DIFFUSION AND REACTION WITHIN A SHAPED NICKEL PEROVSKITE CATALYST

Abstract : In this study, we prepared a LaNi0.3Al0.7O3 perovskite catalyst using a sol-gel related method (with prop ionic acid as a solvent) for use in the methane dry reforming reaction to produce synthesis gas. We defined the catalyst structure on the basis of X-ray diffraction analysis and measu...

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Main Authors: M. Parvari, M. Moradi
Format: Article
Language:English
Published: Iran University of Science & Technology 2008-07-01
Series:International Journal of Industrial Engineering and Production Research
Subjects:
Online Access:http://ijiepr.iust.ac.ir/browse.php?a_code=A-10-1-9&slc_lang=en&sid=1
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author M. Parvari
M. Moradi
author_facet M. Parvari
M. Moradi
author_sort M. Parvari
collection DOAJ
description Abstract : In this study, we prepared a LaNi0.3Al0.7O3 perovskite catalyst using a sol-gel related method (with prop ionic acid as a solvent) for use in the methane dry reforming reaction to produce synthesis gas. We defined the catalyst structure on the basis of X-ray diffraction analysis and measurements of the specific surface area and particle size distribution. The mixed oxide structure was shaped into a cylindrical pellet before being measured for its mechanical strength. The shaped perovskite catalyst was then tested in the methane dry reforming reaction to produce synthesis gas at atmospheric pressure. The results are compared with the predictions of a mathematical model that is used to estimate the concentration profile within the pellet. The outlet concentration of the reactants and conversion products calculated by the mathematical model has been consistent with the results obtained by experiments conducted in a fixed bed reactor.
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spelling doaj.art-f43a092d47644cc69892ebe04d9fac912022-12-21T19:02:50ZengIran University of Science & TechnologyInternational Journal of Industrial Engineering and Production Research2008-48892345-363X2008-07-01193716DIFFUSION AND REACTION WITHIN A SHAPED NICKEL PEROVSKITE CATALYSTM. Parvari0M. Moradi1 Abstract : In this study, we prepared a LaNi0.3Al0.7O3 perovskite catalyst using a sol-gel related method (with prop ionic acid as a solvent) for use in the methane dry reforming reaction to produce synthesis gas. We defined the catalyst structure on the basis of X-ray diffraction analysis and measurements of the specific surface area and particle size distribution. The mixed oxide structure was shaped into a cylindrical pellet before being measured for its mechanical strength. The shaped perovskite catalyst was then tested in the methane dry reforming reaction to produce synthesis gas at atmospheric pressure. The results are compared with the predictions of a mathematical model that is used to estimate the concentration profile within the pellet. The outlet concentration of the reactants and conversion products calculated by the mathematical model has been consistent with the results obtained by experiments conducted in a fixed bed reactor.http://ijiepr.iust.ac.ir/browse.php?a_code=A-10-1-9&slc_lang=en&sid=1Nickel Perovskite Diffusion Dry Reforming Synthesis Gas
spellingShingle M. Parvari
M. Moradi
DIFFUSION AND REACTION WITHIN A SHAPED NICKEL PEROVSKITE CATALYST
International Journal of Industrial Engineering and Production Research
Nickel
Perovskite
Diffusion
Dry Reforming
Synthesis Gas
title DIFFUSION AND REACTION WITHIN A SHAPED NICKEL PEROVSKITE CATALYST
title_full DIFFUSION AND REACTION WITHIN A SHAPED NICKEL PEROVSKITE CATALYST
title_fullStr DIFFUSION AND REACTION WITHIN A SHAPED NICKEL PEROVSKITE CATALYST
title_full_unstemmed DIFFUSION AND REACTION WITHIN A SHAPED NICKEL PEROVSKITE CATALYST
title_short DIFFUSION AND REACTION WITHIN A SHAPED NICKEL PEROVSKITE CATALYST
title_sort diffusion and reaction within a shaped nickel perovskite catalyst
topic Nickel
Perovskite
Diffusion
Dry Reforming
Synthesis Gas
url http://ijiepr.iust.ac.ir/browse.php?a_code=A-10-1-9&slc_lang=en&sid=1
work_keys_str_mv AT mparvari diffusionandreactionwithinashapednickelperovskitecatalyst
AT mmoradi diffusionandreactionwithinashapednickelperovskitecatalyst