Photocatalytic degradation of Orange-II by surfactant assisted Mn/Mg co-doped TiO2 nanoparticles under visible light irradiation

In this research, the photocatalytic effect was studied for sol-gel synthesized Mn/Mg co-doped metal oxide (TiO2) nanoparticles (NPs), which are encapsulated with anionic Gemini surfactant. The physicochemical properties of Mn/Mg co-doped TiO2 were investigated using a variety of characteri...

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Main Authors: Sankara Rao Miditana, Siva Rao Tirukkovalluri, Imandi Manga Raju, Shaik Abdul Alim
Format: Article
Language:English
Published: Growing Science 2024-01-01
Series:Current Chemistry Letters
Online Access:http://www.growingscience.com/ccl/Vol13/ccl_2023_40.pdf
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author Sankara Rao Miditana
Siva Rao Tirukkovalluri
Imandi Manga Raju
Shaik Abdul Alim
author_facet Sankara Rao Miditana
Siva Rao Tirukkovalluri
Imandi Manga Raju
Shaik Abdul Alim
author_sort Sankara Rao Miditana
collection DOAJ
description In this research, the photocatalytic effect was studied for sol-gel synthesized Mn/Mg co-doped metal oxide (TiO2) nanoparticles (NPs), which are encapsulated with anionic Gemini surfactant. The physicochemical properties of Mn/Mg co-doped TiO2 were investigated using a variety of characterization techniques, FT-IR, UV Vis-DRS, XRD, SEM, EDX, TEM, BET and PL. Characterization results reveal that Mn/Mg dopants stabilize TiO2 in the form of anatase phase and reduce the bandgap energy. Presence of strong chemical bonding and functional groups at the interface of dopant and TiO2 NPs was confirmed with FT-IR. The photocatalytic activity of these catalysts was assessed by the degradation of Orange II (AO7) using visible light irradiation. Of the variable nanomaterials MMT5-GS2 showed remarkable results. The photoluminescence studies revealed that OH radicals are the reactive species and responsible for oxidative photocatalytic degradation of Orange II.
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spelling doaj.art-f38722b9dce04e20a63201bdeddd2b272023-10-06T13:15:32ZengGrowing ScienceCurrent Chemistry Letters1927-72961927-730X2024-01-0113126527610.5267/j.ccl.2023.6.003Photocatalytic degradation of Orange-II by surfactant assisted Mn/Mg co-doped TiO2 nanoparticles under visible light irradiationSankara Rao Miditana Siva Rao TirukkovalluriImandi Manga Raju Shaik Abdul Alim In this research, the photocatalytic effect was studied for sol-gel synthesized Mn/Mg co-doped metal oxide (TiO2) nanoparticles (NPs), which are encapsulated with anionic Gemini surfactant. The physicochemical properties of Mn/Mg co-doped TiO2 were investigated using a variety of characterization techniques, FT-IR, UV Vis-DRS, XRD, SEM, EDX, TEM, BET and PL. Characterization results reveal that Mn/Mg dopants stabilize TiO2 in the form of anatase phase and reduce the bandgap energy. Presence of strong chemical bonding and functional groups at the interface of dopant and TiO2 NPs was confirmed with FT-IR. The photocatalytic activity of these catalysts was assessed by the degradation of Orange II (AO7) using visible light irradiation. Of the variable nanomaterials MMT5-GS2 showed remarkable results. The photoluminescence studies revealed that OH radicals are the reactive species and responsible for oxidative photocatalytic degradation of Orange II.http://www.growingscience.com/ccl/Vol13/ccl_2023_40.pdf
spellingShingle Sankara Rao Miditana
Siva Rao Tirukkovalluri
Imandi Manga Raju
Shaik Abdul Alim
Photocatalytic degradation of Orange-II by surfactant assisted Mn/Mg co-doped TiO2 nanoparticles under visible light irradiation
Current Chemistry Letters
title Photocatalytic degradation of Orange-II by surfactant assisted Mn/Mg co-doped TiO2 nanoparticles under visible light irradiation
title_full Photocatalytic degradation of Orange-II by surfactant assisted Mn/Mg co-doped TiO2 nanoparticles under visible light irradiation
title_fullStr Photocatalytic degradation of Orange-II by surfactant assisted Mn/Mg co-doped TiO2 nanoparticles under visible light irradiation
title_full_unstemmed Photocatalytic degradation of Orange-II by surfactant assisted Mn/Mg co-doped TiO2 nanoparticles under visible light irradiation
title_short Photocatalytic degradation of Orange-II by surfactant assisted Mn/Mg co-doped TiO2 nanoparticles under visible light irradiation
title_sort photocatalytic degradation of orange ii by surfactant assisted mn mg co doped tio2 nanoparticles under visible light irradiation
url http://www.growingscience.com/ccl/Vol13/ccl_2023_40.pdf
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AT imandimangaraju photocatalyticdegradationoforangeiibysurfactantassistedmnmgcodopedtio2nanoparticlesundervisiblelightirradiation
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