Synthesis, magnetic, AC conductivity and dielectric properties of hematite nanocrystallites

We are reporting the synthesis along with magnetic, ac conductivity and dielectric properties of hematite nanocrystallites. The prepared Fe2O3 is crystallizing in corundum structure which belongs to the rhombohedron system with the space group R3-c. The magnetization data shows a typical Morin trans...

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Main Authors: Naresh Babu Gatchakayala, Rama Sekhara Reddy Dachuru
Format: Article
Language:English
Published: Vasyl Stefanyk Precarpathian National University 2023-04-01
Series:Фізика і хімія твердого тіла
Subjects:
Online Access:https://journals.pnu.edu.ua/index.php/pcss/article/view/6159
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author Naresh Babu Gatchakayala
Rama Sekhara Reddy Dachuru
author_facet Naresh Babu Gatchakayala
Rama Sekhara Reddy Dachuru
author_sort Naresh Babu Gatchakayala
collection DOAJ
description We are reporting the synthesis along with magnetic, ac conductivity and dielectric properties of hematite nanocrystallites. The prepared Fe2O3 is crystallizing in corundum structure which belongs to the rhombohedron system with the space group R3-c. The magnetization data shows a typical Morin transition, TN = 265 K for 110 nm crystallites, whereas this transition is decreasing with decrease in crystallite size, TN = 252 K for 33 nm. The value of magnetization is increased with increasing crystallite size. The enhanced dielectric permittivity and ac conductivity were observed in higher hematite crystallite size. The overall dielectric response has revealed conduction mechanism is due to the extrinsic contribution from the dominant Maxwell-Wagner polarization.
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spelling doaj.art-f32b2c589f9a4fc5a59e7393a08f89ef2023-09-19T08:42:35ZengVasyl Stefanyk Precarpathian National UniversityФізика і хімія твердого тіла1729-44282309-85892023-04-0124224424810.15330/pcss.24.2.244-2486159Synthesis, magnetic, AC conductivity and dielectric properties of hematite nanocrystallitesNaresh Babu Gatchakayala0Rama Sekhara Reddy Dachuru1Krishna University, Machilipatnam, Andhra Pradesh, IndiaKrishna University, Machilipatnam, Andhra Pradesh, IndiaWe are reporting the synthesis along with magnetic, ac conductivity and dielectric properties of hematite nanocrystallites. The prepared Fe2O3 is crystallizing in corundum structure which belongs to the rhombohedron system with the space group R3-c. The magnetization data shows a typical Morin transition, TN = 265 K for 110 nm crystallites, whereas this transition is decreasing with decrease in crystallite size, TN = 252 K for 33 nm. The value of magnetization is increased with increasing crystallite size. The enhanced dielectric permittivity and ac conductivity were observed in higher hematite crystallite size. The overall dielectric response has revealed conduction mechanism is due to the extrinsic contribution from the dominant Maxwell-Wagner polarization.https://journals.pnu.edu.ua/index.php/pcss/article/view/6159hematite nanoparticlescole-cole plotdielectric propertiesac conductivityimpedance
spellingShingle Naresh Babu Gatchakayala
Rama Sekhara Reddy Dachuru
Synthesis, magnetic, AC conductivity and dielectric properties of hematite nanocrystallites
Фізика і хімія твердого тіла
hematite nanoparticles
cole-cole plot
dielectric properties
ac conductivity
impedance
title Synthesis, magnetic, AC conductivity and dielectric properties of hematite nanocrystallites
title_full Synthesis, magnetic, AC conductivity and dielectric properties of hematite nanocrystallites
title_fullStr Synthesis, magnetic, AC conductivity and dielectric properties of hematite nanocrystallites
title_full_unstemmed Synthesis, magnetic, AC conductivity and dielectric properties of hematite nanocrystallites
title_short Synthesis, magnetic, AC conductivity and dielectric properties of hematite nanocrystallites
title_sort synthesis magnetic ac conductivity and dielectric properties of hematite nanocrystallites
topic hematite nanoparticles
cole-cole plot
dielectric properties
ac conductivity
impedance
url https://journals.pnu.edu.ua/index.php/pcss/article/view/6159
work_keys_str_mv AT nareshbabugatchakayala synthesismagneticacconductivityanddielectricpropertiesofhematitenanocrystallites
AT ramasekharareddydachuru synthesismagneticacconductivityanddielectricpropertiesofhematitenanocrystallites