Isolation of Responsive Elements of Planar Multi-Element Photodiodes

In the mass production of multi-element silicon p-i-n photodiodes, the problem of systematic rejection of products due to a decrease in the insulation resistance between the active elements of photodetectors has been revealed. The purpose of this work is to study the causes of insulation resistance...

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Main Author: Mykola S. Kukurudziak
Format: Article
Language:English
Published: V.N. Karazin Kharkiv National University Publishing 2023-09-01
Series:East European Journal of Physics
Subjects:
Online Access:https://periodicals.karazin.ua/eejp/article/view/22026
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author Mykola S. Kukurudziak
author_facet Mykola S. Kukurudziak
author_sort Mykola S. Kukurudziak
collection DOAJ
description In the mass production of multi-element silicon p-i-n photodiodes, the problem of systematic rejection of products due to a decrease in the insulation resistance between the active elements of photodetectors has been revealed. The purpose of this work is to study the causes of insulation resistance degradation and to establish optimal methods for avoiding this phenomenon. A comparative analysis of three insulation methods was carried out: classical insulation by the surface of a non-conductive substrate and a dielectric layer; insulation by means of mesaprofile grooves with a dielectric film; insulation by means of areas of limitation of surface leakage channels isotypic with the substrate material (in this case, p+-type) formed in the gaps between active elements. The study found that the reason for the deterioration of the insulation resistance between the active elements of photodiodes is the presence of conductive inversion channels at the Si-SiO2 interface due to the use of silicon with high resistivity. One mechanism for the formation of inversion channels is the redistribution of impurities in the masking oxide (in particular, phosphorus) and their diffusion to the interface during thermal operations. Another mechanism for the formation of inversion layers is the diffusion of boron from silicon into SiO2 during heat treatment due to the fact that the boron segregation coefficient is less than one. In the manufacture of samples with insulation using non-conductive areas of the substrate, a decrease in insulation resistance was observed as the technological route was performed (after each subsequent operation, the resistance degraded). The degree of degradation can be reduced by reducing the duration of thermal operations. It has been shown that reducing the thickness of the masking oxide causes a decrease in insulation resistance. When using mesa-technology, it is possible to increase the insulation resistance by eliminating the high-temperature oxidation operation and, in fact, due to the absence of a masking coating during phosphorus deposition. Insulation by means of p+-type areas in the gaps between the active elements    allows to obtain the highest insulation resistance values. The formation of these regions with a width of 100 μm in the gaps with a width of 200 μm allowed us to obtain an insulation resistance of 25-30 MΩ. To ensure the insulation of the active elements of photodiodes by this method, two thermal operations are added to the technological route. The number of thermal operations can be reduced by doping the entire silicon surface with a low boron concentration before forming a masking coating.
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spelling doaj.art-f3c3aba845d34d25861e61b8a2a173372023-09-10T16:51:57ZengV.N. Karazin Kharkiv National University PublishingEast European Journal of Physics2312-43342312-45392023-09-01343444010.26565/2312-4334-2023-3-4822026Isolation of Responsive Elements of Planar Multi-Element PhotodiodesMykola S. Kukurudziak0Rhythm Optoelectronics Shareholding Company, Chernivtsi, Ukraine; Yuriy Fedkovych Chernivtsi National University, Chernivtsi, UkraineIn the mass production of multi-element silicon p-i-n photodiodes, the problem of systematic rejection of products due to a decrease in the insulation resistance between the active elements of photodetectors has been revealed. The purpose of this work is to study the causes of insulation resistance degradation and to establish optimal methods for avoiding this phenomenon. A comparative analysis of three insulation methods was carried out: classical insulation by the surface of a non-conductive substrate and a dielectric layer; insulation by means of mesaprofile grooves with a dielectric film; insulation by means of areas of limitation of surface leakage channels isotypic with the substrate material (in this case, p+-type) formed in the gaps between active elements. The study found that the reason for the deterioration of the insulation resistance between the active elements of photodiodes is the presence of conductive inversion channels at the Si-SiO2 interface due to the use of silicon with high resistivity. One mechanism for the formation of inversion channels is the redistribution of impurities in the masking oxide (in particular, phosphorus) and their diffusion to the interface during thermal operations. Another mechanism for the formation of inversion layers is the diffusion of boron from silicon into SiO2 during heat treatment due to the fact that the boron segregation coefficient is less than one. In the manufacture of samples with insulation using non-conductive areas of the substrate, a decrease in insulation resistance was observed as the technological route was performed (after each subsequent operation, the resistance degraded). The degree of degradation can be reduced by reducing the duration of thermal operations. It has been shown that reducing the thickness of the masking oxide causes a decrease in insulation resistance. When using mesa-technology, it is possible to increase the insulation resistance by eliminating the high-temperature oxidation operation and, in fact, due to the absence of a masking coating during phosphorus deposition. Insulation by means of p+-type areas in the gaps between the active elements    allows to obtain the highest insulation resistance values. The formation of these regions with a width of 100 μm in the gaps with a width of 200 μm allowed us to obtain an insulation resistance of 25-30 MΩ. To ensure the insulation of the active elements of photodiodes by this method, two thermal operations are added to the technological route. The number of thermal operations can be reduced by doping the entire silicon surface with a low boron concentration before forming a masking coating.https://periodicals.karazin.ua/eejp/article/view/22026siliconphotodiodeinsulation resistancesilicon oxide
spellingShingle Mykola S. Kukurudziak
Isolation of Responsive Elements of Planar Multi-Element Photodiodes
East European Journal of Physics
silicon
photodiode
insulation resistance
silicon oxide
title Isolation of Responsive Elements of Planar Multi-Element Photodiodes
title_full Isolation of Responsive Elements of Planar Multi-Element Photodiodes
title_fullStr Isolation of Responsive Elements of Planar Multi-Element Photodiodes
title_full_unstemmed Isolation of Responsive Elements of Planar Multi-Element Photodiodes
title_short Isolation of Responsive Elements of Planar Multi-Element Photodiodes
title_sort isolation of responsive elements of planar multi element photodiodes
topic silicon
photodiode
insulation resistance
silicon oxide
url https://periodicals.karazin.ua/eejp/article/view/22026
work_keys_str_mv AT mykolaskukurudziak isolationofresponsiveelementsofplanarmultielementphotodiodes