Bis[2,6-bis(benzimidazol-2-yl)pyridine-κ3N,N′,N′′]nickel(II) bis(trifluoromethanesulfonate) diethyl ether monosolvate
In the title complex, [Ni(C19H13N5)2](CF3SO3)2·(CH3CH2)2O, the central NiII atom is sixfold coordinated by three nitrogen atoms of each 2,6-bis(2-benzimidazolyl)pyridine ligand in a distorted octahedral geometry with two trifluoromethanesulfonate ions and a molecule of diethyl ether completing the o...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2024-01-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314624000889 |
| _version_ | 1797324018179637248 |
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| author | Sarah E. Ruiz Hadi D. Arman Rafael A. Adrian |
| author_facet | Sarah E. Ruiz Hadi D. Arman Rafael A. Adrian |
| author_sort | Sarah E. Ruiz |
| collection | DOAJ |
| description | In the title complex, [Ni(C19H13N5)2](CF3SO3)2·(CH3CH2)2O, the central NiII atom is sixfold coordinated by three nitrogen atoms of each 2,6-bis(2-benzimidazolyl)pyridine ligand in a distorted octahedral geometry with two trifluoromethanesulfonate ions and a molecule of diethyl ether completing the outer coordination sphere of the complex. Hydrogen bonding contributes to the organization of the asymmetric units in columns along the a axis generating a porous supramolecular structure. The structure was refined as a two-component twin with a refined BASF value of 0.4104 (13). |
| first_indexed | 2024-03-08T05:36:25Z |
| format | Article |
| id | doaj.art-f4593790371c4d908b851c4dee25b5e5 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-03-08T05:36:25Z |
| publishDate | 2024-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-f4593790371c4d908b851c4dee25b5e52024-02-05T17:27:28ZengInternational Union of CrystallographyIUCrData2414-31462024-01-0191x24008810.1107/S2414314624000889vm4063Bis[2,6-bis(benzimidazol-2-yl)pyridine-κ3N,N′,N′′]nickel(II) bis(trifluoromethanesulfonate) diethyl ether monosolvateSarah E. Ruiz0Hadi D. Arman1Rafael A. Adrian2Department of Chemistry and Biochemistry, University of the Incarnate Word, San Antonio, Texas 78209, USADepartment of Chemistry, The University of Texas at San Antonio, San Antonio, Texas 78249, USADepartment of Chemistry and Biochemistry, University of the Incarnate Word, San Antonio, Texas 78209, USAIn the title complex, [Ni(C19H13N5)2](CF3SO3)2·(CH3CH2)2O, the central NiII atom is sixfold coordinated by three nitrogen atoms of each 2,6-bis(2-benzimidazolyl)pyridine ligand in a distorted octahedral geometry with two trifluoromethanesulfonate ions and a molecule of diethyl ether completing the outer coordination sphere of the complex. Hydrogen bonding contributes to the organization of the asymmetric units in columns along the a axis generating a porous supramolecular structure. The structure was refined as a two-component twin with a refined BASF value of 0.4104 (13).http://scripts.iucr.org/cgi-bin/paper?S2414314624000889crystal structurenickel(ii)trifluoromethanesulfonate salt2,6-bis(2-benzimidazolyl)pyridineoctahedral geometryhydrogen bonddiethyl ether solvate |
| spellingShingle | Sarah E. Ruiz Hadi D. Arman Rafael A. Adrian Bis[2,6-bis(benzimidazol-2-yl)pyridine-κ3N,N′,N′′]nickel(II) bis(trifluoromethanesulfonate) diethyl ether monosolvate IUCrData crystal structure nickel(ii) trifluoromethanesulfonate salt 2,6-bis(2-benzimidazolyl)pyridine octahedral geometry hydrogen bond diethyl ether solvate |
| title | Bis[2,6-bis(benzimidazol-2-yl)pyridine-κ3N,N′,N′′]nickel(II) bis(trifluoromethanesulfonate) diethyl ether monosolvate |
| title_full | Bis[2,6-bis(benzimidazol-2-yl)pyridine-κ3N,N′,N′′]nickel(II) bis(trifluoromethanesulfonate) diethyl ether monosolvate |
| title_fullStr | Bis[2,6-bis(benzimidazol-2-yl)pyridine-κ3N,N′,N′′]nickel(II) bis(trifluoromethanesulfonate) diethyl ether monosolvate |
| title_full_unstemmed | Bis[2,6-bis(benzimidazol-2-yl)pyridine-κ3N,N′,N′′]nickel(II) bis(trifluoromethanesulfonate) diethyl ether monosolvate |
| title_short | Bis[2,6-bis(benzimidazol-2-yl)pyridine-κ3N,N′,N′′]nickel(II) bis(trifluoromethanesulfonate) diethyl ether monosolvate |
| title_sort | bis 2 6 bis benzimidazol 2 yl pyridine κ3n n n nickel ii bis trifluoromethanesulfonate diethyl ether monosolvate |
| topic | crystal structure nickel(ii) trifluoromethanesulfonate salt 2,6-bis(2-benzimidazolyl)pyridine octahedral geometry hydrogen bond diethyl ether solvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314624000889 |
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