Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane
Perovskite-type LaSrMO4 (M = Mn, Fe, Co, Ni, Cu) mixed oxides were prepared by the decomposition of amorphous citric and ethylenediaminetetraacetic acid complexes and investigated by the XRD, FTIR, BET, TPR, TPD and XPSmethods. Their catalytic behavior in the total oxidation of hexane was examined....
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Serbian Chemical Society
2006-01-01
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Series: | Journal of the Serbian Chemical Society |
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Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390610049Z.pdf |
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author | Zhong H. Zeng R. |
author_facet | Zhong H. Zeng R. |
author_sort | Zhong H. |
collection | DOAJ |
description | Perovskite-type LaSrMO4 (M = Mn, Fe, Co, Ni, Cu) mixed oxides were prepared by the decomposition of amorphous citric and ethylenediaminetetraacetic acid complexes and investigated by the XRD, FTIR, BET, TPR, TPD and XPSmethods. Their catalytic behavior in the total oxidation of hexane was examined. The following activity order was found LaSrCoO4 > LaSrNiO4 > LaSrCuO4 > LaSrFeO4 > LaSrMnO4. This is explained in terms of oxygen vacancies and mobile lattice oxygen, particle size and BET surface area. . |
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institution | Directory Open Access Journal |
issn | 0352-5139 1820-7421 |
language | English |
last_indexed | 2024-12-24T00:46:07Z |
publishDate | 2006-01-01 |
publisher | Serbian Chemical Society |
record_format | Article |
series | Journal of the Serbian Chemical Society |
spelling | doaj.art-f36bf7d8237346dc9d75063e2e7ebd602022-12-21T17:23:48ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212006-01-0171101049105910.2298/JSC0610049Z0352-51390610049ZStructure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexaneZhong H.0Zeng R.1Provincial key laboratory of coordination chemistry, Jinggangshan University, Jian, College of chemistry and chemical engineering, Jinggangshan University, JianProvincial key laboratory of coordination chemistry, Jinggangshan University, Jian, College of chemistry and chemical engineering, Jinggangshan University, JianPerovskite-type LaSrMO4 (M = Mn, Fe, Co, Ni, Cu) mixed oxides were prepared by the decomposition of amorphous citric and ethylenediaminetetraacetic acid complexes and investigated by the XRD, FTIR, BET, TPR, TPD and XPSmethods. Their catalytic behavior in the total oxidation of hexane was examined. The following activity order was found LaSrCoO4 > LaSrNiO4 > LaSrCuO4 > LaSrFeO4 > LaSrMnO4. This is explained in terms of oxygen vacancies and mobile lattice oxygen, particle size and BET surface area. .http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390610049Z.pdfperovskite-type lasrmo4hexane oxidationcatalytic property |
spellingShingle | Zhong H. Zeng R. Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane Journal of the Serbian Chemical Society perovskite-type lasrmo4 hexane oxidation catalytic property |
title | Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane |
title_full | Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane |
title_fullStr | Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane |
title_full_unstemmed | Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane |
title_short | Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane |
title_sort | structure of lasrmo4 m mn fe co ni cu and their catalytic properties in the total oxidation of hexane |
topic | perovskite-type lasrmo4 hexane oxidation catalytic property |
url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390610049Z.pdf |
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