solid (VLS) catalysts for growing SiNWs with diameters of ~100 nm and length of several micrometers, respectively. The SiNWs have core&#8211;shell structures where the Er-crystalline layer is sandwiched between silica layers. Photoluminescence spectra analyses showed the optical activity of SiNWs from both Pt and Au. A stronger Er<sup>3+</sup> luminescence of 1,534 nm was observed from the SiNWs with Pt at room- and low-temperature (25 K) using the 488- and/or 477-nm line of an Ar laser that may be due to the uniform incorporation of more Er ions into NWs with the exclusion of the formation of catalyst-induced deep levels in the band-gap. Pt would be used as a VLS catalyst for high performance optically active Er&#8211;SiNWs.</p>
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spelling doaj.art-f2bb4e46575a424887f5bc884c413c202023-08-02T04:53:27ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2009-01-0152286290Platinum Assisted Vapor&#8211;Liquid&#8211;Solid Growth of Er&#8211;Si Nanowires and Their Optical PropertiesShin JungKim Myoung-HaKim Il-SooPark Yong-HeePark Tae-EonChoi Heon-Jin<p>Abstract</p> <p>We report the optical activation of erbium coated silicon nanowires (Er&#8211;SiNWs) grown with the assist of platinum (Pt) and gold (Au), respectively. The NWs were grown on Si substrates by using a chemical vapor transport process using SiCl<sub>4</sub> and ErCl<sub>4</sub> as precursors. Pt as well as Au worked successfully as vapor&#8211;liquid&#8211;solid (VLS) catalysts for growing SiNWs with diameters of ~100 nm and length of several micrometers, respectively. The SiNWs have core&#8211;shell structures where the Er-crystalline layer is sandwiched between silica layers. Photoluminescence spectra analyses showed the optical activity of SiNWs from both Pt and Au. A stronger Er<sup>3+</sup> luminescence of 1,534 nm was observed from the SiNWs with Pt at room- and low-temperature (25 K) using the 488- and/or 477-nm line of an Ar laser that may be due to the uniform incorporation of more Er ions into NWs with the exclusion of the formation of catalyst-induced deep levels in the band-gap. Pt would be used as a VLS catalyst for high performance optically active Er&#8211;SiNWs.</p>http://dx.doi.org/10.1007/s11671-009-9477-5Si nanowiresErbiumLuminescencePlatinum catalyst
spellingShingle Shin Jung
Kim Myoung-Ha
Kim Il-Soo
Park Yong-Hee
Park Tae-Eon
Choi Heon-Jin
Platinum Assisted Vapor&#8211;Liquid&#8211;Solid Growth of Er&#8211;Si Nanowires and Their Optical Properties
Nanoscale Research Letters
Si nanowires
Erbium
Luminescence
Platinum catalyst
title Platinum Assisted Vapor&#8211;Liquid&#8211;Solid Growth of Er&#8211;Si Nanowires and Their Optical Properties
title_full Platinum Assisted Vapor&#8211;Liquid&#8211;Solid Growth of Er&#8211;Si Nanowires and Their Optical Properties
title_fullStr Platinum Assisted Vapor&#8211;Liquid&#8211;Solid Growth of Er&#8211;Si Nanowires and Their Optical Properties
title_full_unstemmed Platinum Assisted Vapor&#8211;Liquid&#8211;Solid Growth of Er&#8211;Si Nanowires and Their Optical Properties
title_short Platinum Assisted Vapor&#8211;Liquid&#8211;Solid Growth of Er&#8211;Si Nanowires and Their Optical Properties
title_sort platinum assisted vapor 8211 liquid 8211 solid growth of er 8211 si nanowires and their optical properties
topic Si nanowires
Erbium
Luminescence
Platinum catalyst
url http://dx.doi.org/10.1007/s11671-009-9477-5
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