Entropy and crystal-facet modulation of P2-type layered cathodes for long-lasting sodium-based batteries
The use of Mn-rich layered cathodes in Na-based batteries is hindered by inadequate cycling reversibility and sluggish anionic redox kinetics. Here, the authors report a strategy to stabilize the structure and promote anionic redox via configurational entropy and ion-diffusion structural tuning.
| Main Authors: | , , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-05-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-30113-0 |
| _version_ | 1811255077381341184 |
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| author | Fang Fu Xiang Liu Xiaoguang Fu Hongwei Chen Ling Huang Jingjing Fan Jiabo Le Qiuxiang Wang Weihua Yang Yang Ren Khalil Amine Shi-Gang Sun Gui-Liang Xu |
| author_facet | Fang Fu Xiang Liu Xiaoguang Fu Hongwei Chen Ling Huang Jingjing Fan Jiabo Le Qiuxiang Wang Weihua Yang Yang Ren Khalil Amine Shi-Gang Sun Gui-Liang Xu |
| author_sort | Fang Fu |
| collection | DOAJ |
| description | The use of Mn-rich layered cathodes in Na-based batteries is hindered by inadequate cycling reversibility and sluggish anionic redox kinetics. Here, the authors report a strategy to stabilize the structure and promote anionic redox via configurational entropy and ion-diffusion structural tuning. |
| first_indexed | 2024-04-12T17:18:19Z |
| format | Article |
| id | doaj.art-f37a104677d54f5e8771ee056f13d714 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-12T17:18:19Z |
| publishDate | 2022-05-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-f37a104677d54f5e8771ee056f13d7142022-12-22T03:23:35ZengNature PortfolioNature Communications2041-17232022-05-0113111210.1038/s41467-022-30113-0Entropy and crystal-facet modulation of P2-type layered cathodes for long-lasting sodium-based batteriesFang Fu0Xiang Liu1Xiaoguang Fu2Hongwei Chen3Ling Huang4Jingjing Fan5Jiabo Le6Qiuxiang Wang7Weihua Yang8Yang Ren9Khalil Amine10Shi-Gang Sun11Gui-Liang Xu12College of Materials Science and Engineering, Huaqiao UniversityChemical Sciences and Engineering Division, Argonne National LaboratoryCollege of Materials Science and Engineering, Huaqiao UniversityCollege of Materials Science and Engineering, Huaqiao UniversityState Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen UniversityState Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen UniversityState Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen UniversityCollege of Materials Science and Engineering, Huaqiao UniversityCollege of Materials Science and Engineering, Huaqiao UniversityX-ray Science Division, Advanced Photon Source, Argonne National LaboratoryChemical Sciences and Engineering Division, Argonne National LaboratoryState Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen UniversityChemical Sciences and Engineering Division, Argonne National LaboratoryThe use of Mn-rich layered cathodes in Na-based batteries is hindered by inadequate cycling reversibility and sluggish anionic redox kinetics. Here, the authors report a strategy to stabilize the structure and promote anionic redox via configurational entropy and ion-diffusion structural tuning.https://doi.org/10.1038/s41467-022-30113-0 |
| spellingShingle | Fang Fu Xiang Liu Xiaoguang Fu Hongwei Chen Ling Huang Jingjing Fan Jiabo Le Qiuxiang Wang Weihua Yang Yang Ren Khalil Amine Shi-Gang Sun Gui-Liang Xu Entropy and crystal-facet modulation of P2-type layered cathodes for long-lasting sodium-based batteries Nature Communications |
| title | Entropy and crystal-facet modulation of P2-type layered cathodes for long-lasting sodium-based batteries |
| title_full | Entropy and crystal-facet modulation of P2-type layered cathodes for long-lasting sodium-based batteries |
| title_fullStr | Entropy and crystal-facet modulation of P2-type layered cathodes for long-lasting sodium-based batteries |
| title_full_unstemmed | Entropy and crystal-facet modulation of P2-type layered cathodes for long-lasting sodium-based batteries |
| title_short | Entropy and crystal-facet modulation of P2-type layered cathodes for long-lasting sodium-based batteries |
| title_sort | entropy and crystal facet modulation of p2 type layered cathodes for long lasting sodium based batteries |
| url | https://doi.org/10.1038/s41467-022-30113-0 |
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