Structural Identifiability of Equivalent Circuit Models for Li-Ion Batteries

Structural identifiability is a critical aspect of modelling that has been overlooked in the vast majority of Li-ion battery modelling studies. It considers whether it is possible to obtain a unique solution for the unknown model parameters from experimental data. This is a fundamental prerequisite...

Full description

Bibliographic Details
Main Authors: Thomas R. B. Grandjean, Andrew McGordon, Paul A. Jennings
Format: Article
Language:English
Published: MDPI AG 2017-01-01
Series:Energies
Subjects:
Online Access:http://www.mdpi.com/1996-1073/10/1/90
_version_ 1798042495213371392
author Thomas R. B. Grandjean
Andrew McGordon
Paul A. Jennings
author_facet Thomas R. B. Grandjean
Andrew McGordon
Paul A. Jennings
author_sort Thomas R. B. Grandjean
collection DOAJ
description Structural identifiability is a critical aspect of modelling that has been overlooked in the vast majority of Li-ion battery modelling studies. It considers whether it is possible to obtain a unique solution for the unknown model parameters from experimental data. This is a fundamental prerequisite of the modelling process, especially when the parameters represent physical battery attributes and the proposed model is utilised to estimate them. Numerical estimates for unidentifiable parameters are effectively meaningless since unidentifiable parameters have an infinite number of possible numerical solutions. It is demonstrated that the physical phenomena assignment to a two-RC (resistor–capacitor) network equivalent circuit model (ECM) is not possible without additional information. Established methods to ascertain structural identifiability are applied to 12 ECMs covering the majority of model templates used previously. Seven ECMs are shown not to be uniquely identifiable, reducing the confidence in the accuracy of the parameter values obtained and highlighting the relevance of structural identifiability even for relatively simple models. Suggestions are proposed to make the models identifiable and, therefore, more valuable in battery management system applications. The detailed analyses illustrate the importance of structural identifiability prior to performing parameter estimation experiments, and the algebraic complications encountered even for simple models.
first_indexed 2024-04-11T22:36:18Z
format Article
id doaj.art-f327eab557d74a02878783847075ec75
institution Directory Open Access Journal
issn 1996-1073
language English
last_indexed 2024-04-11T22:36:18Z
publishDate 2017-01-01
publisher MDPI AG
record_format Article
series Energies
spelling doaj.art-f327eab557d74a02878783847075ec752022-12-22T03:59:13ZengMDPI AGEnergies1996-10732017-01-011019010.3390/en10010090en10010090Structural Identifiability of Equivalent Circuit Models for Li-Ion BatteriesThomas R. B. Grandjean0Andrew McGordon1Paul A. Jennings2Energy and Electrical Systems, WMG, University of Warwick, Coventry CV4 7AL, UKEnergy and Electrical Systems, WMG, University of Warwick, Coventry CV4 7AL, UKEnergy and Electrical Systems, WMG, University of Warwick, Coventry CV4 7AL, UKStructural identifiability is a critical aspect of modelling that has been overlooked in the vast majority of Li-ion battery modelling studies. It considers whether it is possible to obtain a unique solution for the unknown model parameters from experimental data. This is a fundamental prerequisite of the modelling process, especially when the parameters represent physical battery attributes and the proposed model is utilised to estimate them. Numerical estimates for unidentifiable parameters are effectively meaningless since unidentifiable parameters have an infinite number of possible numerical solutions. It is demonstrated that the physical phenomena assignment to a two-RC (resistor–capacitor) network equivalent circuit model (ECM) is not possible without additional information. Established methods to ascertain structural identifiability are applied to 12 ECMs covering the majority of model templates used previously. Seven ECMs are shown not to be uniquely identifiable, reducing the confidence in the accuracy of the parameter values obtained and highlighting the relevance of structural identifiability even for relatively simple models. Suggestions are proposed to make the models identifiable and, therefore, more valuable in battery management system applications. The detailed analyses illustrate the importance of structural identifiability prior to performing parameter estimation experiments, and the algebraic complications encountered even for simple models.http://www.mdpi.com/1996-1073/10/1/90structural identifiabilitylithium ion battery modellingequivalent circuit models
spellingShingle Thomas R. B. Grandjean
Andrew McGordon
Paul A. Jennings
Structural Identifiability of Equivalent Circuit Models for Li-Ion Batteries
Energies
structural identifiability
lithium ion battery modelling
equivalent circuit models
title Structural Identifiability of Equivalent Circuit Models for Li-Ion Batteries
title_full Structural Identifiability of Equivalent Circuit Models for Li-Ion Batteries
title_fullStr Structural Identifiability of Equivalent Circuit Models for Li-Ion Batteries
title_full_unstemmed Structural Identifiability of Equivalent Circuit Models for Li-Ion Batteries
title_short Structural Identifiability of Equivalent Circuit Models for Li-Ion Batteries
title_sort structural identifiability of equivalent circuit models for li ion batteries
topic structural identifiability
lithium ion battery modelling
equivalent circuit models
url http://www.mdpi.com/1996-1073/10/1/90
work_keys_str_mv AT thomasrbgrandjean structuralidentifiabilityofequivalentcircuitmodelsforliionbatteries
AT andrewmcgordon structuralidentifiabilityofequivalentcircuitmodelsforliionbatteries
AT paulajennings structuralidentifiabilityofequivalentcircuitmodelsforliionbatteries