CuO/CaO mediated synthesis of amino-1,8-naphthalimides from the nitro analogues
Amino-1,8-naphthalimides are a sought-after class of materials due to their optoelectronic properties. This work demonstrates the application of CuO/CaO for a chemoselective synthesis of amino-1,8-naphthalimide fluorophores from the corresponding nitro-analogues with 100% conversion and selectivity....
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| Format: | Article |
| Language: | English |
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Elsevier
2022-01-01
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| Series: | Results in Chemistry |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2211715622001497 |
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| author | Karuppusamy Rajendran Ananthu Shanmughan Pandurangan Nanjan Deepak Krishnan Balaji Sankarasekaran Shanmugaraju Dinesh Jagadeesan |
| author_facet | Karuppusamy Rajendran Ananthu Shanmughan Pandurangan Nanjan Deepak Krishnan Balaji Sankarasekaran Shanmugaraju Dinesh Jagadeesan |
| author_sort | Karuppusamy Rajendran |
| collection | DOAJ |
| description | Amino-1,8-naphthalimides are a sought-after class of materials due to their optoelectronic properties. This work demonstrates the application of CuO/CaO for a chemoselective synthesis of amino-1,8-naphthalimide fluorophores from the corresponding nitro-analogues with 100% conversion and selectivity. The reaction was completed in 10 min in isopropyl alcohol using hydrazine hydrate as a reducing agent at 80 °C. The material was characterized using XRD, FT-IR, SEM, TEM, and adsorption techniques. The product, 4-amino-1,8-naphthalimides, was characterized by using NMR (1H and 13C), LCMS, and photophysical properties were measured in DCM at 298 K. |
| first_indexed | 2024-04-12T01:41:14Z |
| format | Article |
| id | doaj.art-f41249d07fd14704be52726441f6da55 |
| institution | Directory Open Access Journal |
| issn | 2211-7156 |
| language | English |
| last_indexed | 2024-04-12T01:41:14Z |
| publishDate | 2022-01-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Results in Chemistry |
| spelling | doaj.art-f41249d07fd14704be52726441f6da552022-12-22T03:53:12ZengElsevierResults in Chemistry2211-71562022-01-014100430CuO/CaO mediated synthesis of amino-1,8-naphthalimides from the nitro analoguesKaruppusamy Rajendran0Ananthu Shanmughan1Pandurangan Nanjan2Deepak Krishnan Balaji3Sankarasekaran Shanmugaraju4Dinesh Jagadeesan5Department of Chemistry, Indian Institute of Technology Palakkad, Ahalia Integrated Campus, Kozhippara, Palakkad 678 557, IndiaDepartment of Chemistry, Indian Institute of Technology Palakkad, Ahalia Integrated Campus, Kozhippara, Palakkad 678 557, IndiaDepartment of Chemistry, Indian Institute of Technology Palakkad, Ahalia Integrated Campus, Kozhippara, Palakkad 678 557, IndiaDepartment of Chemistry, Indian Institute of Technology Palakkad, Ahalia Integrated Campus, Kozhippara, Palakkad 678 557, IndiaDepartment of Chemistry, Indian Institute of Technology Palakkad, Ahalia Integrated Campus, Kozhippara, Palakkad 678 557, India; Corresponding authors at: Department of Chemistry, Indian Institute of Technology Palakkad, Ahalia Integrated Campus, Kozhippara, Palakkad 678 557, India (D. Jagadeesan).Department of Chemistry, Indian Institute of Technology Palakkad, Ahalia Integrated Campus, Kozhippara, Palakkad 678 557, India; Environmental Sciences and Sustainable Engineering Center (ESSENCE), Indian Institute of Technology Palakkad, Ahalia Integrated Campus, Kozhippara, Palakkad 678 557, India; Corresponding authors at: Department of Chemistry, Indian Institute of Technology Palakkad, Ahalia Integrated Campus, Kozhippara, Palakkad 678 557, India (D. Jagadeesan).Amino-1,8-naphthalimides are a sought-after class of materials due to their optoelectronic properties. This work demonstrates the application of CuO/CaO for a chemoselective synthesis of amino-1,8-naphthalimide fluorophores from the corresponding nitro-analogues with 100% conversion and selectivity. The reaction was completed in 10 min in isopropyl alcohol using hydrazine hydrate as a reducing agent at 80 °C. The material was characterized using XRD, FT-IR, SEM, TEM, and adsorption techniques. The product, 4-amino-1,8-naphthalimides, was characterized by using NMR (1H and 13C), LCMS, and photophysical properties were measured in DCM at 298 K.http://www.sciencedirect.com/science/article/pii/S2211715622001497Solid reagentNaphthalimideCuO/CaOReductionSolvatochromism |
| spellingShingle | Karuppusamy Rajendran Ananthu Shanmughan Pandurangan Nanjan Deepak Krishnan Balaji Sankarasekaran Shanmugaraju Dinesh Jagadeesan CuO/CaO mediated synthesis of amino-1,8-naphthalimides from the nitro analogues Results in Chemistry Solid reagent Naphthalimide CuO/CaO Reduction Solvatochromism |
| title | CuO/CaO mediated synthesis of amino-1,8-naphthalimides from the nitro analogues |
| title_full | CuO/CaO mediated synthesis of amino-1,8-naphthalimides from the nitro analogues |
| title_fullStr | CuO/CaO mediated synthesis of amino-1,8-naphthalimides from the nitro analogues |
| title_full_unstemmed | CuO/CaO mediated synthesis of amino-1,8-naphthalimides from the nitro analogues |
| title_short | CuO/CaO mediated synthesis of amino-1,8-naphthalimides from the nitro analogues |
| title_sort | cuo cao mediated synthesis of amino 1 8 naphthalimides from the nitro analogues |
| topic | Solid reagent Naphthalimide CuO/CaO Reduction Solvatochromism |
| url | http://www.sciencedirect.com/science/article/pii/S2211715622001497 |
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