Lignin-based phenolic resin modified with whisker silicon and its application

In this study, lignin-based phenolic resin was modified with whisker silicon and preparation of the phenolic foam was carried out. The resin and foam materials were characterized by Fourier transform infrared spectroscopy (FT-IR), thermo gravimetric analyzer (TGA), thermal conductivity test, limit o...

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Main Authors: Na Zhang, Zhuo Li, Yanan Xiao, Zheng Pan, Puyou Jia, Guodong Feng, Caiying Bao, Yonghong Zhou, Lilong Hua
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2020-02-01
Series:Journal of Bioresources and Bioproducts
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S236996982030058X
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author Na Zhang
Zhuo Li
Yanan Xiao
Zheng Pan
Puyou Jia
Guodong Feng
Caiying Bao
Yonghong Zhou
Lilong Hua
author_facet Na Zhang
Zhuo Li
Yanan Xiao
Zheng Pan
Puyou Jia
Guodong Feng
Caiying Bao
Yonghong Zhou
Lilong Hua
author_sort Na Zhang
collection DOAJ
description In this study, lignin-based phenolic resin was modified with whisker silicon and preparation of the phenolic foam was carried out. The resin and foam materials were characterized by Fourier transform infrared spectroscopy (FT-IR), thermo gravimetric analyzer (TGA), thermal conductivity test, limit oxygen index (LOI) analyzer and cone calorimeter. The results showed that when the content of lignin and whisker silicon increased, the oxygen index of the foam increases and the calorific value of combustion decreased. However, if the amount of lignin increased, the open porosity of the foam and the thermal conductivity increased. When the lignin substitution rate was 30% and the whisker silicon addition amount was 1%, the phenolic foam (PF4) had the best performance: the 57.1% mass lost at 600  °C and the thermal stability was 16.8% higher than that of ordinary resin. The LOI was 49.6%, and 39.3% higher than that of ordinary phenolic foam.
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spelling doaj.art-f36e1839b2684e23aabf3a158e87252a2023-03-24T04:22:27ZengKeAi Communications Co., Ltd.Journal of Bioresources and Bioproducts2369-96982020-02-01516777Lignin-based phenolic resin modified with whisker silicon and its applicationNa Zhang0Zhuo Li1Yanan Xiao2Zheng Pan3Puyou Jia4Guodong Feng5Caiying Bao6Yonghong Zhou7Lilong Hua8Institute of Chemical Industry of Forest Products, Chinese Academy of Forest, Co-innovation Center of Efficient Processing and Utilization of Forest Resource, Nanjing Forestry University, Nanjing 210042, ChinaInstitute of Chemical Industry of Forest Products, Chinese Academy of Forest, Co-innovation Center of Efficient Processing and Utilization of Forest Resource, Nanjing Forestry University, Nanjing 210042, ChinaSchool of Petrochemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, ChinaInstitute of Chemical Industry of Forest Products, Chinese Academy of Forest, Co-innovation Center of Efficient Processing and Utilization of Forest Resource, Nanjing Forestry University, Nanjing 210042, ChinaInstitute of Chemical Industry of Forest Products, Chinese Academy of Forest, Co-innovation Center of Efficient Processing and Utilization of Forest Resource, Nanjing Forestry University, Nanjing 210042, ChinaInstitute of Chemical Industry of Forest Products, Chinese Academy of Forest, Co-innovation Center of Efficient Processing and Utilization of Forest Resource, Nanjing Forestry University, Nanjing 210042, ChinaInstitute of Chemical Industry of Forest Products, Chinese Academy of Forest, Co-innovation Center of Efficient Processing and Utilization of Forest Resource, Nanjing Forestry University, Nanjing 210042, ChinaInstitute of Chemical Industry of Forest Products, Chinese Academy of Forest, Co-innovation Center of Efficient Processing and Utilization of Forest Resource, Nanjing Forestry University, Nanjing 210042, ChinaInstitute of Chemical Industry of Forest Products, Chinese Academy of Forest, Co-innovation Center of Efficient Processing and Utilization of Forest Resource, Nanjing Forestry University, Nanjing 210042, China; Corresponding author.In this study, lignin-based phenolic resin was modified with whisker silicon and preparation of the phenolic foam was carried out. The resin and foam materials were characterized by Fourier transform infrared spectroscopy (FT-IR), thermo gravimetric analyzer (TGA), thermal conductivity test, limit oxygen index (LOI) analyzer and cone calorimeter. The results showed that when the content of lignin and whisker silicon increased, the oxygen index of the foam increases and the calorific value of combustion decreased. However, if the amount of lignin increased, the open porosity of the foam and the thermal conductivity increased. When the lignin substitution rate was 30% and the whisker silicon addition amount was 1%, the phenolic foam (PF4) had the best performance: the 57.1% mass lost at 600  °C and the thermal stability was 16.8% higher than that of ordinary resin. The LOI was 49.6%, and 39.3% higher than that of ordinary phenolic foam.http://www.sciencedirect.com/science/article/pii/S236996982030058XPhenolic foamPhenolic resinLigninWhisker silicon
spellingShingle Na Zhang
Zhuo Li
Yanan Xiao
Zheng Pan
Puyou Jia
Guodong Feng
Caiying Bao
Yonghong Zhou
Lilong Hua
Lignin-based phenolic resin modified with whisker silicon and its application
Journal of Bioresources and Bioproducts
Phenolic foam
Phenolic resin
Lignin
Whisker silicon
title Lignin-based phenolic resin modified with whisker silicon and its application
title_full Lignin-based phenolic resin modified with whisker silicon and its application
title_fullStr Lignin-based phenolic resin modified with whisker silicon and its application
title_full_unstemmed Lignin-based phenolic resin modified with whisker silicon and its application
title_short Lignin-based phenolic resin modified with whisker silicon and its application
title_sort lignin based phenolic resin modified with whisker silicon and its application
topic Phenolic foam
Phenolic resin
Lignin
Whisker silicon
url http://www.sciencedirect.com/science/article/pii/S236996982030058X
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