High Power Factor vs. High <i>zT</i>—A Review of Thermoelectric Materials for High-Temperature Application

Energy harvesting with thermoelectric materials has been investigated with increasing attention over recent decades. However, the vast number of various material classes makes it difficult to maintain an overview of the best candidates. Thus, we revitalize Ioffe plots as a useful tool for making the...

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Main Authors: Mario Wolf, Richard Hinterding, Armin Feldhoff
Format: Article
Language:English
Published: MDPI AG 2019-10-01
Series:Entropy
Subjects:
Online Access:https://www.mdpi.com/1099-4300/21/11/1058
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author Mario Wolf
Richard Hinterding
Armin Feldhoff
author_facet Mario Wolf
Richard Hinterding
Armin Feldhoff
author_sort Mario Wolf
collection DOAJ
description Energy harvesting with thermoelectric materials has been investigated with increasing attention over recent decades. However, the vast number of various material classes makes it difficult to maintain an overview of the best candidates. Thus, we revitalize Ioffe plots as a useful tool for making the thermoelectric properties of a material obvious and easily comparable. These plots enable us to consider not only the efficiency of the material by the figure of merit <i>zT</i> but also the power factor and entropy conductivity as separate parameters. This is especially important for high-temperature applications, where a critical look at the impact of the power factor and thermal conductivity is mandatory. Thus, this review focuses on material classes for high-temperature applications and emphasizes the best candidates within the material classes of oxides, oxyselenides, Zintl phases, half-Heusler compounds, and SiGe alloys. An overall comparison between these material classes with respect to either a high efficiency or a high power output is discussed.
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spelling doaj.art-f2ec54309e9d48029d664070aab11d8c2022-12-22T03:09:54ZengMDPI AGEntropy1099-43002019-10-012111105810.3390/e21111058e21111058High Power Factor vs. High <i>zT</i>—A Review of Thermoelectric Materials for High-Temperature ApplicationMario Wolf0Richard Hinterding1Armin Feldhoff2Institute of Physical Chemistry and Electrochemistry, Leibniz University Hannover, Callinstraße 3A, D-30167 Hannover, GermanyInstitute of Physical Chemistry and Electrochemistry, Leibniz University Hannover, Callinstraße 3A, D-30167 Hannover, GermanyInstitute of Physical Chemistry and Electrochemistry, Leibniz University Hannover, Callinstraße 3A, D-30167 Hannover, GermanyEnergy harvesting with thermoelectric materials has been investigated with increasing attention over recent decades. However, the vast number of various material classes makes it difficult to maintain an overview of the best candidates. Thus, we revitalize Ioffe plots as a useful tool for making the thermoelectric properties of a material obvious and easily comparable. These plots enable us to consider not only the efficiency of the material by the figure of merit <i>zT</i> but also the power factor and entropy conductivity as separate parameters. This is especially important for high-temperature applications, where a critical look at the impact of the power factor and thermal conductivity is mandatory. Thus, this review focuses on material classes for high-temperature applications and emphasizes the best candidates within the material classes of oxides, oxyselenides, Zintl phases, half-Heusler compounds, and SiGe alloys. An overall comparison between these material classes with respect to either a high efficiency or a high power output is discussed.https://www.mdpi.com/1099-4300/21/11/1058thermoelectric materialsenergy harvestingenergy materials
spellingShingle Mario Wolf
Richard Hinterding
Armin Feldhoff
High Power Factor vs. High <i>zT</i>—A Review of Thermoelectric Materials for High-Temperature Application
Entropy
thermoelectric materials
energy harvesting
energy materials
title High Power Factor vs. High <i>zT</i>—A Review of Thermoelectric Materials for High-Temperature Application
title_full High Power Factor vs. High <i>zT</i>—A Review of Thermoelectric Materials for High-Temperature Application
title_fullStr High Power Factor vs. High <i>zT</i>—A Review of Thermoelectric Materials for High-Temperature Application
title_full_unstemmed High Power Factor vs. High <i>zT</i>—A Review of Thermoelectric Materials for High-Temperature Application
title_short High Power Factor vs. High <i>zT</i>—A Review of Thermoelectric Materials for High-Temperature Application
title_sort high power factor vs high i zt i a review of thermoelectric materials for high temperature application
topic thermoelectric materials
energy harvesting
energy materials
url https://www.mdpi.com/1099-4300/21/11/1058
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AT arminfeldhoff highpowerfactorvshighiztiareviewofthermoelectricmaterialsforhightemperatureapplication