Synthesis and spectroscopic studies of new leucine acid derivative with their metal complexes.
A new ligand N-[(acetyl amino)-thioxo methyl]leucine(ATL) are synthesized by reaction of acetyl-isothio cyanate with leucine acid. The ligand is characterized by elemental analysis, FT-IR and NMR spectra, some transition metal complex of this ligand were prepared and characterized by FT-IR, UV-visib...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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University of Anbar
2013-11-01
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| Series: | مجلة جامعة الانبار للعلوم الصرفة |
| Subjects: | |
| Online Access: | https://juaps.uoanbar.edu.iq/article_83185_6d835722fad13eaac62e1051533e357f.pdf |
| _version_ | 1827396276607516672 |
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| author | Muhammed Ahmed.Awaad Basima M.Sarhan Abdul Sattar Z.Khalaf |
| author_facet | Muhammed Ahmed.Awaad Basima M.Sarhan Abdul Sattar Z.Khalaf |
| author_sort | Muhammed Ahmed.Awaad |
| collection | DOAJ |
| description | A new ligand N-[(acetyl amino)-thioxo methyl]leucine(ATL) are synthesized by reaction of acetyl-isothio cyanate with leucine acid. The ligand is characterized by elemental analysis, FT-IR and NMR spectra, some transition metal complex of this ligand were prepared and characterized by FT-IR, UV-visible spectra, conductively measurements, magnatic suscpility, atomic absorption and determination of molar ration(M:L). from results obtained, the following formaula [M(ATL)2] where M+2 =(Mn, Fe, Co, Ni, Cu, Zn, Cd and Hg) and the proposed molecular structure for these complexes as tetrahedral geometry. |
| first_indexed | 2024-03-08T18:48:35Z |
| format | Article |
| id | doaj.art-f3aaf30a1004417f8d2e2e2125e4a66e |
| institution | Directory Open Access Journal |
| issn | 1991-8941 2706-6703 |
| language | English |
| last_indexed | 2024-03-08T18:48:35Z |
| publishDate | 2013-11-01 |
| publisher | University of Anbar |
| record_format | Article |
| series | مجلة جامعة الانبار للعلوم الصرفة |
| spelling | doaj.art-f3aaf30a1004417f8d2e2e2125e4a66e2023-12-28T21:56:51ZengUniversity of Anbarمجلة جامعة الانبار للعلوم الصرفة1991-89412706-67032013-11-0171667310.37652/juaps.2013.8318583185Synthesis and spectroscopic studies of new leucine acid derivative with their metal complexes.Muhammed Ahmed.Awaad0Basima M.Sarhan1Abdul Sattar Z.Khalaf2University of Anbar- Collage of Education for pure sciencesUniversity Of Baghdad-Ibn-Al-Haitham Education collage.University of Anbar- Collage of Education for pure sciencesA new ligand N-[(acetyl amino)-thioxo methyl]leucine(ATL) are synthesized by reaction of acetyl-isothio cyanate with leucine acid. The ligand is characterized by elemental analysis, FT-IR and NMR spectra, some transition metal complex of this ligand were prepared and characterized by FT-IR, UV-visible spectra, conductively measurements, magnatic suscpility, atomic absorption and determination of molar ration(M:L). from results obtained, the following formaula [M(ATL)2] where M+2 =(Mn, Fe, Co, Ni, Cu, Zn, Cd and Hg) and the proposed molecular structure for these complexes as tetrahedral geometry.https://juaps.uoanbar.edu.iq/article_83185_6d835722fad13eaac62e1051533e357f.pdfleucineacetyl isothiocyanatetransition metals |
| spellingShingle | Muhammed Ahmed.Awaad Basima M.Sarhan Abdul Sattar Z.Khalaf Synthesis and spectroscopic studies of new leucine acid derivative with their metal complexes. مجلة جامعة الانبار للعلوم الصرفة leucine acetyl isothiocyanate transition metals |
| title | Synthesis and spectroscopic studies of new leucine acid derivative with their metal complexes. |
| title_full | Synthesis and spectroscopic studies of new leucine acid derivative with their metal complexes. |
| title_fullStr | Synthesis and spectroscopic studies of new leucine acid derivative with their metal complexes. |
| title_full_unstemmed | Synthesis and spectroscopic studies of new leucine acid derivative with their metal complexes. |
| title_short | Synthesis and spectroscopic studies of new leucine acid derivative with their metal complexes. |
| title_sort | synthesis and spectroscopic studies of new leucine acid derivative with their metal complexes |
| topic | leucine acetyl isothiocyanate transition metals |
| url | https://juaps.uoanbar.edu.iq/article_83185_6d835722fad13eaac62e1051533e357f.pdf |
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