Solution-Processed Large-Area Organic/Inorganic Hybrid Antireflective Films for Perovskite Solar Cell

In recent years, organic/inorganic hybrid materials have attracted much attention in the field of multilayer antireflection films because of their excellent optical properties. In this paper, the organic/inorganic nanocomposite was prepared from polyvinyl alcohol (PVA) and titanium (IV) isopropoxide...

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Main Authors: Mingfang Huo, Yun Hu, Qin Xue, Jingsong Huang, Guohua Xie
Format: Article
Language:English
Published: MDPI AG 2023-02-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/28/5/2145
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author Mingfang Huo
Yun Hu
Qin Xue
Jingsong Huang
Guohua Xie
author_facet Mingfang Huo
Yun Hu
Qin Xue
Jingsong Huang
Guohua Xie
author_sort Mingfang Huo
collection DOAJ
description In recent years, organic/inorganic hybrid materials have attracted much attention in the field of multilayer antireflection films because of their excellent optical properties. In this paper, the organic/inorganic nanocomposite was prepared from polyvinyl alcohol (PVA) and titanium (IV) isopropoxide (TTIP). The hybrid material has a wide, tunable window of refractive index, i.e., 1.65–1.95, at a wavelength of 550 nm. The atomic force microscope (AFM) results of the hybrid films show the lowest root-mean-square surface roughness of 2.7 Å and a low haze of 0.23%, indicating that the films have good potential for optical applications. The double-sided antireflection films (10 × 10 cm<sup>2</sup>) with one side of hybrid nanocomposite/cellulose acetate and the other side of hybrid nanocomposite /polymethyl methacrylate (PMMA) achieved high transmittances of 98% and 99.3%, respectively. After 240 days of aging testing, the hybrid solution and the antireflective film remained stable with almost no attenuation. Furthermore, the application of the antireflection films in perovskite solar cell modules increased the power conversion efficiency from 16.57% to 17.25%.
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spelling doaj.art-f2f8ddc0f16c4974b6fb89b497bf54912023-11-17T08:12:37ZengMDPI AGMolecules1420-30492023-02-01285214510.3390/molecules28052145Solution-Processed Large-Area Organic/Inorganic Hybrid Antireflective Films for Perovskite Solar CellMingfang Huo0Yun Hu1Qin Xue2Jingsong Huang3Guohua Xie4Department of Physical Science and Technology, Central China Normal University, Wuhan 430079, ChinaOxford Suzhou Centre for Advanced Research (OSCAR), University of Oxford, Suzhou 215123, ChinaDepartment of Physical Science and Technology, Central China Normal University, Wuhan 430079, ChinaOxford Suzhou Centre for Advanced Research (OSCAR), University of Oxford, Suzhou 215123, ChinaThe Institute of Flexible Electronics (Future Technologies), Xiamen University, Xiamen 361005, ChinaIn recent years, organic/inorganic hybrid materials have attracted much attention in the field of multilayer antireflection films because of their excellent optical properties. In this paper, the organic/inorganic nanocomposite was prepared from polyvinyl alcohol (PVA) and titanium (IV) isopropoxide (TTIP). The hybrid material has a wide, tunable window of refractive index, i.e., 1.65–1.95, at a wavelength of 550 nm. The atomic force microscope (AFM) results of the hybrid films show the lowest root-mean-square surface roughness of 2.7 Å and a low haze of 0.23%, indicating that the films have good potential for optical applications. The double-sided antireflection films (10 × 10 cm<sup>2</sup>) with one side of hybrid nanocomposite/cellulose acetate and the other side of hybrid nanocomposite /polymethyl methacrylate (PMMA) achieved high transmittances of 98% and 99.3%, respectively. After 240 days of aging testing, the hybrid solution and the antireflective film remained stable with almost no attenuation. Furthermore, the application of the antireflection films in perovskite solar cell modules increased the power conversion efficiency from 16.57% to 17.25%.https://www.mdpi.com/1420-3049/28/5/2145antireflection filmorganic/inorganic hybrid materialadjustable refractive index
spellingShingle Mingfang Huo
Yun Hu
Qin Xue
Jingsong Huang
Guohua Xie
Solution-Processed Large-Area Organic/Inorganic Hybrid Antireflective Films for Perovskite Solar Cell
Molecules
antireflection film
organic/inorganic hybrid material
adjustable refractive index
title Solution-Processed Large-Area Organic/Inorganic Hybrid Antireflective Films for Perovskite Solar Cell
title_full Solution-Processed Large-Area Organic/Inorganic Hybrid Antireflective Films for Perovskite Solar Cell
title_fullStr Solution-Processed Large-Area Organic/Inorganic Hybrid Antireflective Films for Perovskite Solar Cell
title_full_unstemmed Solution-Processed Large-Area Organic/Inorganic Hybrid Antireflective Films for Perovskite Solar Cell
title_short Solution-Processed Large-Area Organic/Inorganic Hybrid Antireflective Films for Perovskite Solar Cell
title_sort solution processed large area organic inorganic hybrid antireflective films for perovskite solar cell
topic antireflection film
organic/inorganic hybrid material
adjustable refractive index
url https://www.mdpi.com/1420-3049/28/5/2145
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AT yunhu solutionprocessedlargeareaorganicinorganichybridantireflectivefilmsforperovskitesolarcell
AT qinxue solutionprocessedlargeareaorganicinorganichybridantireflectivefilmsforperovskitesolarcell
AT jingsonghuang solutionprocessedlargeareaorganicinorganichybridantireflectivefilmsforperovskitesolarcell
AT guohuaxie solutionprocessedlargeareaorganicinorganichybridantireflectivefilmsforperovskitesolarcell