Characterization of activated carbon from waste tea (Camellia sinensis) using chemical activation for removal of methylene blue and cadmium ions

The activated carbon based on waste tea (WT-AC) was prepared using sulfuric acid as an activating agent at different concentrations (5%, 10%, 20%, and 30%). Suitable characteristics as adsorbent have revealed concentration at 30% of waste tea activated carbon (WT-AC4) yield better adsorption, whereb...

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Main Authors: Mohd Affandy Aqilah Mariah, Kobun Rovina, Joseph Merillyn Vonnie, Kana Husna Erna
Format: Article
Language:English
Published: Elsevier 2023-04-01
Series:South African Journal of Chemical Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1026918523000082
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author Mohd Affandy Aqilah Mariah
Kobun Rovina
Joseph Merillyn Vonnie
Kana Husna Erna
author_facet Mohd Affandy Aqilah Mariah
Kobun Rovina
Joseph Merillyn Vonnie
Kana Husna Erna
author_sort Mohd Affandy Aqilah Mariah
collection DOAJ
description The activated carbon based on waste tea (WT-AC) was prepared using sulfuric acid as an activating agent at different concentrations (5%, 10%, 20%, and 30%). Suitable characteristics as adsorbent have revealed concentration at 30% of waste tea activated carbon (WT-AC4) yield better adsorption, whereby other parameters including bulk density, ash content, volatile matter content, and moisture content obtained are 0.301 g mL−1, 3.40%, 26.76%, and 4.34%, sequentially. Overall, WT-AC samples have shown a well-developed porous structure and are declared an amorphous region. Comparatively, the results of adsorption studies reveal iodine value of WT-AC4 is 593.41 mg g−1 and commercial activated carbon is 738.62 mg g−1, while in 100 mg L−1 of methylene blue, the percentage of removal along with adsorption capacity yield the value of 89.2% (1.78 mg g−1) and 97.6 (1.98 mg g−1), respectively. In 0.5 mg L−1 and 1.0 mg L−1 of cadmium ions, WT-AC4 achieved 100% removal in both concentrations compared to commercially activated carbon with only 88.9%, then dropped to 46.2%. Significantly, the activated carbon from waste tea at a concentration of 30% sulfuric acid could be used as a low-cost adsorbent to remove organic and inorganic pollutants.
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spelling doaj.art-f2f8e7ef706840188c40ce7298a4201a2023-02-09T04:13:44ZengElsevierSouth African Journal of Chemical Engineering1026-91852023-04-0144113122Characterization of activated carbon from waste tea (Camellia sinensis) using chemical activation for removal of methylene blue and cadmium ionsMohd Affandy Aqilah Mariah0Kobun Rovina1Joseph Merillyn Vonnie2Kana Husna Erna3Faculty of Food Science and Nutrition, Universiti Malaysia Sabah, Jalan UMS, Kota Kinabalu, Sabah, 88400, MalaysiaCorresponding author.; Faculty of Food Science and Nutrition, Universiti Malaysia Sabah, Jalan UMS, Kota Kinabalu, Sabah, 88400, MalaysiaFaculty of Food Science and Nutrition, Universiti Malaysia Sabah, Jalan UMS, Kota Kinabalu, Sabah, 88400, MalaysiaFaculty of Food Science and Nutrition, Universiti Malaysia Sabah, Jalan UMS, Kota Kinabalu, Sabah, 88400, MalaysiaThe activated carbon based on waste tea (WT-AC) was prepared using sulfuric acid as an activating agent at different concentrations (5%, 10%, 20%, and 30%). Suitable characteristics as adsorbent have revealed concentration at 30% of waste tea activated carbon (WT-AC4) yield better adsorption, whereby other parameters including bulk density, ash content, volatile matter content, and moisture content obtained are 0.301 g mL−1, 3.40%, 26.76%, and 4.34%, sequentially. Overall, WT-AC samples have shown a well-developed porous structure and are declared an amorphous region. Comparatively, the results of adsorption studies reveal iodine value of WT-AC4 is 593.41 mg g−1 and commercial activated carbon is 738.62 mg g−1, while in 100 mg L−1 of methylene blue, the percentage of removal along with adsorption capacity yield the value of 89.2% (1.78 mg g−1) and 97.6 (1.98 mg g−1), respectively. In 0.5 mg L−1 and 1.0 mg L−1 of cadmium ions, WT-AC4 achieved 100% removal in both concentrations compared to commercially activated carbon with only 88.9%, then dropped to 46.2%. Significantly, the activated carbon from waste tea at a concentration of 30% sulfuric acid could be used as a low-cost adsorbent to remove organic and inorganic pollutants.http://www.sciencedirect.com/science/article/pii/S1026918523000082AdsorptionBiomassHeavy metalsDyeChemical activation
spellingShingle Mohd Affandy Aqilah Mariah
Kobun Rovina
Joseph Merillyn Vonnie
Kana Husna Erna
Characterization of activated carbon from waste tea (Camellia sinensis) using chemical activation for removal of methylene blue and cadmium ions
South African Journal of Chemical Engineering
Adsorption
Biomass
Heavy metals
Dye
Chemical activation
title Characterization of activated carbon from waste tea (Camellia sinensis) using chemical activation for removal of methylene blue and cadmium ions
title_full Characterization of activated carbon from waste tea (Camellia sinensis) using chemical activation for removal of methylene blue and cadmium ions
title_fullStr Characterization of activated carbon from waste tea (Camellia sinensis) using chemical activation for removal of methylene blue and cadmium ions
title_full_unstemmed Characterization of activated carbon from waste tea (Camellia sinensis) using chemical activation for removal of methylene blue and cadmium ions
title_short Characterization of activated carbon from waste tea (Camellia sinensis) using chemical activation for removal of methylene blue and cadmium ions
title_sort characterization of activated carbon from waste tea camellia sinensis using chemical activation for removal of methylene blue and cadmium ions
topic Adsorption
Biomass
Heavy metals
Dye
Chemical activation
url http://www.sciencedirect.com/science/article/pii/S1026918523000082
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AT kobunrovina characterizationofactivatedcarbonfromwasteteacamelliasinensisusingchemicalactivationforremovalofmethyleneblueandcadmiumions
AT josephmerillynvonnie characterizationofactivatedcarbonfromwasteteacamelliasinensisusingchemicalactivationforremovalofmethyleneblueandcadmiumions
AT kanahusnaerna characterizationofactivatedcarbonfromwasteteacamelliasinensisusingchemicalactivationforremovalofmethyleneblueandcadmiumions