Dichloridotriphenylantimony(V)–bis(pyrrolidin-1-ylthiocarbonyl) disulfide (1/1)
The asymmetric unit of the title compound, [Sb(C6H5)3Cl2]·C10H16N2S4, comprises a bis(pyrrolidinylthiocarbamoyl) molecule and a dichlorotriphenylantimony(V) complex. In the Sb complex, the central atom is coordinated by three C atoms of the three phenyl ligands and two Cl atoms in a slightl...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807063830 |
| _version_ | 1818083806345691136 |
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| author | Li Quan Handong Yin Jun Zhai Daqi Wang |
| author_facet | Li Quan Handong Yin Jun Zhai Daqi Wang |
| author_sort | Li Quan |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Sb(C6H5)3Cl2]·C10H16N2S4, comprises a bis(pyrrolidinylthiocarbamoyl) molecule and a dichlorotriphenylantimony(V) complex. In the Sb complex, the central atom is coordinated by three C atoms of the three phenyl ligands and two Cl atoms in a slightly distorted trigonal-bipyramidal geometry. The thiocarbamoyl units, connected via the disulfide bond, are approximately perpendicular to each other. The molecules are connected by weak C—H...S and C—H...Cl hydrogen-bonding interactions into two one-dimensional supramolecular chains. |
| first_indexed | 2024-12-10T19:43:51Z |
| format | Article |
| id | doaj.art-f2da296461994336a12ef9c57cba35ea |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T19:43:51Z |
| publishDate | 2008-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-f2da296461994336a12ef9c57cba35ea2022-12-22T01:35:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m108m10810.1107/S1600536807063830Dichloridotriphenylantimony(V)–bis(pyrrolidin-1-ylthiocarbonyl) disulfide (1/1)Li QuanHandong YinJun ZhaiDaqi WangThe asymmetric unit of the title compound, [Sb(C6H5)3Cl2]·C10H16N2S4, comprises a bis(pyrrolidinylthiocarbamoyl) molecule and a dichlorotriphenylantimony(V) complex. In the Sb complex, the central atom is coordinated by three C atoms of the three phenyl ligands and two Cl atoms in a slightly distorted trigonal-bipyramidal geometry. The thiocarbamoyl units, connected via the disulfide bond, are approximately perpendicular to each other. The molecules are connected by weak C—H...S and C—H...Cl hydrogen-bonding interactions into two one-dimensional supramolecular chains.http://scripts.iucr.org/cgi-bin/paper?S1600536807063830 |
| spellingShingle | Li Quan Handong Yin Jun Zhai Daqi Wang Dichloridotriphenylantimony(V)–bis(pyrrolidin-1-ylthiocarbonyl) disulfide (1/1) Acta Crystallographica Section E |
| title | Dichloridotriphenylantimony(V)–bis(pyrrolidin-1-ylthiocarbonyl) disulfide (1/1) |
| title_full | Dichloridotriphenylantimony(V)–bis(pyrrolidin-1-ylthiocarbonyl) disulfide (1/1) |
| title_fullStr | Dichloridotriphenylantimony(V)–bis(pyrrolidin-1-ylthiocarbonyl) disulfide (1/1) |
| title_full_unstemmed | Dichloridotriphenylantimony(V)–bis(pyrrolidin-1-ylthiocarbonyl) disulfide (1/1) |
| title_short | Dichloridotriphenylantimony(V)–bis(pyrrolidin-1-ylthiocarbonyl) disulfide (1/1) |
| title_sort | dichloridotriphenylantimony v 8211 bis pyrrolidin 1 ylthiocarbonyl disulfide 1 1 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536807063830 |
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