NEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDY
Five new oxalato and hydrogenoxalato complexes with ZnBr2 have been synthesized and studied by infrared. Discrete structures have been suggested in the basis of spectroscopic data. The environments around the zinc centre being trigonal bipyramidal, tetrahedral, octahedral or monocapped octahedral....
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2017-09-01
|
| Series: | Journal of Engineering Studies and Research |
| Subjects: | |
| Online Access: | https://jesr.ub.ro/1/article/view/78 |
| _version_ | 1797202289042128896 |
|---|---|
| author | GORGUI AWA SECK LIBASSE DIOP ABOUBACRY SENE |
| author_facet | GORGUI AWA SECK LIBASSE DIOP ABOUBACRY SENE |
| author_sort | GORGUI AWA SECK |
| collection | DOAJ |
| description |
Five new oxalato and hydrogenoxalato complexes with ZnBr2 have been synthesized and studied by infrared. Discrete structures have been suggested in the basis of spectroscopic data. The environments around the zinc centre being trigonal bipyramidal, tetrahedral, octahedral or monocapped octahedral. The anions behave as monochelating ligands. When the cations and OH group are involved in extra hydrogen bonds, a supramolecular architecture may be obtained.
|
| first_indexed | 2024-03-07T17:27:42Z |
| format | Article |
| id | doaj.art-f368015c46444974869b1b6cb4202e75 |
| institution | Directory Open Access Journal |
| issn | 2068-7559 2344-4932 |
| language | English |
| last_indexed | 2024-04-24T08:01:04Z |
| publishDate | 2017-09-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Journal of Engineering Studies and Research |
| spelling | doaj.art-f368015c46444974869b1b6cb4202e752024-04-17T19:35:39ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322017-09-01233NEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDYGORGUI AWA SECK0LIBASSE DIOP1ABOUBACRY SENE2University Cheikh Anta Diop, Faculty of Sciences and Technics, Department of Chemistry, Laboratory of Mineral and Analytical Chemistry, DAKAR, Senegal University Cheikh Anta Diop, Faculty of Sciences and Technics, Department of Chemistry, Laboratory of Mineral and Analytical Chemistry, DAKAR, Senegal University Cheikh Anta Diop, Faculty of Sciences and Technics, Department of Chemistry, Laboratory of Mineral and Analytical Chemistry, DAKAR, Senegal Five new oxalato and hydrogenoxalato complexes with ZnBr2 have been synthesized and studied by infrared. Discrete structures have been suggested in the basis of spectroscopic data. The environments around the zinc centre being trigonal bipyramidal, tetrahedral, octahedral or monocapped octahedral. The anions behave as monochelating ligands. When the cations and OH group are involved in extra hydrogen bonds, a supramolecular architecture may be obtained. https://jesr.ub.ro/1/article/view/78discrete structureshydrogen bondsIR technicmonochelating oxoanionsmonocapped octahedraloxalato and hydrogenoxalato complexes |
| spellingShingle | GORGUI AWA SECK LIBASSE DIOP ABOUBACRY SENE NEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDY Journal of Engineering Studies and Research discrete structures hydrogen bonds IR technic monochelating oxoanions monocapped octahedral oxalato and hydrogenoxalato complexes |
| title | NEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDY |
| title_full | NEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDY |
| title_fullStr | NEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDY |
| title_full_unstemmed | NEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDY |
| title_short | NEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDY |
| title_sort | new zinc oxalato and hydrogenoxalato complexes synthesis and infrared study |
| topic | discrete structures hydrogen bonds IR technic monochelating oxoanions monocapped octahedral oxalato and hydrogenoxalato complexes |
| url | https://jesr.ub.ro/1/article/view/78 |
| work_keys_str_mv | AT gorguiawaseck newzincoxalatoandhydrogenoxalatocomplexessynthesisandinfraredstudy AT libassediop newzincoxalatoandhydrogenoxalatocomplexessynthesisandinfraredstudy AT aboubacrysene newzincoxalatoandhydrogenoxalatocomplexessynthesisandinfraredstudy |