Bimolecular recombination in methylammonium lead triiodide perovskite is an inverse absorption process
Radiative bimolecular processes will dominate charge-carrier recombination in hybrid perovskite solar cells operating near the Shockley-Queisser limit. Here, the authors show that such processes are the inverse of absorption and increase as distribution functions sharpen towards lower temperatures.
| Main Authors: | , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2018-01-01
|
| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-017-02670-2 |
| _version_ | 1818842231750000640 |
|---|---|
| author | Christopher L. Davies Marina R. Filip Jay B. Patel Timothy W. Crothers Carla Verdi Adam D. Wright Rebecca L. Milot Feliciano Giustino Michael B. Johnston Laura M. Herz |
| author_facet | Christopher L. Davies Marina R. Filip Jay B. Patel Timothy W. Crothers Carla Verdi Adam D. Wright Rebecca L. Milot Feliciano Giustino Michael B. Johnston Laura M. Herz |
| author_sort | Christopher L. Davies |
| collection | DOAJ |
| description | Radiative bimolecular processes will dominate charge-carrier recombination in hybrid perovskite solar cells operating near the Shockley-Queisser limit. Here, the authors show that such processes are the inverse of absorption and increase as distribution functions sharpen towards lower temperatures. |
| first_indexed | 2024-12-19T04:38:41Z |
| format | Article |
| id | doaj.art-f408a141d59b4f4782e4e1bd11ded0a4 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-19T04:38:41Z |
| publishDate | 2018-01-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-f408a141d59b4f4782e4e1bd11ded0a42022-12-21T20:35:41ZengNature PortfolioNature Communications2041-17232018-01-01911910.1038/s41467-017-02670-2Bimolecular recombination in methylammonium lead triiodide perovskite is an inverse absorption processChristopher L. Davies0Marina R. Filip1Jay B. Patel2Timothy W. Crothers3Carla Verdi4Adam D. Wright5Rebecca L. Milot6Feliciano Giustino7Michael B. Johnston8Laura M. Herz9Department of Physics, University of Oxford, Clarendon LaboratoryDepartment of Materials, University of OxfordDepartment of Physics, University of Oxford, Clarendon LaboratoryDepartment of Physics, University of Oxford, Clarendon LaboratoryDepartment of Materials, University of OxfordDepartment of Physics, University of Oxford, Clarendon LaboratoryDepartment of Physics, University of Oxford, Clarendon LaboratoryDepartment of Materials, University of OxfordDepartment of Physics, University of Oxford, Clarendon LaboratoryDepartment of Physics, University of Oxford, Clarendon LaboratoryRadiative bimolecular processes will dominate charge-carrier recombination in hybrid perovskite solar cells operating near the Shockley-Queisser limit. Here, the authors show that such processes are the inverse of absorption and increase as distribution functions sharpen towards lower temperatures.https://doi.org/10.1038/s41467-017-02670-2 |
| spellingShingle | Christopher L. Davies Marina R. Filip Jay B. Patel Timothy W. Crothers Carla Verdi Adam D. Wright Rebecca L. Milot Feliciano Giustino Michael B. Johnston Laura M. Herz Bimolecular recombination in methylammonium lead triiodide perovskite is an inverse absorption process Nature Communications |
| title | Bimolecular recombination in methylammonium lead triiodide perovskite is an inverse absorption process |
| title_full | Bimolecular recombination in methylammonium lead triiodide perovskite is an inverse absorption process |
| title_fullStr | Bimolecular recombination in methylammonium lead triiodide perovskite is an inverse absorption process |
| title_full_unstemmed | Bimolecular recombination in methylammonium lead triiodide perovskite is an inverse absorption process |
| title_short | Bimolecular recombination in methylammonium lead triiodide perovskite is an inverse absorption process |
| title_sort | bimolecular recombination in methylammonium lead triiodide perovskite is an inverse absorption process |
| url | https://doi.org/10.1038/s41467-017-02670-2 |
| work_keys_str_mv | AT christopherldavies bimolecularrecombinationinmethylammoniumleadtriiodideperovskiteisaninverseabsorptionprocess AT marinarfilip bimolecularrecombinationinmethylammoniumleadtriiodideperovskiteisaninverseabsorptionprocess AT jaybpatel bimolecularrecombinationinmethylammoniumleadtriiodideperovskiteisaninverseabsorptionprocess AT timothywcrothers bimolecularrecombinationinmethylammoniumleadtriiodideperovskiteisaninverseabsorptionprocess AT carlaverdi bimolecularrecombinationinmethylammoniumleadtriiodideperovskiteisaninverseabsorptionprocess AT adamdwright bimolecularrecombinationinmethylammoniumleadtriiodideperovskiteisaninverseabsorptionprocess AT rebeccalmilot bimolecularrecombinationinmethylammoniumleadtriiodideperovskiteisaninverseabsorptionprocess AT felicianogiustino bimolecularrecombinationinmethylammoniumleadtriiodideperovskiteisaninverseabsorptionprocess AT michaelbjohnston bimolecularrecombinationinmethylammoniumleadtriiodideperovskiteisaninverseabsorptionprocess AT lauramherz bimolecularrecombinationinmethylammoniumleadtriiodideperovskiteisaninverseabsorptionprocess |