Dimethyl 2-{[2-(2-Methoxy-1-methoxycarbonyl-2-oxoethyl)-4,5,7-trimethoxy-3-(2,4,5-trimethoxyphenyl)-2,3-dihydro-1<i>H</i>-inden-1-yl]methyl}malonate
A simple synthetic approach to dimethyl 2-{[2-(2-methoxy-1-methoxycarbonyl-2-oxoethyl)-4,5,7-trimethoxy-3-(2,4,5-trimethoxyphenyl)-2,3-dihydro-1<i>H</i>-inden-1-yl]methyl}malonate has been developed, based on a B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>...
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MDPI AG
2020-01-01
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| Online Access: | https://www.mdpi.com/1422-8599/2020/1/M1107 |
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| author | Maksim A. Boichenko Alexey O. Chagarovskiy Victor B. Rybakov Igor V. Trushkov Olga A. Ivanova |
| author_facet | Maksim A. Boichenko Alexey O. Chagarovskiy Victor B. Rybakov Igor V. Trushkov Olga A. Ivanova |
| author_sort | Maksim A. Boichenko |
| collection | DOAJ |
| description | A simple synthetic approach to dimethyl 2-{[2-(2-methoxy-1-methoxycarbonyl-2-oxoethyl)-4,5,7-trimethoxy-3-(2,4,5-trimethoxyphenyl)-2,3-dihydro-1<i>H</i>-inden-1-yl]methyl}malonate has been developed, based on a B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>-induced domino dimerization of 2-(2,4,5-trimethoxyphenyl)cyclopropane-1,1-diester. |
| first_indexed | 2024-12-22T03:53:48Z |
| format | Article |
| id | doaj.art-f41842e1c60d4d009fc7480216f2f408 |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-12-22T03:53:48Z |
| publishDate | 2020-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-f41842e1c60d4d009fc7480216f2f4082022-12-21T18:39:57ZengMDPI AGMolbank1422-85992020-01-0120201M110710.3390/M1107M1107Dimethyl 2-{[2-(2-Methoxy-1-methoxycarbonyl-2-oxoethyl)-4,5,7-trimethoxy-3-(2,4,5-trimethoxyphenyl)-2,3-dihydro-1<i>H</i>-inden-1-yl]methyl}malonateMaksim A. Boichenko0Alexey O. Chagarovskiy1Victor B. Rybakov2Igor V. Trushkov3Olga A. Ivanova4Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie gory 1-3, Moscow 119991, RussiaN. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky pr. 47, Moscow 119991, RussiaDepartment of Chemistry, M. V. Lomonosov Moscow State University, Leninskie gory 1-3, Moscow 119991, RussiaN. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky pr. 47, Moscow 119991, RussiaDepartment of Chemistry, M. V. Lomonosov Moscow State University, Leninskie gory 1-3, Moscow 119991, RussiaA simple synthetic approach to dimethyl 2-{[2-(2-methoxy-1-methoxycarbonyl-2-oxoethyl)-4,5,7-trimethoxy-3-(2,4,5-trimethoxyphenyl)-2,3-dihydro-1<i>H</i>-inden-1-yl]methyl}malonate has been developed, based on a B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>-induced domino dimerization of 2-(2,4,5-trimethoxyphenyl)cyclopropane-1,1-diester.https://www.mdpi.com/1422-8599/2020/1/M1107donor–acceptor cyclopropane2,3-dihydro-1<i>h</i>-indenedimerization reactiondomino process |
| spellingShingle | Maksim A. Boichenko Alexey O. Chagarovskiy Victor B. Rybakov Igor V. Trushkov Olga A. Ivanova Dimethyl 2-{[2-(2-Methoxy-1-methoxycarbonyl-2-oxoethyl)-4,5,7-trimethoxy-3-(2,4,5-trimethoxyphenyl)-2,3-dihydro-1<i>H</i>-inden-1-yl]methyl}malonate Molbank donor–acceptor cyclopropane 2,3-dihydro-1<i>h</i>-indene dimerization reaction domino process |
| title | Dimethyl 2-{[2-(2-Methoxy-1-methoxycarbonyl-2-oxoethyl)-4,5,7-trimethoxy-3-(2,4,5-trimethoxyphenyl)-2,3-dihydro-1<i>H</i>-inden-1-yl]methyl}malonate |
| title_full | Dimethyl 2-{[2-(2-Methoxy-1-methoxycarbonyl-2-oxoethyl)-4,5,7-trimethoxy-3-(2,4,5-trimethoxyphenyl)-2,3-dihydro-1<i>H</i>-inden-1-yl]methyl}malonate |
| title_fullStr | Dimethyl 2-{[2-(2-Methoxy-1-methoxycarbonyl-2-oxoethyl)-4,5,7-trimethoxy-3-(2,4,5-trimethoxyphenyl)-2,3-dihydro-1<i>H</i>-inden-1-yl]methyl}malonate |
| title_full_unstemmed | Dimethyl 2-{[2-(2-Methoxy-1-methoxycarbonyl-2-oxoethyl)-4,5,7-trimethoxy-3-(2,4,5-trimethoxyphenyl)-2,3-dihydro-1<i>H</i>-inden-1-yl]methyl}malonate |
| title_short | Dimethyl 2-{[2-(2-Methoxy-1-methoxycarbonyl-2-oxoethyl)-4,5,7-trimethoxy-3-(2,4,5-trimethoxyphenyl)-2,3-dihydro-1<i>H</i>-inden-1-yl]methyl}malonate |
| title_sort | dimethyl 2 2 2 methoxy 1 methoxycarbonyl 2 oxoethyl 4 5 7 trimethoxy 3 2 4 5 trimethoxyphenyl 2 3 dihydro 1 i h i inden 1 yl methyl malonate |
| topic | donor–acceptor cyclopropane 2,3-dihydro-1<i>h</i>-indene dimerization reaction domino process |
| url | https://www.mdpi.com/1422-8599/2020/1/M1107 |
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