Crystal structure of bis(cyclohexylammonium) diphenyldioxalatostannate(IV)
Reaction of oxalic acid and diphenyltin dichloride in the presence of cyclohexylamine led to the formation of the title salt, (C6H14N)2[Sn(C6H5)2(C2O4)2]. The dianion is made up from an Sn(C6H5)2 moiety cis-coordinated by two chelating oxalate anions, leading to an overall distorted octahedral coord...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2015-02-01
|
| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989014027716 |
| _version_ | 1798024442849263616 |
|---|---|
| author | Modou Sarr Aminata Diasse-Sarr Libasse Diop Laurent Plasseraud Hélène Cattey |
| author_facet | Modou Sarr Aminata Diasse-Sarr Libasse Diop Laurent Plasseraud Hélène Cattey |
| author_sort | Modou Sarr |
| collection | DOAJ |
| description | Reaction of oxalic acid and diphenyltin dichloride in the presence of cyclohexylamine led to the formation of the title salt, (C6H14N)2[Sn(C6H5)2(C2O4)2]. The dianion is made up from an Sn(C6H5)2 moiety cis-coordinated by two chelating oxalate anions, leading to an overall distorted octahedral coordination geometry of the SnIV atom. The negative charges are compensated by two surrounding cyclohexylammonium cations adopting chair conformations each. In the crystal, anions and cations are linked via a network of N—H...O hydrogen bonds into a layered arrangement parallel to (101). |
| first_indexed | 2024-04-11T18:03:41Z |
| format | Article |
| id | doaj.art-f3ad4947832947e5a4d6c6109a05a72c |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-11T18:03:41Z |
| publishDate | 2015-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-f3ad4947832947e5a4d6c6109a05a72c2022-12-22T04:10:25ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-02-0171215115310.1107/S2056989014027716wm5103Crystal structure of bis(cyclohexylammonium) diphenyldioxalatostannate(IV)Modou Sarr0Aminata Diasse-Sarr1Libasse Diop2Laurent Plasseraud3Hélène Cattey4Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, SenegalLaboratoire de Chimie Minérale et Analytique (LACHIMIA), Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, SenegalLaboratoire de Chimie Minérale et Analytique (LACHIMIA), Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, SenegalICMUB UMR 6302, Université de Bourgogne, Faculté des Sciences, 9 avenue Alain Savary, 21000 Dijon, FranceICMUB UMR 6302, Université de Bourgogne, Faculté des Sciences, 9 avenue Alain Savary, 21000 Dijon, FranceReaction of oxalic acid and diphenyltin dichloride in the presence of cyclohexylamine led to the formation of the title salt, (C6H14N)2[Sn(C6H5)2(C2O4)2]. The dianion is made up from an Sn(C6H5)2 moiety cis-coordinated by two chelating oxalate anions, leading to an overall distorted octahedral coordination geometry of the SnIV atom. The negative charges are compensated by two surrounding cyclohexylammonium cations adopting chair conformations each. In the crystal, anions and cations are linked via a network of N—H...O hydrogen bonds into a layered arrangement parallel to (101).http://scripts.iucr.org/cgi-bin/paper?S2056989014027716crystal structureorganotin(IV) compoundoxalate ligandscis arrangementcyclohexylammoniumN—H...O hydrogen bonding |
| spellingShingle | Modou Sarr Aminata Diasse-Sarr Libasse Diop Laurent Plasseraud Hélène Cattey Crystal structure of bis(cyclohexylammonium) diphenyldioxalatostannate(IV) Acta Crystallographica Section E: Crystallographic Communications crystal structure organotin(IV) compound oxalate ligands cis arrangement cyclohexylammonium N—H...O hydrogen bonding |
| title | Crystal structure of bis(cyclohexylammonium) diphenyldioxalatostannate(IV) |
| title_full | Crystal structure of bis(cyclohexylammonium) diphenyldioxalatostannate(IV) |
| title_fullStr | Crystal structure of bis(cyclohexylammonium) diphenyldioxalatostannate(IV) |
| title_full_unstemmed | Crystal structure of bis(cyclohexylammonium) diphenyldioxalatostannate(IV) |
| title_short | Crystal structure of bis(cyclohexylammonium) diphenyldioxalatostannate(IV) |
| title_sort | crystal structure of bis cyclohexylammonium diphenyldioxalatostannate iv |
| topic | crystal structure organotin(IV) compound oxalate ligands cis arrangement cyclohexylammonium N—H...O hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989014027716 |
| work_keys_str_mv | AT modousarr crystalstructureofbiscyclohexylammoniumdiphenyldioxalatostannateiv AT aminatadiassesarr crystalstructureofbiscyclohexylammoniumdiphenyldioxalatostannateiv AT libassediop crystalstructureofbiscyclohexylammoniumdiphenyldioxalatostannateiv AT laurentplasseraud crystalstructureofbiscyclohexylammoniumdiphenyldioxalatostannateiv AT helenecattey crystalstructureofbiscyclohexylammoniumdiphenyldioxalatostannateiv |