Preparation of Phosphate Coating Solution to Increase the Corrosion Resistance of Carbon Steel in Ambient Conditions

In this work, different zinc phosphating solutions were prepared using sodium phosphate (Na3PO4), sodium nitrate (NaNO3), and nickel carbonate (NiCO3) as accelerators. NaNO3 concentration was ranged from 20 to 80 g/L. While the NiCO3 concentration ranged from 1 to 15 g/L. To identify the interaction...

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Main Authors: Dhafer Fezaa Ali, Abdullah Adnan Abdulkarim, Yosra Mohammed Mahdi, Omar Akram Ahmad
Format: Article
Language:English
Published: Corporation of Research and Industrial Development 2022-12-01
Series:Iraqi Journal of Industrial Research
Subjects:
Online Access:http://ijoir.gov.iq/ijoir/index.php/jou/article/view/281
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author Dhafer Fezaa Ali
Abdullah Adnan Abdulkarim
Yosra Mohammed Mahdi
Omar Akram Ahmad
author_facet Dhafer Fezaa Ali
Abdullah Adnan Abdulkarim
Yosra Mohammed Mahdi
Omar Akram Ahmad
author_sort Dhafer Fezaa Ali
collection DOAJ
description In this work, different zinc phosphating solutions were prepared using sodium phosphate (Na3PO4), sodium nitrate (NaNO3), and nickel carbonate (NiCO3) as accelerators. NaNO3 concentration was ranged from 20 to 80 g/L. While the NiCO3 concentration ranged from 1 to 15 g/L. To identify the interactions between the NaNO3and NiCO3, mixed accelerators were also investigated. Corrosion inspection of the metal surface was tested using potentiostatic experiments. Portable camera microscope was used to capture the surface images of coated samples.  The experimental investigations revealed that the immersion time of 10 min significantly enhanced the corrosion tendency of all accelerators. It was noticed that the corrosion resistance was enhanced with more concentration of NaNO3in the phosphate solution and reached their maximum protection at 80 g/L. While 1 g/L of NiCO3 in solution (which represents the lower value), exhibited higher protection against corrosion. Mixed accelerators resulted in smaller grain size with lower corrosion current (1.83 mA) at 80 g/L and 5 g/L of NaNO3 and NiCO3, respectively. It was also found that chromic acid concentration significantly affected the corrosion resistance.
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spelling doaj.art-f2e0fc8060ad47bf8072f8745528f32d2022-12-22T04:22:56ZengCorporation of Research and Industrial DevelopmentIraqi Journal of Industrial Research2788-712X2022-12-0193727710.53523/ijoirVol9I3ID281281Preparation of Phosphate Coating Solution to Increase the Corrosion Resistance of Carbon Steel in Ambient ConditionsDhafer Fezaa Ali0Abdullah Adnan Abdulkarim1Yosra Mohammed Mahdi2Omar Akram Ahmad3Renewable Energy and Environment Research Center/ Corporation of Research and Industrial Development – IraqIraqi Corrosion Center/ Corporation of Research and Industrial Development – IraqIraqi Corrosion Center/ Corporation of Research and Industrial Development – IraqIraqi Corrosion Center/ Corporation of Research and Industrial Development – IraqIn this work, different zinc phosphating solutions were prepared using sodium phosphate (Na3PO4), sodium nitrate (NaNO3), and nickel carbonate (NiCO3) as accelerators. NaNO3 concentration was ranged from 20 to 80 g/L. While the NiCO3 concentration ranged from 1 to 15 g/L. To identify the interactions between the NaNO3and NiCO3, mixed accelerators were also investigated. Corrosion inspection of the metal surface was tested using potentiostatic experiments. Portable camera microscope was used to capture the surface images of coated samples.  The experimental investigations revealed that the immersion time of 10 min significantly enhanced the corrosion tendency of all accelerators. It was noticed that the corrosion resistance was enhanced with more concentration of NaNO3in the phosphate solution and reached their maximum protection at 80 g/L. While 1 g/L of NiCO3 in solution (which represents the lower value), exhibited higher protection against corrosion. Mixed accelerators resulted in smaller grain size with lower corrosion current (1.83 mA) at 80 g/L and 5 g/L of NaNO3 and NiCO3, respectively. It was also found that chromic acid concentration significantly affected the corrosion resistance.http://ijoir.gov.iq/ijoir/index.php/jou/article/view/281phosphate coatingcorrosionaccelerators
spellingShingle Dhafer Fezaa Ali
Abdullah Adnan Abdulkarim
Yosra Mohammed Mahdi
Omar Akram Ahmad
Preparation of Phosphate Coating Solution to Increase the Corrosion Resistance of Carbon Steel in Ambient Conditions
Iraqi Journal of Industrial Research
phosphate coating
corrosion
accelerators
title Preparation of Phosphate Coating Solution to Increase the Corrosion Resistance of Carbon Steel in Ambient Conditions
title_full Preparation of Phosphate Coating Solution to Increase the Corrosion Resistance of Carbon Steel in Ambient Conditions
title_fullStr Preparation of Phosphate Coating Solution to Increase the Corrosion Resistance of Carbon Steel in Ambient Conditions
title_full_unstemmed Preparation of Phosphate Coating Solution to Increase the Corrosion Resistance of Carbon Steel in Ambient Conditions
title_short Preparation of Phosphate Coating Solution to Increase the Corrosion Resistance of Carbon Steel in Ambient Conditions
title_sort preparation of phosphate coating solution to increase the corrosion resistance of carbon steel in ambient conditions
topic phosphate coating
corrosion
accelerators
url http://ijoir.gov.iq/ijoir/index.php/jou/article/view/281
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AT abdullahadnanabdulkarim preparationofphosphatecoatingsolutiontoincreasethecorrosionresistanceofcarbonsteelinambientconditions
AT yosramohammedmahdi preparationofphosphatecoatingsolutiontoincreasethecorrosionresistanceofcarbonsteelinambientconditions
AT omarakramahmad preparationofphosphatecoatingsolutiontoincreasethecorrosionresistanceofcarbonsteelinambientconditions