Nitro-Perylenediimide: An Emerging Building Block for the Synthesis of Functional Organic Materials
Perylenediimide (PDI) is one of the most important classes of dyes and is intensively explored in the field of functional organic materials. The functionalization of this electron-deficient aromatic core is well-known to tune the outstanding optoelectronic properties of PDI derivatives. In this resp...
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MDPI AG
2020-03-01
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Series: | Molecules |
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Online Access: | https://www.mdpi.com/1420-3049/25/6/1402 |
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author | Lou Rocard Antoine Goujon Piétrick Hudhomme |
author_facet | Lou Rocard Antoine Goujon Piétrick Hudhomme |
author_sort | Lou Rocard |
collection | DOAJ |
description | Perylenediimide (PDI) is one of the most important classes of dyes and is intensively explored in the field of functional organic materials. The functionalization of this electron-deficient aromatic core is well-known to tune the outstanding optoelectronic properties of PDI derivatives. In this respect, the functionalization has been mostly addressed in bay-positions to halogenated derivatives through nucleophilic substitutions or metal-catalyzed coupling reactions. Being aware of the synthetic difficulties of obtaining the key intermediate 1-bromoPDI, we will present as an alternative in this review the potential of 1-nitroPDI: a powerful building block to access a large variety of PDI-based materials. |
first_indexed | 2024-12-11T02:15:00Z |
format | Article |
id | doaj.art-f390a5689bbc4db4a101148e9d9e9da2 |
institution | Directory Open Access Journal |
issn | 1420-3049 |
language | English |
last_indexed | 2024-12-11T02:15:00Z |
publishDate | 2020-03-01 |
publisher | MDPI AG |
record_format | Article |
series | Molecules |
spelling | doaj.art-f390a5689bbc4db4a101148e9d9e9da22022-12-22T01:24:12ZengMDPI AGMolecules1420-30492020-03-01256140210.3390/molecules25061402molecules25061402Nitro-Perylenediimide: An Emerging Building Block for the Synthesis of Functional Organic MaterialsLou Rocard0Antoine Goujon1Piétrick Hudhomme2Laboratoire MOLTECH-Anjou, UMR CNRS 6200, UNIV Angers, SFR MATRIX, 2 Bd Lavoisier, Angers CEDEX 49045, FranceLaboratoire MOLTECH-Anjou, UMR CNRS 6200, UNIV Angers, SFR MATRIX, 2 Bd Lavoisier, Angers CEDEX 49045, FranceLaboratoire MOLTECH-Anjou, UMR CNRS 6200, UNIV Angers, SFR MATRIX, 2 Bd Lavoisier, Angers CEDEX 49045, FrancePerylenediimide (PDI) is one of the most important classes of dyes and is intensively explored in the field of functional organic materials. The functionalization of this electron-deficient aromatic core is well-known to tune the outstanding optoelectronic properties of PDI derivatives. In this respect, the functionalization has been mostly addressed in bay-positions to halogenated derivatives through nucleophilic substitutions or metal-catalyzed coupling reactions. Being aware of the synthetic difficulties of obtaining the key intermediate 1-bromoPDI, we will present as an alternative in this review the potential of 1-nitroPDI: a powerful building block to access a large variety of PDI-based materials.https://www.mdpi.com/1420-3049/25/6/1402perylenediimidenitro grouporganic materials |
spellingShingle | Lou Rocard Antoine Goujon Piétrick Hudhomme Nitro-Perylenediimide: An Emerging Building Block for the Synthesis of Functional Organic Materials Molecules perylenediimide nitro group organic materials |
title | Nitro-Perylenediimide: An Emerging Building Block for the Synthesis of Functional Organic Materials |
title_full | Nitro-Perylenediimide: An Emerging Building Block for the Synthesis of Functional Organic Materials |
title_fullStr | Nitro-Perylenediimide: An Emerging Building Block for the Synthesis of Functional Organic Materials |
title_full_unstemmed | Nitro-Perylenediimide: An Emerging Building Block for the Synthesis of Functional Organic Materials |
title_short | Nitro-Perylenediimide: An Emerging Building Block for the Synthesis of Functional Organic Materials |
title_sort | nitro perylenediimide an emerging building block for the synthesis of functional organic materials |
topic | perylenediimide nitro group organic materials |
url | https://www.mdpi.com/1420-3049/25/6/1402 |
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