Electron spin resonance resolves intermediate triplet states in delayed fluorescence

Despite advances in the design of thermally activated delayed fluorescence (TADF) emitters for devices, the effect of spin interactions is not well understood. Here, the authors report the role of spin-vibronic coupling in TADF organic emitters using transient electron spin resonance spectroscopy.

Dettagli Bibliografici
Autori principali: Bluebell H. Drummond, Naoya Aizawa, Yadong Zhang, William K. Myers, Yao Xiong, Matthew W. Cooper, Stephen Barlow, Qinying Gu, Leah R. Weiss, Alexander J. Gillett, Dan Credgington, Yong-Jin Pu, Seth R. Marder, Emrys W. Evans
Natura: Articolo
Lingua:English
Pubblicazione: Nature Portfolio 2021-07-01
Serie:Nature Communications
Accesso online:https://doi.org/10.1038/s41467-021-24612-9
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author Bluebell H. Drummond
Naoya Aizawa
Yadong Zhang
William K. Myers
Yao Xiong
Matthew W. Cooper
Stephen Barlow
Qinying Gu
Leah R. Weiss
Alexander J. Gillett
Dan Credgington
Yong-Jin Pu
Seth R. Marder
Emrys W. Evans
author_facet Bluebell H. Drummond
Naoya Aizawa
Yadong Zhang
William K. Myers
Yao Xiong
Matthew W. Cooper
Stephen Barlow
Qinying Gu
Leah R. Weiss
Alexander J. Gillett
Dan Credgington
Yong-Jin Pu
Seth R. Marder
Emrys W. Evans
author_sort Bluebell H. Drummond
collection DOAJ
description Despite advances in the design of thermally activated delayed fluorescence (TADF) emitters for devices, the effect of spin interactions is not well understood. Here, the authors report the role of spin-vibronic coupling in TADF organic emitters using transient electron spin resonance spectroscopy.
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spelling doaj.art-f3619e86de5b4afb965b8f8c012cd3a12022-12-21T18:00:33ZengNature PortfolioNature Communications2041-17232021-07-0112111110.1038/s41467-021-24612-9Electron spin resonance resolves intermediate triplet states in delayed fluorescenceBluebell H. Drummond0Naoya Aizawa1Yadong Zhang2William K. Myers3Yao Xiong4Matthew W. Cooper5Stephen Barlow6Qinying Gu7Leah R. Weiss8Alexander J. Gillett9Dan Credgington10Yong-Jin Pu11Seth R. Marder12Emrys W. Evans13Department of Physics, Cavendish Laboratory, J J Thomson Avenue, University of CambridgeRIKEN Center for Emergent Matter Science (CEMS)School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics, Georgia Institute of TechnologyCentre for Advanced Electron Spin Resonance (CAESR), Department of Chemistry, University of Oxford, Inorganic Chemistry LaboratorySchool of Chemistry and Biochemistry and Center for Organic Photonics and Electronics, Georgia Institute of TechnologySchool of Chemistry and Biochemistry and Center for Organic Photonics and Electronics, Georgia Institute of TechnologySchool of Chemistry and Biochemistry and Center for Organic Photonics and Electronics, Georgia Institute of TechnologyDepartment of Physics, Cavendish Laboratory, J J Thomson Avenue, University of CambridgeDepartment of Physics, Cavendish Laboratory, J J Thomson Avenue, University of CambridgeDepartment of Physics, Cavendish Laboratory, J J Thomson Avenue, University of CambridgeDepartment of Physics, Cavendish Laboratory, J J Thomson Avenue, University of CambridgeRIKEN Center for Emergent Matter Science (CEMS)School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics, Georgia Institute of TechnologyDepartment of Physics, Cavendish Laboratory, J J Thomson Avenue, University of CambridgeDespite advances in the design of thermally activated delayed fluorescence (TADF) emitters for devices, the effect of spin interactions is not well understood. Here, the authors report the role of spin-vibronic coupling in TADF organic emitters using transient electron spin resonance spectroscopy.https://doi.org/10.1038/s41467-021-24612-9
spellingShingle Bluebell H. Drummond
Naoya Aizawa
Yadong Zhang
William K. Myers
Yao Xiong
Matthew W. Cooper
Stephen Barlow
Qinying Gu
Leah R. Weiss
Alexander J. Gillett
Dan Credgington
Yong-Jin Pu
Seth R. Marder
Emrys W. Evans
Electron spin resonance resolves intermediate triplet states in delayed fluorescence
Nature Communications
title Electron spin resonance resolves intermediate triplet states in delayed fluorescence
title_full Electron spin resonance resolves intermediate triplet states in delayed fluorescence
title_fullStr Electron spin resonance resolves intermediate triplet states in delayed fluorescence
title_full_unstemmed Electron spin resonance resolves intermediate triplet states in delayed fluorescence
title_short Electron spin resonance resolves intermediate triplet states in delayed fluorescence
title_sort electron spin resonance resolves intermediate triplet states in delayed fluorescence
url https://doi.org/10.1038/s41467-021-24612-9
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