Device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule
A boron subphthalocyanine molecule has been employed as a novel electron donor in organic solar cells (OPVs), and optimized in terms of composition and device structure in small molecule solar cells. It is demonstrated that the power conversion efficiency (PCE) of the devices obtained by solution-pr...
Main Authors: | , , , , , , , , , , |
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Format: | Article |
Language: | English |
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IOP Publishing
2023-01-01
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Series: | JPhys Materials |
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Online Access: | https://doi.org/10.1088/2515-7639/acada2 |
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author | Mehrad Ahmadpour Michela Prete Um Kanta Aryal Anne Ugleholdt Petersen Mariam Ahmad Horst-Günter Rubahn Malte F Jespersen Kurt V Mikkelsen Vida Turkovic Mogens Brøndsted Nielsen Morten Madsen |
author_facet | Mehrad Ahmadpour Michela Prete Um Kanta Aryal Anne Ugleholdt Petersen Mariam Ahmad Horst-Günter Rubahn Malte F Jespersen Kurt V Mikkelsen Vida Turkovic Mogens Brøndsted Nielsen Morten Madsen |
author_sort | Mehrad Ahmadpour |
collection | DOAJ |
description | A boron subphthalocyanine molecule has been employed as a novel electron donor in organic solar cells (OPVs), and optimized in terms of composition and device structure in small molecule solar cells. It is demonstrated that the power conversion efficiency (PCE) of the devices obtained by solution-processing in bulk heterojunction solar cells could be improved by one order of magnitude by changing the fabrication method to vacuum deposition, which promotes a better morphology in the OPV active layers. Importantly, upon insertion of an additional pristine C _70 thin interlayer between the active layer and the hole transport layer the PCE was further improved, highlighting the importance of interfacial layer engineering in such subphthalocyanine small molecule OPVs. |
first_indexed | 2024-04-09T17:26:32Z |
format | Article |
id | doaj.art-f44090765a4445148b91d783b7bf1ce4 |
institution | Directory Open Access Journal |
issn | 2515-7639 |
language | English |
last_indexed | 2024-04-09T17:26:32Z |
publishDate | 2023-01-01 |
publisher | IOP Publishing |
record_format | Article |
series | JPhys Materials |
spelling | doaj.art-f44090765a4445148b91d783b7bf1ce42023-04-18T13:48:48ZengIOP PublishingJPhys Materials2515-76392023-01-016101400810.1088/2515-7639/acada2Device engineering of organic solar cells based on a boron subphthalocyanine electron donor moleculeMehrad Ahmadpour0Michela Prete1Um Kanta Aryal2https://orcid.org/0000-0002-6432-2530Anne Ugleholdt Petersen3Mariam Ahmad4https://orcid.org/0000-0002-1114-8073Horst-Günter Rubahn5https://orcid.org/0000-0002-3606-5653Malte F Jespersen6Kurt V Mikkelsen7Vida Turkovic8https://orcid.org/0000-0001-5608-1362Mogens Brøndsted Nielsen9Morten Madsen10https://orcid.org/0000-0001-6503-0479SDU CAPE Center for Advanced Photovoltaics and Thin-Film Energy Devices, University of Southern Denmark , Sønderborg, DenmarkSDU CAPE Center for Advanced Photovoltaics and Thin-Film Energy Devices, University of Southern Denmark , Sønderborg, DenmarkSDU CAPE Center for Advanced Photovoltaics and Thin-Film Energy Devices, University of Southern Denmark , Sønderborg, DenmarkDepartment of Chemistry, University of Copenhagen , Copenhagen, DenmarkSDU CAPE Center for Advanced Photovoltaics and Thin-Film Energy Devices, University of Southern Denmark , Sønderborg, DenmarkSDU CAPE Center for Advanced Photovoltaics and Thin-Film Energy Devices, University of Southern Denmark , Sønderborg, DenmarkDepartment of Chemistry, University of Copenhagen , Copenhagen, DenmarkDepartment of Chemistry, University of Copenhagen , Copenhagen, DenmarkSDU CAPE Center for Advanced Photovoltaics and Thin-Film Energy Devices, University of Southern Denmark , Sønderborg, DenmarkDepartment of Chemistry, University of Copenhagen , Copenhagen, DenmarkSDU CAPE Center for Advanced Photovoltaics and Thin-Film Energy Devices, University of Southern Denmark , Sønderborg, DenmarkA boron subphthalocyanine molecule has been employed as a novel electron donor in organic solar cells (OPVs), and optimized in terms of composition and device structure in small molecule solar cells. It is demonstrated that the power conversion efficiency (PCE) of the devices obtained by solution-processing in bulk heterojunction solar cells could be improved by one order of magnitude by changing the fabrication method to vacuum deposition, which promotes a better morphology in the OPV active layers. Importantly, upon insertion of an additional pristine C _70 thin interlayer between the active layer and the hole transport layer the PCE was further improved, highlighting the importance of interfacial layer engineering in such subphthalocyanine small molecule OPVs.https://doi.org/10.1088/2515-7639/acada2organic solar cellsinterlayersmall moleculevacuum-deposition |
spellingShingle | Mehrad Ahmadpour Michela Prete Um Kanta Aryal Anne Ugleholdt Petersen Mariam Ahmad Horst-Günter Rubahn Malte F Jespersen Kurt V Mikkelsen Vida Turkovic Mogens Brøndsted Nielsen Morten Madsen Device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule JPhys Materials organic solar cells interlayer small molecule vacuum-deposition |
title | Device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule |
title_full | Device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule |
title_fullStr | Device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule |
title_full_unstemmed | Device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule |
title_short | Device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule |
title_sort | device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule |
topic | organic solar cells interlayer small molecule vacuum-deposition |
url | https://doi.org/10.1088/2515-7639/acada2 |
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