Benzyltris[2-(dibenzylamino)ethyl]ammonium iodide
In the title quaternary ammonium salt, C55H61N4+·I−, all three N,N-dibenzylethanamine, –(CH2)2N(CH2C6H5)2, groups have different conformations. The N—C—C—N torsion angles are significantly different [89.86 (13), 162.61 (10) and 175.70 (10)°] and the dihedral angles between the phenyl rings in these...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2014-01-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813031607 |
Summary: | In the title quaternary ammonium salt, C55H61N4+·I−, all three N,N-dibenzylethanamine, –(CH2)2N(CH2C6H5)2, groups have different conformations. The N—C—C—N torsion angles are significantly different [89.86 (13), 162.61 (10) and 175.70 (10)°] and the dihedral angles between the phenyl rings in these groups are different as well [58.21 (4), 43.73 (4) and 76.72 (5)°]. In the crystal, the I− anions fill empty spaces between the bulky cations. The cations and anions are linked by weak C—H...I interactions, forming a chain along [110]. |
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ISSN: | 1600-5368 |