Flexible and high performance of n-type thermoelectric PVDF composite film induced by nickel nanowires
Nickel nanowires (Ni NW) with high aspect ratio and excellent electrical conductivity were prepared by liquid phase chemical reduction. Polyvinylidene fluoride (PVDF)/Ni NW composite films were fabricated by solution mixing casting and compression molding. The effects of Ni NW with different weight...
Main Authors: | , , , , , , , |
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Format: | Article |
Language: | English |
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Elsevier
2020-03-01
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Series: | Materials & Design |
Online Access: | http://www.sciencedirect.com/science/article/pii/S0264127520300290 |
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author | Sunjie Hu Shuiping Zeng Xiping Li Jiacheng Jiang Wenjie Yang Yuntao Chen Mengjia Li Jiajia Zheng |
author_facet | Sunjie Hu Shuiping Zeng Xiping Li Jiacheng Jiang Wenjie Yang Yuntao Chen Mengjia Li Jiajia Zheng |
author_sort | Sunjie Hu |
collection | DOAJ |
description | Nickel nanowires (Ni NW) with high aspect ratio and excellent electrical conductivity were prepared by liquid phase chemical reduction. Polyvinylidene fluoride (PVDF)/Ni NW composite films were fabricated by solution mixing casting and compression molding. The effects of Ni NW with different weight content on the morphology, crystal structure and thermoelectric properties of PVDF/Ni NW nanocomposites were studied. The results show that the nickel nanowires are uniformly dispersed in the PVDF matrix. With the increase of Ni NW content, the conductivity of the composites increases greatly, and the power factor of the composites increases to 24.3μWm−1 K−2 with 75 wt% Ni NW. Although the tensile strength and elongation of the composites decrease gradually, this flexible thermoelectric film still shows great potential for thermoelectric applications. Keywords: Flexible film, Nickel nanowires, PVDF, Power factor |
first_indexed | 2024-12-21T12:00:15Z |
format | Article |
id | doaj.art-f2fc59c9b28a43dc8db1ff0870ca76d7 |
institution | Directory Open Access Journal |
issn | 0264-1275 |
language | English |
last_indexed | 2024-12-21T12:00:15Z |
publishDate | 2020-03-01 |
publisher | Elsevier |
record_format | Article |
series | Materials & Design |
spelling | doaj.art-f2fc59c9b28a43dc8db1ff0870ca76d72022-12-21T19:04:50ZengElsevierMaterials & Design0264-12752020-03-01188Flexible and high performance of n-type thermoelectric PVDF composite film induced by nickel nanowiresSunjie Hu0Shuiping Zeng1Xiping Li2Jiacheng Jiang3Wenjie Yang4Yuntao Chen5Mengjia Li6Jiajia Zheng7Key Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, Zhejiang Normal University, Jinhua 321004, PR ChinaKey Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, Zhejiang Normal University, Jinhua 321004, PR ChinaCorresponding authors.; Key Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, Zhejiang Normal University, Jinhua 321004, PR ChinaKey Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, Zhejiang Normal University, Jinhua 321004, PR ChinaKey Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, Zhejiang Normal University, Jinhua 321004, PR ChinaKey Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, Zhejiang Normal University, Jinhua 321004, PR ChinaKey Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, Zhejiang Normal University, Jinhua 321004, PR ChinaCorresponding authors.; Key Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, Zhejiang Normal University, Jinhua 321004, PR ChinaNickel nanowires (Ni NW) with high aspect ratio and excellent electrical conductivity were prepared by liquid phase chemical reduction. Polyvinylidene fluoride (PVDF)/Ni NW composite films were fabricated by solution mixing casting and compression molding. The effects of Ni NW with different weight content on the morphology, crystal structure and thermoelectric properties of PVDF/Ni NW nanocomposites were studied. The results show that the nickel nanowires are uniformly dispersed in the PVDF matrix. With the increase of Ni NW content, the conductivity of the composites increases greatly, and the power factor of the composites increases to 24.3μWm−1 K−2 with 75 wt% Ni NW. Although the tensile strength and elongation of the composites decrease gradually, this flexible thermoelectric film still shows great potential for thermoelectric applications. Keywords: Flexible film, Nickel nanowires, PVDF, Power factorhttp://www.sciencedirect.com/science/article/pii/S0264127520300290 |
spellingShingle | Sunjie Hu Shuiping Zeng Xiping Li Jiacheng Jiang Wenjie Yang Yuntao Chen Mengjia Li Jiajia Zheng Flexible and high performance of n-type thermoelectric PVDF composite film induced by nickel nanowires Materials & Design |
title | Flexible and high performance of n-type thermoelectric PVDF composite film induced by nickel nanowires |
title_full | Flexible and high performance of n-type thermoelectric PVDF composite film induced by nickel nanowires |
title_fullStr | Flexible and high performance of n-type thermoelectric PVDF composite film induced by nickel nanowires |
title_full_unstemmed | Flexible and high performance of n-type thermoelectric PVDF composite film induced by nickel nanowires |
title_short | Flexible and high performance of n-type thermoelectric PVDF composite film induced by nickel nanowires |
title_sort | flexible and high performance of n type thermoelectric pvdf composite film induced by nickel nanowires |
url | http://www.sciencedirect.com/science/article/pii/S0264127520300290 |
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