NEW SOLVATOMORPH OF TETRAKIS(μ2-ACETATO-O,O')-BIS(ISONICOTINAMIDE-N)-DI-COPPER(II): SYNTHESIS, IR, TGA AND X-RAY STUDY
Dinucleartetracarboxylato-bridged copper(II)solvato-morph [Cu2(OAc)4(ina)2] •2dmso was prepared and studied by IR spectroscopy, TGA analysis and single crystal X-ray method. Cu(II) ions are bridged by four syn,syn-η1:η1:μ carboxylates, showing a paddle-wheel cage-type with a square-pyramidal geometr...
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| Format: | Article |
| Language: | English |
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Academy of Sciences of Moldova, Institute of Chemistry
2015-12-01
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| Series: | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
| Subjects: | |
| Online Access: | http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold201510(2)_33-39_Croitor.pdf |
| _version_ | 1818915611013545984 |
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| author | Diana Chisca Eduard Coropceanu Oleg Petuhov Lilia Croitor |
| author_facet | Diana Chisca Eduard Coropceanu Oleg Petuhov Lilia Croitor |
| author_sort | Diana Chisca |
| collection | DOAJ |
| description | Dinucleartetracarboxylato-bridged copper(II)solvato-morph [Cu2(OAc)4(ina)2] •2dmso was prepared and studied by IR spectroscopy, TGA analysis and single crystal X-ray method. Cu(II) ions are bridged by four syn,syn-η1:η1:μ carboxylates, showing a paddle-wheel cage-type with a square-pyramidal geometry. |
| first_indexed | 2024-12-20T00:05:01Z |
| format | Article |
| id | doaj.art-f31ef4d47ebd4176acc5dadc725439f2 |
| institution | Directory Open Access Journal |
| issn | 1857-1727 2345-1688 |
| language | English |
| last_indexed | 2024-12-20T00:05:01Z |
| publishDate | 2015-12-01 |
| publisher | Academy of Sciences of Moldova, Institute of Chemistry |
| record_format | Article |
| series | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
| spelling | doaj.art-f31ef4d47ebd4176acc5dadc725439f22022-12-21T20:00:40ZengAcademy of Sciences of Moldova, Institute of ChemistryChemistry Journal of Moldova: General, Industrial and Ecological Chemistry1857-17272345-16882015-12-011023339NEW SOLVATOMORPH OF TETRAKIS(μ2-ACETATO-O,O')-BIS(ISONICOTINAMIDE-N)-DI-COPPER(II): SYNTHESIS, IR, TGA AND X-RAY STUDYDiana Chisca0Eduard Coropceanu1Oleg Petuhov2Lilia Croitor3Institute of Applied Physics of Academy of Sciences of Moldova, 5, Academiei str., Chisinau MD-2028, Republic of Moldova, Institute of Chemistry of Academy of Sciences of Moldova, 3, Academiei str., Chisinau MD-2028, Republic of MoldovaInstitute of Chemistry of Academy of Sciences of Moldova, 3, Academiei str., Chisinau MD-2028, Republic of MoldovaInstitute of Chemistry of Academy of Sciences of Moldova, 3, Academiei str., Chisinau MD-2028, Republic of MoldovaInstitute of Applied Physics of Academy of Sciences of Moldova, 5, Academiei str., Chisinau MD-2028, Republic of MoldovaDinucleartetracarboxylato-bridged copper(II)solvato-morph [Cu2(OAc)4(ina)2] •2dmso was prepared and studied by IR spectroscopy, TGA analysis and single crystal X-ray method. Cu(II) ions are bridged by four syn,syn-η1:η1:μ carboxylates, showing a paddle-wheel cage-type with a square-pyramidal geometry.http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold201510(2)_33-39_Croitor.pdfcopperisonicotinamideX-raypaddle-wheel structure |
| spellingShingle | Diana Chisca Eduard Coropceanu Oleg Petuhov Lilia Croitor NEW SOLVATOMORPH OF TETRAKIS(μ2-ACETATO-O,O')-BIS(ISONICOTINAMIDE-N)-DI-COPPER(II): SYNTHESIS, IR, TGA AND X-RAY STUDY Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry copper isonicotinamide X-ray paddle-wheel structure |
| title | NEW SOLVATOMORPH OF TETRAKIS(μ2-ACETATO-O,O')-BIS(ISONICOTINAMIDE-N)-DI-COPPER(II): SYNTHESIS, IR, TGA AND X-RAY STUDY |
| title_full | NEW SOLVATOMORPH OF TETRAKIS(μ2-ACETATO-O,O')-BIS(ISONICOTINAMIDE-N)-DI-COPPER(II): SYNTHESIS, IR, TGA AND X-RAY STUDY |
| title_fullStr | NEW SOLVATOMORPH OF TETRAKIS(μ2-ACETATO-O,O')-BIS(ISONICOTINAMIDE-N)-DI-COPPER(II): SYNTHESIS, IR, TGA AND X-RAY STUDY |
| title_full_unstemmed | NEW SOLVATOMORPH OF TETRAKIS(μ2-ACETATO-O,O')-BIS(ISONICOTINAMIDE-N)-DI-COPPER(II): SYNTHESIS, IR, TGA AND X-RAY STUDY |
| title_short | NEW SOLVATOMORPH OF TETRAKIS(μ2-ACETATO-O,O')-BIS(ISONICOTINAMIDE-N)-DI-COPPER(II): SYNTHESIS, IR, TGA AND X-RAY STUDY |
| title_sort | new solvatomorph of tetrakis μ2 acetato o o bis isonicotinamide n di copper ii synthesis ir tga and x ray study |
| topic | copper isonicotinamide X-ray paddle-wheel structure |
| url | http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold201510(2)_33-39_Croitor.pdf |
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