Photodegradation of Rhodamine B catalyzed by ZnO pellets

Abstract This paper describes the development of ZnO semiconductors applied as photocatalysts for the degradation of water contaminants, with the shape of ceramic pellets thick enough to maintain their structures, prepared by slip casting and sintering. The samples presented porosities around 40% an...

Full description

Bibliographic Details
Main Authors: T. M. O. Ruellas, G. H. S. Domingos, L. O. O. Peçanha, S. C. Maestrelli, T. R. Giraldi
Format: Article
Language:English
Published: Associação Brasileira de Cerâmica
Series:Cerâmica
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132019000500047&lng=en&tlng=en
_version_ 1818214954622255104
author T. M. O. Ruellas
G. H. S. Domingos
L. O. O. Peçanha
S. C. Maestrelli
T. R. Giraldi
author_facet T. M. O. Ruellas
G. H. S. Domingos
L. O. O. Peçanha
S. C. Maestrelli
T. R. Giraldi
author_sort T. M. O. Ruellas
collection DOAJ
description Abstract This paper describes the development of ZnO semiconductors applied as photocatalysts for the degradation of water contaminants, with the shape of ceramic pellets thick enough to maintain their structures, prepared by slip casting and sintering. The samples presented porosities around 40% and densities around 3.4 g/cm3, which represented about 61% of the theoretical density of ZnO. After obtaining the ceramic samples, the degradation of Rhodamine B dye by photocatalysis was evaluated in six cycles of degradation. After the cycles, changes in the surface of the samples were verified, possibly due to leaching during photocatalysis since they presented mean grain sizes of 0.61 μm before and 0.36 μm after the photocatalysis. The ceramic ZnO samples were able to satisfactorily degrade Rhodamine B for several cycles, resulting in successful reuse of photocatalysts and increased facility of removing the photocatalysts from the medium after degradation compared to powders in suspensions.
first_indexed 2024-12-12T06:28:23Z
format Article
id doaj.art-f35350fd2f0f45879f7eb59a85382e7c
institution Directory Open Access Journal
issn 1678-4553
language English
last_indexed 2024-12-12T06:28:23Z
publisher Associação Brasileira de Cerâmica
record_format Article
series Cerâmica
spelling doaj.art-f35350fd2f0f45879f7eb59a85382e7c2022-12-22T00:34:42ZengAssociação Brasileira de CerâmicaCerâmica1678-455365suppl 1475310.1590/0366-6913201965s12609S0366-69132019000500047Photodegradation of Rhodamine B catalyzed by ZnO pelletsT. M. O. RuellasG. H. S. DomingosL. O. O. PeçanhaS. C. MaestrelliT. R. GiraldiAbstract This paper describes the development of ZnO semiconductors applied as photocatalysts for the degradation of water contaminants, with the shape of ceramic pellets thick enough to maintain their structures, prepared by slip casting and sintering. The samples presented porosities around 40% and densities around 3.4 g/cm3, which represented about 61% of the theoretical density of ZnO. After obtaining the ceramic samples, the degradation of Rhodamine B dye by photocatalysis was evaluated in six cycles of degradation. After the cycles, changes in the surface of the samples were verified, possibly due to leaching during photocatalysis since they presented mean grain sizes of 0.61 μm before and 0.36 μm after the photocatalysis. The ceramic ZnO samples were able to satisfactorily degrade Rhodamine B for several cycles, resulting in successful reuse of photocatalysts and increased facility of removing the photocatalysts from the medium after degradation compared to powders in suspensions.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132019000500047&lng=en&tlng=enslip castingsemiconductorsphotocatalysisRhodamine BZnO
spellingShingle T. M. O. Ruellas
G. H. S. Domingos
L. O. O. Peçanha
S. C. Maestrelli
T. R. Giraldi
Photodegradation of Rhodamine B catalyzed by ZnO pellets
Cerâmica
slip casting
semiconductors
photocatalysis
Rhodamine B
ZnO
title Photodegradation of Rhodamine B catalyzed by ZnO pellets
title_full Photodegradation of Rhodamine B catalyzed by ZnO pellets
title_fullStr Photodegradation of Rhodamine B catalyzed by ZnO pellets
title_full_unstemmed Photodegradation of Rhodamine B catalyzed by ZnO pellets
title_short Photodegradation of Rhodamine B catalyzed by ZnO pellets
title_sort photodegradation of rhodamine b catalyzed by zno pellets
topic slip casting
semiconductors
photocatalysis
Rhodamine B
ZnO
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132019000500047&lng=en&tlng=en
work_keys_str_mv AT tmoruellas photodegradationofrhodaminebcatalyzedbyznopellets
AT ghsdomingos photodegradationofrhodaminebcatalyzedbyznopellets
AT loopecanha photodegradationofrhodaminebcatalyzedbyznopellets
AT scmaestrelli photodegradationofrhodaminebcatalyzedbyznopellets
AT trgiraldi photodegradationofrhodaminebcatalyzedbyznopellets