Device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule

A boron subphthalocyanine molecule has been employed as a novel electron donor in organic solar cells (OPVs), and optimized in terms of composition and device structure in small molecule solar cells. It is demonstrated that the power conversion efficiency (PCE) of the devices obtained by solution-pr...

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Main Authors: Mehrad Ahmadpour, Michela Prete, Um Kanta Aryal, Anne Ugleholdt Petersen, Mariam Ahmad, Horst-Günter Rubahn, Malte F Jespersen, Kurt V Mikkelsen, Vida Turkovic, Mogens Brøndsted Nielsen, Morten Madsen
Format: Article
Language:English
Published: IOP Publishing 2023-01-01
Series:JPhys Materials
Subjects:
Online Access:https://doi.org/10.1088/2515-7639/acada2
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author Mehrad Ahmadpour
Michela Prete
Um Kanta Aryal
Anne Ugleholdt Petersen
Mariam Ahmad
Horst-Günter Rubahn
Malte F Jespersen
Kurt V Mikkelsen
Vida Turkovic
Mogens Brøndsted Nielsen
Morten Madsen
author_facet Mehrad Ahmadpour
Michela Prete
Um Kanta Aryal
Anne Ugleholdt Petersen
Mariam Ahmad
Horst-Günter Rubahn
Malte F Jespersen
Kurt V Mikkelsen
Vida Turkovic
Mogens Brøndsted Nielsen
Morten Madsen
author_sort Mehrad Ahmadpour
collection DOAJ
description A boron subphthalocyanine molecule has been employed as a novel electron donor in organic solar cells (OPVs), and optimized in terms of composition and device structure in small molecule solar cells. It is demonstrated that the power conversion efficiency (PCE) of the devices obtained by solution-processing in bulk heterojunction solar cells could be improved by one order of magnitude by changing the fabrication method to vacuum deposition, which promotes a better morphology in the OPV active layers. Importantly, upon insertion of an additional pristine C _70 thin interlayer between the active layer and the hole transport layer the PCE was further improved, highlighting the importance of interfacial layer engineering in such subphthalocyanine small molecule OPVs.
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spelling doaj.art-f44090765a4445148b91d783b7bf1ce42023-04-18T13:48:48ZengIOP PublishingJPhys Materials2515-76392023-01-016101400810.1088/2515-7639/acada2Device engineering of organic solar cells based on a boron subphthalocyanine electron donor moleculeMehrad Ahmadpour0Michela Prete1Um Kanta Aryal2https://orcid.org/0000-0002-6432-2530Anne Ugleholdt Petersen3Mariam Ahmad4https://orcid.org/0000-0002-1114-8073Horst-Günter Rubahn5https://orcid.org/0000-0002-3606-5653Malte F Jespersen6Kurt V Mikkelsen7Vida Turkovic8https://orcid.org/0000-0001-5608-1362Mogens Brøndsted Nielsen9Morten Madsen10https://orcid.org/0000-0001-6503-0479SDU CAPE Center for Advanced Photovoltaics and Thin-Film Energy Devices, University of Southern Denmark , Sønderborg, DenmarkSDU CAPE Center for Advanced Photovoltaics and Thin-Film Energy Devices, University of Southern Denmark , Sønderborg, DenmarkSDU CAPE Center for Advanced Photovoltaics and Thin-Film Energy Devices, University of Southern Denmark , Sønderborg, DenmarkDepartment of Chemistry, University of Copenhagen , Copenhagen, DenmarkSDU CAPE Center for Advanced Photovoltaics and Thin-Film Energy Devices, University of Southern Denmark , Sønderborg, DenmarkSDU CAPE Center for Advanced Photovoltaics and Thin-Film Energy Devices, University of Southern Denmark , Sønderborg, DenmarkDepartment of Chemistry, University of Copenhagen , Copenhagen, DenmarkDepartment of Chemistry, University of Copenhagen , Copenhagen, DenmarkSDU CAPE Center for Advanced Photovoltaics and Thin-Film Energy Devices, University of Southern Denmark , Sønderborg, DenmarkDepartment of Chemistry, University of Copenhagen , Copenhagen, DenmarkSDU CAPE Center for Advanced Photovoltaics and Thin-Film Energy Devices, University of Southern Denmark , Sønderborg, DenmarkA boron subphthalocyanine molecule has been employed as a novel electron donor in organic solar cells (OPVs), and optimized in terms of composition and device structure in small molecule solar cells. It is demonstrated that the power conversion efficiency (PCE) of the devices obtained by solution-processing in bulk heterojunction solar cells could be improved by one order of magnitude by changing the fabrication method to vacuum deposition, which promotes a better morphology in the OPV active layers. Importantly, upon insertion of an additional pristine C _70 thin interlayer between the active layer and the hole transport layer the PCE was further improved, highlighting the importance of interfacial layer engineering in such subphthalocyanine small molecule OPVs.https://doi.org/10.1088/2515-7639/acada2organic solar cellsinterlayersmall moleculevacuum-deposition
spellingShingle Mehrad Ahmadpour
Michela Prete
Um Kanta Aryal
Anne Ugleholdt Petersen
Mariam Ahmad
Horst-Günter Rubahn
Malte F Jespersen
Kurt V Mikkelsen
Vida Turkovic
Mogens Brøndsted Nielsen
Morten Madsen
Device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule
JPhys Materials
organic solar cells
interlayer
small molecule
vacuum-deposition
title Device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule
title_full Device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule
title_fullStr Device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule
title_full_unstemmed Device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule
title_short Device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule
title_sort device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule
topic organic solar cells
interlayer
small molecule
vacuum-deposition
url https://doi.org/10.1088/2515-7639/acada2
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