Effects of Mineral Composition on Movable Fluid Porosity in Micro-Nanoscale Porous Media

In natural micro-nanoscale porous media, the movable fluid porosity can effectively represent storage and permeable properties, but various mineral compositions have complicated effects on it. Taking saline lacustrine shale as an example, this study researched the effects of mineral composition on m...

Full description

Bibliographic Details
Main Authors: Quanqi Dai, Yangwen Zhu, Yingfu He, Rui Wang, Da Zheng, Yinbang Zhou, Yunfeng Liu, Guiwen Wang, Hao Wu
Format: Article
Language:English
Published: MDPI AG 2023-07-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/16/13/5166
_version_ 1797591803950530560
author Quanqi Dai
Yangwen Zhu
Yingfu He
Rui Wang
Da Zheng
Yinbang Zhou
Yunfeng Liu
Guiwen Wang
Hao Wu
author_facet Quanqi Dai
Yangwen Zhu
Yingfu He
Rui Wang
Da Zheng
Yinbang Zhou
Yunfeng Liu
Guiwen Wang
Hao Wu
author_sort Quanqi Dai
collection DOAJ
description In natural micro-nanoscale porous media, the movable fluid porosity can effectively represent storage and permeable properties, but various mineral compositions have complicated effects on it. Taking saline lacustrine shale as an example, this study researched the effects of mineral composition on movable fluid porosity, based on nuclear magnetic resonance (NMR), focused ion beam (FIB), and x-ray diffraction (XRD) experiments. The results show that movable fluid porosity exhibits a stronger dependence on porosity than movable fluid saturation does. Micropores (<100 nm) and macropores (>1000 nm) are mostly developed in silicate and gypsum minerals, and have a highly heterogeneous distribution. In contrast, carbonate intercrystalline pores are dominated by mesopores (100−1000 nm), and behave strongly heterogeneously. Many mesopores play a positive role in generating highly movable fluid porosity, but the development of micropores and macropores is not conducive to an increase in movable fluid porosity. Overall, a significant negative effect is observed between silicate mineral content and movable fluid porosity, and carbonate mineral content has a strong positive effect on movable fluid porosity, whereas movable fluid porosity exhibits a relatively small reduction with an increase in the gypsum.
first_indexed 2024-03-11T01:42:35Z
format Article
id doaj.art-f3ff03cd539e463ea94a74162f83fb35
institution Directory Open Access Journal
issn 1996-1073
language English
last_indexed 2024-03-11T01:42:35Z
publishDate 2023-07-01
publisher MDPI AG
record_format Article
series Energies
spelling doaj.art-f3ff03cd539e463ea94a74162f83fb352023-11-18T16:31:23ZengMDPI AGEnergies1996-10732023-07-011613516610.3390/en16135166Effects of Mineral Composition on Movable Fluid Porosity in Micro-Nanoscale Porous MediaQuanqi Dai0Yangwen Zhu1Yingfu He2Rui Wang3Da Zheng4Yinbang Zhou5Yunfeng Liu6Guiwen Wang7Hao Wu8State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Beijing 102206, ChinaState Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Beijing 102206, ChinaState Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Beijing 102206, ChinaState Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Beijing 102206, ChinaResearch Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, ChinaState Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Beijing 102206, ChinaState Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Beijing 102206, ChinaCollege of Geosciences, China University of Petroleum—Beijing, Beijing 102249, ChinaSchool of Earth Sciences, Lanzhou University, Lanzhou 730000, ChinaIn natural micro-nanoscale porous media, the movable fluid porosity can effectively represent storage and permeable properties, but various mineral compositions have complicated effects on it. Taking saline lacustrine shale as an example, this study researched the effects of mineral composition on movable fluid porosity, based on nuclear magnetic resonance (NMR), focused ion beam (FIB), and x-ray diffraction (XRD) experiments. The results show that movable fluid porosity exhibits a stronger dependence on porosity than movable fluid saturation does. Micropores (<100 nm) and macropores (>1000 nm) are mostly developed in silicate and gypsum minerals, and have a highly heterogeneous distribution. In contrast, carbonate intercrystalline pores are dominated by mesopores (100−1000 nm), and behave strongly heterogeneously. Many mesopores play a positive role in generating highly movable fluid porosity, but the development of micropores and macropores is not conducive to an increase in movable fluid porosity. Overall, a significant negative effect is observed between silicate mineral content and movable fluid porosity, and carbonate mineral content has a strong positive effect on movable fluid porosity, whereas movable fluid porosity exhibits a relatively small reduction with an increase in the gypsum.https://www.mdpi.com/1996-1073/16/13/5166micro-nanoscale porous mediamovable fluid porositymineral compositionsaline lacustrineshale
spellingShingle Quanqi Dai
Yangwen Zhu
Yingfu He
Rui Wang
Da Zheng
Yinbang Zhou
Yunfeng Liu
Guiwen Wang
Hao Wu
Effects of Mineral Composition on Movable Fluid Porosity in Micro-Nanoscale Porous Media
Energies
micro-nanoscale porous media
movable fluid porosity
mineral composition
saline lacustrine
shale
title Effects of Mineral Composition on Movable Fluid Porosity in Micro-Nanoscale Porous Media
title_full Effects of Mineral Composition on Movable Fluid Porosity in Micro-Nanoscale Porous Media
title_fullStr Effects of Mineral Composition on Movable Fluid Porosity in Micro-Nanoscale Porous Media
title_full_unstemmed Effects of Mineral Composition on Movable Fluid Porosity in Micro-Nanoscale Porous Media
title_short Effects of Mineral Composition on Movable Fluid Porosity in Micro-Nanoscale Porous Media
title_sort effects of mineral composition on movable fluid porosity in micro nanoscale porous media
topic micro-nanoscale porous media
movable fluid porosity
mineral composition
saline lacustrine
shale
url https://www.mdpi.com/1996-1073/16/13/5166
work_keys_str_mv AT quanqidai effectsofmineralcompositiononmovablefluidporosityinmicronanoscaleporousmedia
AT yangwenzhu effectsofmineralcompositiononmovablefluidporosityinmicronanoscaleporousmedia
AT yingfuhe effectsofmineralcompositiononmovablefluidporosityinmicronanoscaleporousmedia
AT ruiwang effectsofmineralcompositiononmovablefluidporosityinmicronanoscaleporousmedia
AT dazheng effectsofmineralcompositiononmovablefluidporosityinmicronanoscaleporousmedia
AT yinbangzhou effectsofmineralcompositiononmovablefluidporosityinmicronanoscaleporousmedia
AT yunfengliu effectsofmineralcompositiononmovablefluidporosityinmicronanoscaleporousmedia
AT guiwenwang effectsofmineralcompositiononmovablefluidporosityinmicronanoscaleporousmedia
AT haowu effectsofmineralcompositiononmovablefluidporosityinmicronanoscaleporousmedia