{4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}copper(II)
In the title Schiff base complex, [Cu(C19H16Cl4N2O2)], the geometry around the CuII atom is distorted square-planar defined by the N2O2 donor atoms of the coordinated ligand. The dihedral angle between the substituted benzene rings is 29.95 (16)°. In the crystal, molecules...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681200195X |
| _version_ | 1819294057953755136 |
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| author | Hadi Kargar Reza Kia Saeideh Abbasian Muhammad Nawaz Tahir |
| author_facet | Hadi Kargar Reza Kia Saeideh Abbasian Muhammad Nawaz Tahir |
| author_sort | Hadi Kargar |
| collection | DOAJ |
| description | In the title Schiff base complex, [Cu(C19H16Cl4N2O2)], the geometry around the CuII atom is distorted square-planar defined by the N2O2 donor atoms of the coordinated ligand. The dihedral angle between the substituted benzene rings is 29.95 (16)°. In the crystal, molecules are linked along the b axis, forming individual dimers through C—H...O interactions. The crystal structure is further stabilized by intermolecular π–π interactions [centroid–centroid distance = 3.6131 (17) Å]. |
| first_indexed | 2024-12-24T04:20:17Z |
| format | Article |
| id | doaj.art-f43f864bdacf49478bd38884bda7513b |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T04:20:17Z |
| publishDate | 2012-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-f43f864bdacf49478bd38884bda7513b2022-12-21T17:15:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m182m18210.1107/S160053681200195X{4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}copper(II)Hadi KargarReza KiaSaeideh AbbasianMuhammad Nawaz TahirIn the title Schiff base complex, [Cu(C19H16Cl4N2O2)], the geometry around the CuII atom is distorted square-planar defined by the N2O2 donor atoms of the coordinated ligand. The dihedral angle between the substituted benzene rings is 29.95 (16)°. In the crystal, molecules are linked along the b axis, forming individual dimers through C—H...O interactions. The crystal structure is further stabilized by intermolecular π–π interactions [centroid–centroid distance = 3.6131 (17) Å].http://scripts.iucr.org/cgi-bin/paper?S160053681200195X |
| spellingShingle | Hadi Kargar Reza Kia Saeideh Abbasian Muhammad Nawaz Tahir {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}copper(II) Acta Crystallographica Section E |
| title | {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}copper(II) |
| title_full | {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}copper(II) |
| title_fullStr | {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}copper(II) |
| title_full_unstemmed | {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}copper(II) |
| title_short | {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}copper(II) |
| title_sort | 4 4 amp 8242 6 6 amp 8242 tetrachloro 2 2 amp 8242 2 2 dimethylpropane 1 3 diylbis nitrilomethanylylidene copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681200195X |
| work_keys_str_mv | AT hadikargar 44amp824266amp8242tetrachloro22amp824222dimethylpropane13diylbisnitrilomethanylylidenecopperii AT rezakia 44amp824266amp8242tetrachloro22amp824222dimethylpropane13diylbisnitrilomethanylylidenecopperii AT saeidehabbasian 44amp824266amp8242tetrachloro22amp824222dimethylpropane13diylbisnitrilomethanylylidenecopperii AT muhammadnawaztahir 44amp824266amp8242tetrachloro22amp824222dimethylpropane13diylbisnitrilomethanylylidenecopperii |