Estudo da oxidação total do etanol usando óxidos tipo perovskita LaBO3 (B= Mn, Ni, Fe) Study of total oxidation of ethanol using the perovskite-type oxides LaBO3 (B= Mn, Ni, Fe)
<abstract language="eng">The present work investigated the effect of coprecipitation-oxidant synthesis on the specific surface area of perovskite-type oxides LaBO3 (B= Mn, Ni, Fe) for total oxidation of ethanol. The perovskite-type oxides were characterized by X-ray diffraction, nitr...
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Language: | English |
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Sociedade Brasileira de Química
2007-10-01
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Series: | Química Nova |
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Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000500002 |
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author | Ana Brígida Soares Paulo Roberto Nagipe da Silva Jair C. C. Freitas Clara Muniz de Almeida |
author_facet | Ana Brígida Soares Paulo Roberto Nagipe da Silva Jair C. C. Freitas Clara Muniz de Almeida |
author_sort | Ana Brígida Soares |
collection | DOAJ |
description | <abstract language="eng">The present work investigated the effect of coprecipitation-oxidant synthesis on the specific surface area of perovskite-type oxides LaBO3 (B= Mn, Ni, Fe) for total oxidation of ethanol. The perovskite-type oxides were characterized by X-ray diffraction, nitrogen adsorption (BET method), thermogravimetric analysis (TGA-DTA), TPR and X-ray photoelectron spectroscopy (XPS). Through method involving the coprecipitation-oxidant was possible to obtain catalysts with different BET specific surface areas, of 33-51 m²/g. The results of the catalytic test confirmed that all oxides investigated in this work have specific catalytic activity for total oxidation of ethanol, though the temperatures for total conversion change for each transition metal. |
first_indexed | 2024-04-12T18:39:08Z |
format | Article |
id | doaj.art-f432424fcd184b4a86d07c380715cf47 |
institution | Directory Open Access Journal |
issn | 0100-4042 1678-7064 |
language | English |
last_indexed | 2024-04-12T18:39:08Z |
publishDate | 2007-10-01 |
publisher | Sociedade Brasileira de Química |
record_format | Article |
series | Química Nova |
spelling | doaj.art-f432424fcd184b4a86d07c380715cf472022-12-22T03:20:50ZengSociedade Brasileira de QuímicaQuímica Nova0100-40421678-70642007-10-013051061106610.1590/S0100-40422007000500002Estudo da oxidação total do etanol usando óxidos tipo perovskita LaBO3 (B= Mn, Ni, Fe) Study of total oxidation of ethanol using the perovskite-type oxides LaBO3 (B= Mn, Ni, Fe)Ana Brígida SoaresPaulo Roberto Nagipe da SilvaJair C. C. FreitasClara Muniz de Almeida<abstract language="eng">The present work investigated the effect of coprecipitation-oxidant synthesis on the specific surface area of perovskite-type oxides LaBO3 (B= Mn, Ni, Fe) for total oxidation of ethanol. The perovskite-type oxides were characterized by X-ray diffraction, nitrogen adsorption (BET method), thermogravimetric analysis (TGA-DTA), TPR and X-ray photoelectron spectroscopy (XPS). Through method involving the coprecipitation-oxidant was possible to obtain catalysts with different BET specific surface areas, of 33-51 m²/g. The results of the catalytic test confirmed that all oxides investigated in this work have specific catalytic activity for total oxidation of ethanol, though the temperatures for total conversion change for each transition metal.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000500002perovskitesoxidationethanol |
spellingShingle | Ana Brígida Soares Paulo Roberto Nagipe da Silva Jair C. C. Freitas Clara Muniz de Almeida Estudo da oxidação total do etanol usando óxidos tipo perovskita LaBO3 (B= Mn, Ni, Fe) Study of total oxidation of ethanol using the perovskite-type oxides LaBO3 (B= Mn, Ni, Fe) Química Nova perovskites oxidation ethanol |
title | Estudo da oxidação total do etanol usando óxidos tipo perovskita LaBO3 (B= Mn, Ni, Fe) Study of total oxidation of ethanol using the perovskite-type oxides LaBO3 (B= Mn, Ni, Fe) |
title_full | Estudo da oxidação total do etanol usando óxidos tipo perovskita LaBO3 (B= Mn, Ni, Fe) Study of total oxidation of ethanol using the perovskite-type oxides LaBO3 (B= Mn, Ni, Fe) |
title_fullStr | Estudo da oxidação total do etanol usando óxidos tipo perovskita LaBO3 (B= Mn, Ni, Fe) Study of total oxidation of ethanol using the perovskite-type oxides LaBO3 (B= Mn, Ni, Fe) |
title_full_unstemmed | Estudo da oxidação total do etanol usando óxidos tipo perovskita LaBO3 (B= Mn, Ni, Fe) Study of total oxidation of ethanol using the perovskite-type oxides LaBO3 (B= Mn, Ni, Fe) |
title_short | Estudo da oxidação total do etanol usando óxidos tipo perovskita LaBO3 (B= Mn, Ni, Fe) Study of total oxidation of ethanol using the perovskite-type oxides LaBO3 (B= Mn, Ni, Fe) |
title_sort | estudo da oxidacao total do etanol usando oxidos tipo perovskita labo3 b mn ni fe study of total oxidation of ethanol using the perovskite type oxides labo3 b mn ni fe |
topic | perovskites oxidation ethanol |
url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000500002 |
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