tert-Butyl 4-(2-diazoacetyl)piperazine-1-carboxylate
The title crystal structure, C11H18N4O3, is the first diazoacetamide in which the diazoacetyl group is attached to an N atom. The piperazine ring is in a chair form and hence the molecule has an extended conformation. Both ring N atoms are bonded in an essentially planar configuration with the sum o...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810016211 |
| _version_ | 1819279923174440960 |
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| author | Åsmund Kaupang Carl Henrik Görbitz Tore Hansen |
| author_facet | Åsmund Kaupang Carl Henrik Görbitz Tore Hansen |
| author_sort | Åsmund Kaupang |
| collection | DOAJ |
| description | The title crystal structure, C11H18N4O3, is the first diazoacetamide in which the diazoacetyl group is attached to an N atom. The piperazine ring is in a chair form and hence the molecule has an extended conformation. Both ring N atoms are bonded in an essentially planar configuration with the sum of the C—N—C angles being 359.8 (2) and 357.7 (2)°. In the crystal structure, the O atom of the diazoacetyl group accepts two H atoms from C—H donors, thus generating chains of weak hydrogen-bonded R21(7) rings. |
| first_indexed | 2024-12-24T00:35:37Z |
| format | Article |
| id | doaj.art-f469d67298a848de975375887fefefee |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:35:37Z |
| publishDate | 2010-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-f469d67298a848de975375887fefefee2022-12-21T17:24:05ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666o1299o129910.1107/S1600536810016211tert-Butyl 4-(2-diazoacetyl)piperazine-1-carboxylateÅsmund KaupangCarl Henrik GörbitzTore HansenThe title crystal structure, C11H18N4O3, is the first diazoacetamide in which the diazoacetyl group is attached to an N atom. The piperazine ring is in a chair form and hence the molecule has an extended conformation. Both ring N atoms are bonded in an essentially planar configuration with the sum of the C—N—C angles being 359.8 (2) and 357.7 (2)°. In the crystal structure, the O atom of the diazoacetyl group accepts two H atoms from C—H donors, thus generating chains of weak hydrogen-bonded R21(7) rings.http://scripts.iucr.org/cgi-bin/paper?S1600536810016211 |
| spellingShingle | Åsmund Kaupang Carl Henrik Görbitz Tore Hansen tert-Butyl 4-(2-diazoacetyl)piperazine-1-carboxylate Acta Crystallographica Section E |
| title | tert-Butyl 4-(2-diazoacetyl)piperazine-1-carboxylate |
| title_full | tert-Butyl 4-(2-diazoacetyl)piperazine-1-carboxylate |
| title_fullStr | tert-Butyl 4-(2-diazoacetyl)piperazine-1-carboxylate |
| title_full_unstemmed | tert-Butyl 4-(2-diazoacetyl)piperazine-1-carboxylate |
| title_short | tert-Butyl 4-(2-diazoacetyl)piperazine-1-carboxylate |
| title_sort | tert butyl 4 2 diazoacetyl piperazine 1 carboxylate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810016211 |
| work_keys_str_mv | AT amp197smundkaupang tertbutyl42diazoacetylpiperazine1carboxylate AT carlhenrikgamp246rbitz tertbutyl42diazoacetylpiperazine1carboxylate AT torehansen tertbutyl42diazoacetylpiperazine1carboxylate |