RbFe(HAsO4)2 and TlFe(HAsO4)2, two new hydrogenarsenates adopting two closely related structure types
Rubidium iron bis[hydrogen arsenate(V)], RbFe(HAsO4)2, and thallium iron bis[hydrogen arsenate(V)], TlFe(HAsO4)2, were grown under mild hydrothermal conditions (T = 493 K, 7 d). RbFe(HAsO4)2 adopts the RbFe(HPO4)2 structure type (space group R\overline{3}c), while TlFe(HAsO4)2 crystallizes in the (N...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2018-06-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989018006473 |
| _version_ | 1798018498497085440 |
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| author | Karolina Schwendtner Uwe Kolitsch |
| author_facet | Karolina Schwendtner Uwe Kolitsch |
| author_sort | Karolina Schwendtner |
| collection | DOAJ |
| description | Rubidium iron bis[hydrogen arsenate(V)], RbFe(HAsO4)2, and thallium iron bis[hydrogen arsenate(V)], TlFe(HAsO4)2, were grown under mild hydrothermal conditions (T = 493 K, 7 d). RbFe(HAsO4)2 adopts the RbFe(HPO4)2 structure type (space group R\overline{3}c), while TlFe(HAsO4)2 crystallizes in the (NH4)Fe(HPO4)2 structure type (space group P\overline{1}). Both compounds have tetrahedral–octahedral framework topologies. The M+ cations are located in channels of the respective framework and are disordered in TlFe(HAsO4)2, which may suggest that the M+ cations can move in the channels. |
| first_indexed | 2024-04-11T16:25:02Z |
| format | Article |
| id | doaj.art-f32da46bb13b41bca9ab457af0794c4f |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-11T16:25:02Z |
| publishDate | 2018-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-f32da46bb13b41bca9ab457af0794c4f2022-12-22T04:14:13ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902018-06-0174676677110.1107/S2056989018006473pj2051RbFe(HAsO4)2 and TlFe(HAsO4)2, two new hydrogenarsenates adopting two closely related structure typesKarolina Schwendtner0Uwe Kolitsch1Institute for Chemical Technology and Analytics, Division of Structural Chemistry, TU Wien, Getreidemarkt 9/164-SC, 1060 Vienna, AustriaNaturhistorisches Museum, Burgring 7, 1010 Wien, and Institut für Mineralogie und Kristallographie, Universität Wien, Althanstrasse 14, 1090 Wien, AustriaRubidium iron bis[hydrogen arsenate(V)], RbFe(HAsO4)2, and thallium iron bis[hydrogen arsenate(V)], TlFe(HAsO4)2, were grown under mild hydrothermal conditions (T = 493 K, 7 d). RbFe(HAsO4)2 adopts the RbFe(HPO4)2 structure type (space group R\overline{3}c), while TlFe(HAsO4)2 crystallizes in the (NH4)Fe(HPO4)2 structure type (space group P\overline{1}). Both compounds have tetrahedral–octahedral framework topologies. The M+ cations are located in channels of the respective framework and are disordered in TlFe(HAsO4)2, which may suggest that the M+ cations can move in the channels.http://scripts.iucr.org/cgi-bin/paper?S2056989018006473crystal structureRbFe(HAsO4)2TlFe(HAsO4)2arsenatehydrogenarsenate(V)framework structurecation disorder |
| spellingShingle | Karolina Schwendtner Uwe Kolitsch RbFe(HAsO4)2 and TlFe(HAsO4)2, two new hydrogenarsenates adopting two closely related structure types Acta Crystallographica Section E: Crystallographic Communications crystal structure RbFe(HAsO4)2 TlFe(HAsO4)2 arsenate hydrogenarsenate(V) framework structure cation disorder |
| title | RbFe(HAsO4)2 and TlFe(HAsO4)2, two new hydrogenarsenates adopting two closely related structure types |
| title_full | RbFe(HAsO4)2 and TlFe(HAsO4)2, two new hydrogenarsenates adopting two closely related structure types |
| title_fullStr | RbFe(HAsO4)2 and TlFe(HAsO4)2, two new hydrogenarsenates adopting two closely related structure types |
| title_full_unstemmed | RbFe(HAsO4)2 and TlFe(HAsO4)2, two new hydrogenarsenates adopting two closely related structure types |
| title_short | RbFe(HAsO4)2 and TlFe(HAsO4)2, two new hydrogenarsenates adopting two closely related structure types |
| title_sort | rbfe haso4 2 and tlfe haso4 2 two new hydrogenarsenates adopting two closely related structure types |
| topic | crystal structure RbFe(HAsO4)2 TlFe(HAsO4)2 arsenate hydrogenarsenate(V) framework structure cation disorder |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989018006473 |
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