Sustainable Gas Phase Selective Photocatalytic Oxidation of Cyclohexane on MoO<sub>x</sub>/TiO<sub>2</sub>/SiO<sub>2</sub> catalysts
Gas phase selective photocatalytic oxidation of cyclohexane was studied in a two dimensional fluidized bed reactor on MoOx catalysts supported on grafted TiO2/SiO2. The influence of sulphate and Mo loading was evaluated. Photocatalytic tests showed that benzene was the main reaction product formed d...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
AIDIC Servizi S.r.l.
2014-08-01
|
| Series: | Chemical Engineering Transactions |
| Online Access: | https://www.cetjournal.it/index.php/cet/article/view/5396 |
| _version_ | 1818923502207500288 |
|---|---|
| author | V. Vaiano D. Sannino P. Ciambelli |
| author_facet | V. Vaiano D. Sannino P. Ciambelli |
| author_sort | V. Vaiano |
| collection | DOAJ |
| description | Gas phase selective photocatalytic oxidation of cyclohexane was studied in a two dimensional fluidized bed reactor on MoOx catalysts supported on grafted TiO2/SiO2. The influence of sulphate and Mo loading was evaluated. Photocatalytic tests showed that benzene was the main reaction product formed during irradiation with together CO2 and cyclohexene as by products.
Depending on the TiO2, Mo and sulphate loading, an enhancement of the activity and catalysts stability occurred during irradiation. MoOx/TiO2/SiO2 samples showed a higher photocatalytic activity with respect to MoOx/TiO2-Al2O3. This behaviour was attributed to the better transmission of UV light through SiO2 than through Al2O3 and the lower absorption of the radiation. |
| first_indexed | 2024-12-20T02:10:27Z |
| format | Article |
| id | doaj.art-f36cae3b207642709b74e8bb0520069c |
| institution | Directory Open Access Journal |
| issn | 2283-9216 |
| language | English |
| last_indexed | 2024-12-20T02:10:27Z |
| publishDate | 2014-08-01 |
| publisher | AIDIC Servizi S.r.l. |
| record_format | Article |
| series | Chemical Engineering Transactions |
| spelling | doaj.art-f36cae3b207642709b74e8bb0520069c2022-12-21T19:57:05ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162014-08-013910.3303/CET1439095Sustainable Gas Phase Selective Photocatalytic Oxidation of Cyclohexane on MoO<sub>x</sub>/TiO<sub>2</sub>/SiO<sub>2</sub> catalystsV. VaianoD. SanninoP. CiambelliGas phase selective photocatalytic oxidation of cyclohexane was studied in a two dimensional fluidized bed reactor on MoOx catalysts supported on grafted TiO2/SiO2. The influence of sulphate and Mo loading was evaluated. Photocatalytic tests showed that benzene was the main reaction product formed during irradiation with together CO2 and cyclohexene as by products. Depending on the TiO2, Mo and sulphate loading, an enhancement of the activity and catalysts stability occurred during irradiation. MoOx/TiO2/SiO2 samples showed a higher photocatalytic activity with respect to MoOx/TiO2-Al2O3. This behaviour was attributed to the better transmission of UV light through SiO2 than through Al2O3 and the lower absorption of the radiation.https://www.cetjournal.it/index.php/cet/article/view/5396 |
| spellingShingle | V. Vaiano D. Sannino P. Ciambelli Sustainable Gas Phase Selective Photocatalytic Oxidation of Cyclohexane on MoO<sub>x</sub>/TiO<sub>2</sub>/SiO<sub>2</sub> catalysts Chemical Engineering Transactions |
| title | Sustainable Gas Phase Selective Photocatalytic Oxidation of Cyclohexane on MoO<sub>x</sub>/TiO<sub>2</sub>/SiO<sub>2</sub> catalysts |
| title_full | Sustainable Gas Phase Selective Photocatalytic Oxidation of Cyclohexane on MoO<sub>x</sub>/TiO<sub>2</sub>/SiO<sub>2</sub> catalysts |
| title_fullStr | Sustainable Gas Phase Selective Photocatalytic Oxidation of Cyclohexane on MoO<sub>x</sub>/TiO<sub>2</sub>/SiO<sub>2</sub> catalysts |
| title_full_unstemmed | Sustainable Gas Phase Selective Photocatalytic Oxidation of Cyclohexane on MoO<sub>x</sub>/TiO<sub>2</sub>/SiO<sub>2</sub> catalysts |
| title_short | Sustainable Gas Phase Selective Photocatalytic Oxidation of Cyclohexane on MoO<sub>x</sub>/TiO<sub>2</sub>/SiO<sub>2</sub> catalysts |
| title_sort | sustainable gas phase selective photocatalytic oxidation of cyclohexane on moo sub x sub tio sub 2 sub sio sub 2 sub catalysts |
| url | https://www.cetjournal.it/index.php/cet/article/view/5396 |
| work_keys_str_mv | AT vvaiano sustainablegasphaseselectivephotocatalyticoxidationofcyclohexaneonmoosubxsubtiosub2subsiosub2subcatalysts AT dsannino sustainablegasphaseselectivephotocatalyticoxidationofcyclohexaneonmoosubxsubtiosub2subsiosub2subcatalysts AT pciambelli sustainablegasphaseselectivephotocatalyticoxidationofcyclohexaneonmoosubxsubtiosub2subsiosub2subcatalysts |