The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs
Cycloparaphenylenes (CPPs) and their analogs have recently attracted much attention due to their aesthetical structures and optoelectronic properties with radial π-conjugation systems. The past 10 years have witnessed a remarkable advancement in CPPs research, from synthetic methodology to optoelect...
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| Format: | Article |
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Frontiers Media S.A.
2019-10-01
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| Series: | Frontiers in Chemistry |
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| Online Access: | https://www.frontiersin.org/article/10.3389/fchem.2019.00668/full |
| _version_ | 1818027103114756096 |
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| author | Dapeng Lu Qiang Huang Shengda Wang Jinyi Wang Pingsen Huang Pingwu Du |
| author_facet | Dapeng Lu Qiang Huang Shengda Wang Jinyi Wang Pingsen Huang Pingwu Du |
| author_sort | Dapeng Lu |
| collection | DOAJ |
| description | Cycloparaphenylenes (CPPs) and their analogs have recently attracted much attention due to their aesthetical structures and optoelectronic properties with radial π-conjugation systems. The past 10 years have witnessed a remarkable advancement in CPPs research, from synthetic methodology to optoelectronic investigations. In this present minireview, we highlight the supramolecular chemistry of CPPs and their analogs, mainly focusing on the size-selective encapsulation of fullerenes, endohedral metallofullerenes, and small molecules by these hoop-shaped macrocycles. We will also discuss the assembly of molecular bearings using some belt-persistent tubular cycloarylene molecules and fullerenes, photoinduced electron transfer properties in supramolecular systems containing carbon nanohoop hosts and fullerene guests, as well as the shape recognition properties for structure self-sorting by using dumbbell-shaped dimer of [60]fullerene ligand. Besides, the supramolecular complexes with guest molecules other than fullerenes, such as CPPs themselves, iodine, pyridinium cations, and bowl-shaped corannulene, are also discussed. |
| first_indexed | 2024-12-10T04:42:34Z |
| format | Article |
| id | doaj.art-f36a08bc61e24d91b21655e615f5f945 |
| institution | Directory Open Access Journal |
| issn | 2296-2646 |
| language | English |
| last_indexed | 2024-12-10T04:42:34Z |
| publishDate | 2019-10-01 |
| publisher | Frontiers Media S.A. |
| record_format | Article |
| series | Frontiers in Chemistry |
| spelling | doaj.art-f36a08bc61e24d91b21655e615f5f9452022-12-22T02:01:51ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462019-10-01710.3389/fchem.2019.00668490882The Supramolecular Chemistry of Cycloparaphenylenes and Their AnalogsDapeng Lu0Qiang Huang1Shengda Wang2Jinyi Wang3Pingsen Huang4Pingwu Du5School of Pharmacy, Anhui Medical University, Hefei, ChinaHefei National Laboratory for Physical Sciences at the Microscale, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, ChinaHefei National Laboratory for Physical Sciences at the Microscale, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, ChinaHefei National Laboratory for Physical Sciences at the Microscale, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, ChinaHefei National Laboratory for Physical Sciences at the Microscale, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, ChinaHefei National Laboratory for Physical Sciences at the Microscale, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, ChinaCycloparaphenylenes (CPPs) and their analogs have recently attracted much attention due to their aesthetical structures and optoelectronic properties with radial π-conjugation systems. The past 10 years have witnessed a remarkable advancement in CPPs research, from synthetic methodology to optoelectronic investigations. In this present minireview, we highlight the supramolecular chemistry of CPPs and their analogs, mainly focusing on the size-selective encapsulation of fullerenes, endohedral metallofullerenes, and small molecules by these hoop-shaped macrocycles. We will also discuss the assembly of molecular bearings using some belt-persistent tubular cycloarylene molecules and fullerenes, photoinduced electron transfer properties in supramolecular systems containing carbon nanohoop hosts and fullerene guests, as well as the shape recognition properties for structure self-sorting by using dumbbell-shaped dimer of [60]fullerene ligand. Besides, the supramolecular complexes with guest molecules other than fullerenes, such as CPPs themselves, iodine, pyridinium cations, and bowl-shaped corannulene, are also discussed.https://www.frontiersin.org/article/10.3389/fchem.2019.00668/fullsupramolecular chemistryfullerene guestnon-fullerene guestcarbon nanohoopcycloparaphenylene |
| spellingShingle | Dapeng Lu Qiang Huang Shengda Wang Jinyi Wang Pingsen Huang Pingwu Du The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs Frontiers in Chemistry supramolecular chemistry fullerene guest non-fullerene guest carbon nanohoop cycloparaphenylene |
| title | The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs |
| title_full | The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs |
| title_fullStr | The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs |
| title_full_unstemmed | The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs |
| title_short | The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs |
| title_sort | supramolecular chemistry of cycloparaphenylenes and their analogs |
| topic | supramolecular chemistry fullerene guest non-fullerene guest carbon nanohoop cycloparaphenylene |
| url | https://www.frontiersin.org/article/10.3389/fchem.2019.00668/full |
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