Bis[N5,N7-bis(pyridin-2-yl)-6,7-dihydro-5H-pyrrolo[3,4-b]pyrazine-5,7-diimine]cobalt(III) perchlorate acetonitrile disolvate

Bis[N5,N7-bis(pyridin-2-yl)-6,7-dihydro-5H-pyrrolo[3,4-b]pyrazine-5,7-diimine]cobalt(III) perchlorate acetonitrile disolvate

In the title complex, [Co(C16H10N7)2]ClO4·2CH3CN, the cation possesses twofold rotational symmetry. The CoIII ion is located on a twofold rotation axis and is octahedrally coordinated to two tridentate `pincer' ligands. The Cl atom of the perchlorate anion is located on a fourfold rotoinversion...

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Bibliographic Details
Main Authors: Maciej Posel, Helen Stoeckli-Evans
Format: Article
Language:English
Published: International Union of Crystallography 2018-05-01
Series:IUCrData
Subjects:
crystal structure
pyrrolopyrazine
pincer ligand
isoindoline analogue
cobalt(III)
hydrogen bonding
supramolecular framework
Online Access:http://scripts.iucr.org/cgi-bin/paper?S241431461800754X

Internet

http://scripts.iucr.org/cgi-bin/paper?S241431461800754X

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