Flexible and high performance of n-type thermoelectric PVDF composite film induced by nickel nanowires

Nickel nanowires (Ni NW) with high aspect ratio and excellent electrical conductivity were prepared by liquid phase chemical reduction. Polyvinylidene fluoride (PVDF)/Ni NW composite films were fabricated by solution mixing casting and compression molding. The effects of Ni NW with different weight...

Full description

Bibliographic Details
Main Authors: Sunjie Hu, Shuiping Zeng, Xiping Li, Jiacheng Jiang, Wenjie Yang, Yuntao Chen, Mengjia Li, Jiajia Zheng
Format: Article
Language:English
Published: Elsevier 2020-03-01
Series:Materials & Design
Online Access:http://www.sciencedirect.com/science/article/pii/S0264127520300290
_version_ 1819051206144688128
author Sunjie Hu
Shuiping Zeng
Xiping Li
Jiacheng Jiang
Wenjie Yang
Yuntao Chen
Mengjia Li
Jiajia Zheng
author_facet Sunjie Hu
Shuiping Zeng
Xiping Li
Jiacheng Jiang
Wenjie Yang
Yuntao Chen
Mengjia Li
Jiajia Zheng
author_sort Sunjie Hu
collection DOAJ
description Nickel nanowires (Ni NW) with high aspect ratio and excellent electrical conductivity were prepared by liquid phase chemical reduction. Polyvinylidene fluoride (PVDF)/Ni NW composite films were fabricated by solution mixing casting and compression molding. The effects of Ni NW with different weight content on the morphology, crystal structure and thermoelectric properties of PVDF/Ni NW nanocomposites were studied. The results show that the nickel nanowires are uniformly dispersed in the PVDF matrix. With the increase of Ni NW content, the conductivity of the composites increases greatly, and the power factor of the composites increases to 24.3μWm−1 K−2 with 75 wt% Ni NW. Although the tensile strength and elongation of the composites decrease gradually, this flexible thermoelectric film still shows great potential for thermoelectric applications. Keywords: Flexible film, Nickel nanowires, PVDF, Power factor
first_indexed 2024-12-21T12:00:15Z
format Article
id doaj.art-f2fc59c9b28a43dc8db1ff0870ca76d7
institution Directory Open Access Journal
issn 0264-1275
language English
last_indexed 2024-12-21T12:00:15Z
publishDate 2020-03-01
publisher Elsevier
record_format Article
series Materials & Design
spelling doaj.art-f2fc59c9b28a43dc8db1ff0870ca76d72022-12-21T19:04:50ZengElsevierMaterials & Design0264-12752020-03-01188Flexible and high performance of n-type thermoelectric PVDF composite film induced by nickel nanowiresSunjie Hu0Shuiping Zeng1Xiping Li2Jiacheng Jiang3Wenjie Yang4Yuntao Chen5Mengjia Li6Jiajia Zheng7Key Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, Zhejiang Normal University, Jinhua 321004, PR ChinaKey Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, Zhejiang Normal University, Jinhua 321004, PR ChinaCorresponding authors.; Key Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, Zhejiang Normal University, Jinhua 321004, PR ChinaKey Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, Zhejiang Normal University, Jinhua 321004, PR ChinaKey Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, Zhejiang Normal University, Jinhua 321004, PR ChinaKey Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, Zhejiang Normal University, Jinhua 321004, PR ChinaKey Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, Zhejiang Normal University, Jinhua 321004, PR ChinaCorresponding authors.; Key Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, Zhejiang Normal University, Jinhua 321004, PR ChinaNickel nanowires (Ni NW) with high aspect ratio and excellent electrical conductivity were prepared by liquid phase chemical reduction. Polyvinylidene fluoride (PVDF)/Ni NW composite films were fabricated by solution mixing casting and compression molding. The effects of Ni NW with different weight content on the morphology, crystal structure and thermoelectric properties of PVDF/Ni NW nanocomposites were studied. The results show that the nickel nanowires are uniformly dispersed in the PVDF matrix. With the increase of Ni NW content, the conductivity of the composites increases greatly, and the power factor of the composites increases to 24.3μWm−1 K−2 with 75 wt% Ni NW. Although the tensile strength and elongation of the composites decrease gradually, this flexible thermoelectric film still shows great potential for thermoelectric applications. Keywords: Flexible film, Nickel nanowires, PVDF, Power factorhttp://www.sciencedirect.com/science/article/pii/S0264127520300290
spellingShingle Sunjie Hu
Shuiping Zeng
Xiping Li
Jiacheng Jiang
Wenjie Yang
Yuntao Chen
Mengjia Li
Jiajia Zheng
Flexible and high performance of n-type thermoelectric PVDF composite film induced by nickel nanowires
Materials & Design
title Flexible and high performance of n-type thermoelectric PVDF composite film induced by nickel nanowires
title_full Flexible and high performance of n-type thermoelectric PVDF composite film induced by nickel nanowires
title_fullStr Flexible and high performance of n-type thermoelectric PVDF composite film induced by nickel nanowires
title_full_unstemmed Flexible and high performance of n-type thermoelectric PVDF composite film induced by nickel nanowires
title_short Flexible and high performance of n-type thermoelectric PVDF composite film induced by nickel nanowires
title_sort flexible and high performance of n type thermoelectric pvdf composite film induced by nickel nanowires
url http://www.sciencedirect.com/science/article/pii/S0264127520300290
work_keys_str_mv AT sunjiehu flexibleandhighperformanceofntypethermoelectricpvdfcompositefilminducedbynickelnanowires
AT shuipingzeng flexibleandhighperformanceofntypethermoelectricpvdfcompositefilminducedbynickelnanowires
AT xipingli flexibleandhighperformanceofntypethermoelectricpvdfcompositefilminducedbynickelnanowires
AT jiachengjiang flexibleandhighperformanceofntypethermoelectricpvdfcompositefilminducedbynickelnanowires
AT wenjieyang flexibleandhighperformanceofntypethermoelectricpvdfcompositefilminducedbynickelnanowires
AT yuntaochen flexibleandhighperformanceofntypethermoelectricpvdfcompositefilminducedbynickelnanowires
AT mengjiali flexibleandhighperformanceofntypethermoelectricpvdfcompositefilminducedbynickelnanowires
AT jiajiazheng flexibleandhighperformanceofntypethermoelectricpvdfcompositefilminducedbynickelnanowires