Estudo da oxidação total do etanol usando óxidos tipo perovskita LaBO3 (B= Mn, Ni, Fe) Study of total oxidation of ethanol using the perovskite-type oxides LaBO3 (B= Mn, Ni, Fe)

<abstract language="eng">The present work investigated the effect of coprecipitation-oxidant synthesis on the specific surface area of perovskite-type oxides LaBO3 (B= Mn, Ni, Fe) for total oxidation of ethanol. The perovskite-type oxides were characterized by X-ray diffraction, nitr...

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Main Authors: Ana Brígida Soares, Paulo Roberto Nagipe da Silva, Jair C. C. Freitas, Clara Muniz de Almeida
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2007-10-01
Series:Química Nova
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000500002
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author Ana Brígida Soares
Paulo Roberto Nagipe da Silva
Jair C. C. Freitas
Clara Muniz de Almeida
author_facet Ana Brígida Soares
Paulo Roberto Nagipe da Silva
Jair C. C. Freitas
Clara Muniz de Almeida
author_sort Ana Brígida Soares
collection DOAJ
description <abstract language="eng">The present work investigated the effect of coprecipitation-oxidant synthesis on the specific surface area of perovskite-type oxides LaBO3 (B= Mn, Ni, Fe) for total oxidation of ethanol. The perovskite-type oxides were characterized by X-ray diffraction, nitrogen adsorption (BET method), thermogravimetric analysis (TGA-DTA), TPR and X-ray photoelectron spectroscopy (XPS). Through method involving the coprecipitation-oxidant was possible to obtain catalysts with different BET specific surface areas, of 33-51 m²/g. The results of the catalytic test confirmed that all oxides investigated in this work have specific catalytic activity for total oxidation of ethanol, though the temperatures for total conversion change for each transition metal.
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spelling doaj.art-f432424fcd184b4a86d07c380715cf472022-12-22T03:20:50ZengSociedade Brasileira de QuímicaQuímica Nova0100-40421678-70642007-10-013051061106610.1590/S0100-40422007000500002Estudo da oxidação total do etanol usando óxidos tipo perovskita LaBO3 (B= Mn, Ni, Fe) Study of total oxidation of ethanol using the perovskite-type oxides LaBO3 (B= Mn, Ni, Fe)Ana Brígida SoaresPaulo Roberto Nagipe da SilvaJair C. C. FreitasClara Muniz de Almeida<abstract language="eng">The present work investigated the effect of coprecipitation-oxidant synthesis on the specific surface area of perovskite-type oxides LaBO3 (B= Mn, Ni, Fe) for total oxidation of ethanol. The perovskite-type oxides were characterized by X-ray diffraction, nitrogen adsorption (BET method), thermogravimetric analysis (TGA-DTA), TPR and X-ray photoelectron spectroscopy (XPS). Through method involving the coprecipitation-oxidant was possible to obtain catalysts with different BET specific surface areas, of 33-51 m²/g. The results of the catalytic test confirmed that all oxides investigated in this work have specific catalytic activity for total oxidation of ethanol, though the temperatures for total conversion change for each transition metal.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000500002perovskitesoxidationethanol
spellingShingle Ana Brígida Soares
Paulo Roberto Nagipe da Silva
Jair C. C. Freitas
Clara Muniz de Almeida
Estudo da oxidação total do etanol usando óxidos tipo perovskita LaBO3 (B= Mn, Ni, Fe) Study of total oxidation of ethanol using the perovskite-type oxides LaBO3 (B= Mn, Ni, Fe)
Química Nova
perovskites
oxidation
ethanol
title Estudo da oxidação total do etanol usando óxidos tipo perovskita LaBO3 (B= Mn, Ni, Fe) Study of total oxidation of ethanol using the perovskite-type oxides LaBO3 (B= Mn, Ni, Fe)
title_full Estudo da oxidação total do etanol usando óxidos tipo perovskita LaBO3 (B= Mn, Ni, Fe) Study of total oxidation of ethanol using the perovskite-type oxides LaBO3 (B= Mn, Ni, Fe)
title_fullStr Estudo da oxidação total do etanol usando óxidos tipo perovskita LaBO3 (B= Mn, Ni, Fe) Study of total oxidation of ethanol using the perovskite-type oxides LaBO3 (B= Mn, Ni, Fe)
title_full_unstemmed Estudo da oxidação total do etanol usando óxidos tipo perovskita LaBO3 (B= Mn, Ni, Fe) Study of total oxidation of ethanol using the perovskite-type oxides LaBO3 (B= Mn, Ni, Fe)
title_short Estudo da oxidação total do etanol usando óxidos tipo perovskita LaBO3 (B= Mn, Ni, Fe) Study of total oxidation of ethanol using the perovskite-type oxides LaBO3 (B= Mn, Ni, Fe)
title_sort estudo da oxidacao total do etanol usando oxidos tipo perovskita labo3 b mn ni fe study of total oxidation of ethanol using the perovskite type oxides labo3 b mn ni fe
topic perovskites
oxidation
ethanol
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000500002
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