Nitro-Perylenediimide: An Emerging Building Block for the Synthesis of Functional Organic Materials

Perylenediimide (PDI) is one of the most important classes of dyes and is intensively explored in the field of functional organic materials. The functionalization of this electron-deficient aromatic core is well-known to tune the outstanding optoelectronic properties of PDI derivatives. In this resp...

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Main Authors: Lou Rocard, Antoine Goujon, Piétrick Hudhomme
Format: Article
Language:English
Published: MDPI AG 2020-03-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/25/6/1402
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author Lou Rocard
Antoine Goujon
Piétrick Hudhomme
author_facet Lou Rocard
Antoine Goujon
Piétrick Hudhomme
author_sort Lou Rocard
collection DOAJ
description Perylenediimide (PDI) is one of the most important classes of dyes and is intensively explored in the field of functional organic materials. The functionalization of this electron-deficient aromatic core is well-known to tune the outstanding optoelectronic properties of PDI derivatives. In this respect, the functionalization has been mostly addressed in bay-positions to halogenated derivatives through nucleophilic substitutions or metal-catalyzed coupling reactions. Being aware of the synthetic difficulties of obtaining the key intermediate 1-bromoPDI, we will present as an alternative in this review the potential of 1-nitroPDI: a powerful building block to access a large variety of PDI-based materials.
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spelling doaj.art-f390a5689bbc4db4a101148e9d9e9da22022-12-22T01:24:12ZengMDPI AGMolecules1420-30492020-03-01256140210.3390/molecules25061402molecules25061402Nitro-Perylenediimide: An Emerging Building Block for the Synthesis of Functional Organic MaterialsLou Rocard0Antoine Goujon1Piétrick Hudhomme2Laboratoire MOLTECH-Anjou, UMR CNRS 6200, UNIV Angers, SFR MATRIX, 2 Bd Lavoisier, Angers CEDEX 49045, FranceLaboratoire MOLTECH-Anjou, UMR CNRS 6200, UNIV Angers, SFR MATRIX, 2 Bd Lavoisier, Angers CEDEX 49045, FranceLaboratoire MOLTECH-Anjou, UMR CNRS 6200, UNIV Angers, SFR MATRIX, 2 Bd Lavoisier, Angers CEDEX 49045, FrancePerylenediimide (PDI) is one of the most important classes of dyes and is intensively explored in the field of functional organic materials. The functionalization of this electron-deficient aromatic core is well-known to tune the outstanding optoelectronic properties of PDI derivatives. In this respect, the functionalization has been mostly addressed in bay-positions to halogenated derivatives through nucleophilic substitutions or metal-catalyzed coupling reactions. Being aware of the synthetic difficulties of obtaining the key intermediate 1-bromoPDI, we will present as an alternative in this review the potential of 1-nitroPDI: a powerful building block to access a large variety of PDI-based materials.https://www.mdpi.com/1420-3049/25/6/1402perylenediimidenitro grouporganic materials
spellingShingle Lou Rocard
Antoine Goujon
Piétrick Hudhomme
Nitro-Perylenediimide: An Emerging Building Block for the Synthesis of Functional Organic Materials
Molecules
perylenediimide
nitro group
organic materials
title Nitro-Perylenediimide: An Emerging Building Block for the Synthesis of Functional Organic Materials
title_full Nitro-Perylenediimide: An Emerging Building Block for the Synthesis of Functional Organic Materials
title_fullStr Nitro-Perylenediimide: An Emerging Building Block for the Synthesis of Functional Organic Materials
title_full_unstemmed Nitro-Perylenediimide: An Emerging Building Block for the Synthesis of Functional Organic Materials
title_short Nitro-Perylenediimide: An Emerging Building Block for the Synthesis of Functional Organic Materials
title_sort nitro perylenediimide an emerging building block for the synthesis of functional organic materials
topic perylenediimide
nitro group
organic materials
url https://www.mdpi.com/1420-3049/25/6/1402
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