Bis[N5,N7-bis(pyridin-2-yl)-6,7-dihydro-5H-pyrrolo[3,4-b]pyrazine-5,7-diimine]cobalt(III) perchlorate acetonitrile disolvate
In the title complex, [Co(C16H10N7)2]ClO4·2CH3CN, the cation possesses twofold rotational symmetry. The CoIII ion is located on a twofold rotation axis and is octahedrally coordinated to two tridentate `pincer' ligands. The Cl atom of the perchlorate anion is located on a fourfold rotoinversion...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2018-05-01
|
| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S241431461800754X |
| _version_ | 1819048303184052224 |
|---|---|
| author | Maciej Posel Helen Stoeckli-Evans |
| author_facet | Maciej Posel Helen Stoeckli-Evans |
| author_sort | Maciej Posel |
| collection | DOAJ |
| description | In the title complex, [Co(C16H10N7)2]ClO4·2CH3CN, the cation possesses twofold rotational symmetry. The CoIII ion is located on a twofold rotation axis and is octahedrally coordinated to two tridentate `pincer' ligands. The Cl atom of the perchlorate anion is located on a fourfold rotoinversion axis. In the crystal, the cations are linked via C—H...O and C—H...N hydrogen bonds involving the perchlorate anion and the solvate acetonitrile molecules. These interactions lead to the formation of a supramolecular three-dimensional framework. |
| first_indexed | 2024-12-21T11:14:07Z |
| format | Article |
| id | doaj.art-f39ef5b3eb4d469fbe2c01a73950d93e |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-21T11:14:07Z |
| publishDate | 2018-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-f39ef5b3eb4d469fbe2c01a73950d93e2022-12-21T19:05:58ZengInternational Union of CrystallographyIUCrData2414-31462018-05-0135x18075410.1107/S241431461800754Xbh4036Bis[N5,N7-bis(pyridin-2-yl)-6,7-dihydro-5H-pyrrolo[3,4-b]pyrazine-5,7-diimine]cobalt(III) perchlorate acetonitrile disolvateMaciej Posel0Helen Stoeckli-Evans1Institute of Chemistry, University of Neuchâtel, Av de Bellevaux 51, CH-2000 Neuchâtel, SwitzerlandInstitute of Physics, University of Neuchâtel, rue Emile-Argand 11, CH-2000 Neuchâtel, SwitzerlandIn the title complex, [Co(C16H10N7)2]ClO4·2CH3CN, the cation possesses twofold rotational symmetry. The CoIII ion is located on a twofold rotation axis and is octahedrally coordinated to two tridentate `pincer' ligands. The Cl atom of the perchlorate anion is located on a fourfold rotoinversion axis. In the crystal, the cations are linked via C—H...O and C—H...N hydrogen bonds involving the perchlorate anion and the solvate acetonitrile molecules. These interactions lead to the formation of a supramolecular three-dimensional framework.http://scripts.iucr.org/cgi-bin/paper?S241431461800754Xcrystal structurepyrrolopyrazinepincer ligandisoindoline analoguecobalt(III)hydrogen bondingsupramolecular framework |
| spellingShingle | Maciej Posel Helen Stoeckli-Evans Bis[N5,N7-bis(pyridin-2-yl)-6,7-dihydro-5H-pyrrolo[3,4-b]pyrazine-5,7-diimine]cobalt(III) perchlorate acetonitrile disolvate IUCrData crystal structure pyrrolopyrazine pincer ligand isoindoline analogue cobalt(III) hydrogen bonding supramolecular framework |
| title | Bis[N5,N7-bis(pyridin-2-yl)-6,7-dihydro-5H-pyrrolo[3,4-b]pyrazine-5,7-diimine]cobalt(III) perchlorate acetonitrile disolvate |
| title_full | Bis[N5,N7-bis(pyridin-2-yl)-6,7-dihydro-5H-pyrrolo[3,4-b]pyrazine-5,7-diimine]cobalt(III) perchlorate acetonitrile disolvate |
| title_fullStr | Bis[N5,N7-bis(pyridin-2-yl)-6,7-dihydro-5H-pyrrolo[3,4-b]pyrazine-5,7-diimine]cobalt(III) perchlorate acetonitrile disolvate |
| title_full_unstemmed | Bis[N5,N7-bis(pyridin-2-yl)-6,7-dihydro-5H-pyrrolo[3,4-b]pyrazine-5,7-diimine]cobalt(III) perchlorate acetonitrile disolvate |
| title_short | Bis[N5,N7-bis(pyridin-2-yl)-6,7-dihydro-5H-pyrrolo[3,4-b]pyrazine-5,7-diimine]cobalt(III) perchlorate acetonitrile disolvate |
| title_sort | bis n5 n7 bis pyridin 2 yl 6 7 dihydro 5h pyrrolo 3 4 b pyrazine 5 7 diimine cobalt iii perchlorate acetonitrile disolvate |
| topic | crystal structure pyrrolopyrazine pincer ligand isoindoline analogue cobalt(III) hydrogen bonding supramolecular framework |
| url | http://scripts.iucr.org/cgi-bin/paper?S241431461800754X |
| work_keys_str_mv | AT maciejposel bisn5n7bispyridin2yl67dihydro5hpyrrolo34bpyrazine57diiminecobaltiiiperchlorateacetonitriledisolvate AT helenstoecklievans bisn5n7bispyridin2yl67dihydro5hpyrrolo34bpyrazine57diiminecobaltiiiperchlorateacetonitriledisolvate |